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Electrochemical identification of painters/workshops: The case of Valencian Renaissance-Baroque painters (ca. 1550- ca. 1670)

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Electrochemical identification of painters/workshops: The case of Valencian Renaissance-Baroque painters (ca. 1550- ca. 1670)

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dc.contributor.author Doménech Carbó, Antonio es_ES
dc.contributor.author Domenech Carbo, Mª Teresa es_ES
dc.contributor.author Castelló Palacios, Amparo es_ES
dc.contributor.author Guerola Blay, Vicente es_ES
dc.contributor.author Pérez Marín, Eva es_ES
dc.date.accessioned 2019-06-23T20:01:08Z
dc.date.available 2019-06-23T20:01:08Z
dc.date.issued 2019 es_ES
dc.identifier.issn 0013-4686 es_ES
dc.identifier.uri http://hdl.handle.net/10251/122557
dc.description.abstract [EN] The voltammetry of immobilized particles (VIMP) methodology was applied to discriminate the oil painting production of a series of seven painters/workshops that worked in Valencia (Spain) between ca. 1530 and ca. 1650. When submicrosamples used for cross-section FESEM/EDX analysis were attached to graphite electrodes in contact with aqueous acetate buffer, well-defined responses were obtained. The reductive processes of lead pigments (lead white and lead-tin yellow) overlapped those associated to the lead soaps and other species resulting from the pigment-oil binder interaction in the sample. Such responses, which are theoretically modeled, were sensitive to changes in paint type and dose and thus provided a painter/workshop-characteristic voltammetric response defining a usable electrochemical fingerprint for authorship assessments. (C) 2018 Elsevier Ltd. All rights reserved. es_ES
dc.description.sponsorship Project CTQ2017-85317-C2-1-P, supported with Ministerio de Economia, Industria y Competitividad (MINECO), Fondo Europeo de Desarrollo Regional (ERDF) and Agencia Estatal de Investigacion (AEI), is gratefully acknowledged. The authors wish also to thank Mr. Manuel Planes and Dr. Jose Luis Moya, technical supervisors of the Electron Microscopy Service of the Universitat Politecnica de Valencia. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation AEI/CTQ2017-85317-C2-1-P-AR es_ES
dc.relation.ispartof Electrochimica Acta es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Electrochemistry es_ES
dc.subject Oil painting es_ES
dc.subject Authorship discrimination es_ES
dc.subject Lead pigments es_ES
dc.subject Lead soaps es_ES
dc.subject Electron Microscopy Service of the UPV es_ES
dc.subject.classification PINTURA es_ES
dc.title Electrochemical identification of painters/workshops: The case of Valencian Renaissance-Baroque painters (ca. 1550- ca. 1670) es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.electacta.2018.11.212 es_ES
dc.rights.accessRights Embargado es_ES
dc.date.embargoEndDate 2021-02-20 es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Conservación y Restauración de Bienes Culturales - Departament de Conservació i Restauració de Béns Culturals es_ES
dc.description.bibliographicCitation Doménech Carbó, A.; Domenech Carbo, MT.; Castelló Palacios, A.; Guerola Blay, V.; Pérez Marín, E. (2019). Electrochemical identification of painters/workshops: The case of Valencian Renaissance-Baroque painters (ca. 1550- ca. 1670). Electrochimica Acta. 297:685-695. https://doi.org/10.1016/j.electacta.2018.11.212 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1016/j.electacta.2018.11.212 es_ES
dc.description.upvformatpinicio 685 es_ES
dc.description.upvformatpfin 695 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 297 es_ES
dc.relation.pasarela S\377395 es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES


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