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Direct crude oil cracking for producing chemicals: Thermal cracking modeling

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Direct crude oil cracking for producing chemicals: Thermal cracking modeling

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dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author Sauvanaud, Laurent L.A. es_ES
dc.contributor.author Mathieu, Yannick es_ES
dc.contributor.author Al-bogami, Saad es_ES
dc.contributor.author Bourane, Abdennour es_ES
dc.contributor.author Al-Ghrami, Musaed es_ES
dc.date.accessioned 2019-06-30T20:01:53Z
dc.date.available 2019-06-30T20:01:53Z
dc.date.issued 2018 es_ES
dc.identifier.issn 0016-2361 es_ES
dc.identifier.uri http://hdl.handle.net/10251/122918
dc.description.abstract [EN] The direct cracking of crude oil is an interesting option for producing cheaply large amounts of petrochemicals. This may be carried out with catalyst and equipment similar to that of catalytic cracking, but at a temperature range between that of standard catalytic cracking and steam cracking. Thermal cracking will play a role in the conversion, but is rarely disclosed in experimental or modeling work. Thus, a crude oil and its fractions were thermally cracked and the products yields were modeled using a 9 lumps cracking scheme. It was found that heavy fraction cracks twice as fast as diesel fraction and ten times faster than gasoline fraction, with activation energies in the 140-200 kJ/mol range. Selectivity to ethylene, propylene and butenes were found similar in the operating range explored. es_ES
dc.description.sponsorship The authors thank Saudi Aramco for its material and financial support. Financial support by the Spanish Government-MINECO through programs "Severo Ochoa" (SEV 2012-0267) and CTQ2015-70126-R and by the Generalitat Valenciana through the Prometeo program (PROMETEOII/2013/011) is also acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation MINECO/SEV-2012-0267 es_ES
dc.relation GV/PROMETEO II /2013/011 es_ES
dc.relation MINECO/CTQ2015-70126-R es_ES
dc.relation.ispartof Fuel es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Crude oil es_ES
dc.subject Thermal cracking es_ES
dc.subject Modeling es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Direct crude oil cracking for producing chemicals: Thermal cracking modeling es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.fuel.2017.09.099 es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Corma Canós, A.; Sauvanaud, LL.; Mathieu, Y.; Al-Bogami, S.; Bourane, A.; Al-Ghrami, M. (2018). Direct crude oil cracking for producing chemicals: Thermal cracking modeling. Fuel. 211:726-736. https://doi.org/10.1016/j.fuel.2017.09.099 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1016/j.fuel.2017.09.099 es_ES
dc.description.upvformatpinicio 726 es_ES
dc.description.upvformatpfin 736 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 211 es_ES
dc.relation.pasarela 358665 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Generalitat Valenciana es_ES


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