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dc.contributor.author | Arias Carrascal, Karen Sulay![]() |
es_ES |
dc.contributor.author | Garcia-Ortiz, Andrea![]() |
es_ES |
dc.contributor.author | Climent Olmedo, María José![]() |
es_ES |
dc.contributor.author | Corma Canós, Avelino![]() |
es_ES |
dc.contributor.author | Iborra Chornet, Sara![]() |
es_ES |
dc.date.accessioned | 2019-06-14T20:42:04Z | |
dc.date.available | 2019-06-14T20:42:04Z | |
dc.date.issued | 2018 | es_ES |
dc.identifier.issn | 2168-0485 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/122230 | |
dc.description | This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Sustainable Chemistry & Engineering, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acssuschemeng.7b04685 | |
dc.description.abstract | [EN] Biomass platform molecules such as glycerol and 5-hydroxymethylfurfural have been valorized into diol monomers by acetalization reaction in the presence of tridirectional large pore zeolites (HY and Beta), a laminar zeolite (ITQ-2) and a mesoporous aluminosilicate (MGM-41), and a conventional homogeneous acid catalyst (p-toluenesulfonic acid). The influence of the solvent polarity, pore structure, hydrophobic character, and acidity of the catalyst on the activity and selectivity to 5-hydroxymethylfurfural (HMF) glyceryl acetals has been studied. Results showed that, while the homogeneous catalyst mainly promotes polymerization reactions, tridirectional zeolites are more active catalysts but less selective and deactivate more rapidly than mesoporous MCM-41 and delaminated two-dimensional zeolites. ITQ-2 and MCM-41 catalysts with smaller confinement effects, easy diffusion, and adequate surface polarity provide high yield (98%) and selectivity (100%) to the target compound. These catalysts are stable and allow regeneration and reuse. | es_ES |
dc.description.sponsorship | Spanish MICINN Project CTQ-2015-67592-P and Program Severo Ochoa (SEV-2016-0683) are gratefully acknowledged. A.G.-O. thanks the Severo Ochoa Program for FPI fellowships. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | ACS Sustainable Chemistry & Engineering | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | 5-Hydroxymethylfwfural glyceryl acetals | es_ES |
dc.subject | Platform biomass molecules | es_ES |
dc.subject | Diol monomers | es_ES |
dc.subject | ITQ-2 | es_ES |
dc.subject | MCM-41 | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Mutual Valorization of 5-Hydroxymethylfurfural and Glycerol into Valuable Diol Monomers with Solid Acid Catalysts | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1021/acssuschemeng.7b04685 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-67592-P/ES/VALORIZACION DE COMPUESTO OXIGENADOS PRESENTES EN FRACCIONES ACUOSAS DERIVADAS DE BIOMASA EN COMBUSTIBLES Y PRODUCTOS QUIMICOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Arias Carrascal, KS.; Garcia-Ortiz, A.; Climent Olmedo, MJ.; Corma Canós, A.; Iborra Chornet, S. (2018). Mutual Valorization of 5-Hydroxymethylfurfural and Glycerol into Valuable Diol Monomers with Solid Acid Catalysts. ACS Sustainable Chemistry & Engineering. 6(3):4239-4245. https://doi.org/10.1021/acssuschemeng.7b04685 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1021/acssuschemeng.7b04685 | es_ES |
dc.description.upvformatpinicio | 4239 | es_ES |
dc.description.upvformatpfin | 4245 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 6 | es_ES |
dc.description.issue | 3 | es_ES |
dc.relation.pasarela | S\370364 | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |