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Processing and Characterization of Environmentally Friendly Composites from Biobased Polyethylene and Natural Fillers from Thyme Herbs

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Processing and Characterization of Environmentally Friendly Composites from Biobased Polyethylene and Natural Fillers from Thyme Herbs

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dc.contributor.author Montanes, Nestor es_ES
dc.contributor.author Garcia-Sanoguera, David es_ES
dc.contributor.author Segui Llinares, Vicente Jesús es_ES
dc.contributor.author Fenollar, Octavio es_ES
dc.contributor.author Boronat, Teodomiro es_ES
dc.date.accessioned 2019-09-19T20:00:34Z
dc.date.available 2019-09-19T20:00:34Z
dc.date.issued 2018 es_ES
dc.identifier.issn 1566-2543 es_ES
dc.identifier.uri http://hdl.handle.net/10251/126096
dc.description.abstract [EN] The main aim of this research work is to assess the potential of a distillery waste from thyme as multifunctional filler in natural fiber reinforced plastics (NFRP) with biobased polyethylene matrix. Several ethylene-based copolymers with different co-monomers (vinyl alcohol, methyl methacrylate, glycidyl methacrylate and acrylic acid) were used as compatibilizer agents to overcome the lack of compatibility between the highly hydrophobic matrix and the highly hydrophilic lignocellulosic filler. The effect of the compatibilizer type and amount, as well as the lignocellulosic filler content was followed by thermal, mechanical, morphological and rheological characterizations. In addition to the typical filler effect, thyme also provides a remarkable increase in thermal stability at moderate temperatures with a positive effect on widening the processing window. The compatibilizer agent that offers best balanced properties is the glycidyl methacrylate copolymer with a noticeable increase in stiffness, flexural and tensile strength. Regarding processability, the viscosity increases with the filler content. This is highly important at low shear rates but the effect is almost negligible at high shear rates typical of injection molding processes. es_ES
dc.description.sponsorship This research was supported by the Ministry of Economy and Competitiveness-MINECO through the grant number MAT2014-59242-C2-1-R. Authors also wish to thank "Licores Sinc, S.A." for kindly supplying the Thymus moroderi wastes. es_ES
dc.language Inglés es_ES
dc.publisher Springer-Verlag es_ES
dc.relation.ispartof Journal of Polymers and the Environment es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Natural fiber composites es_ES
dc.subject Particle reinforcement es_ES
dc.subject Mechanical properties es_ES
dc.subject Thermal properties es_ES
dc.subject Thyme es_ES
dc.subject.classification INGENIERIA DE LOS PROCESOS DE FABRICACION es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Processing and Characterization of Environmentally Friendly Composites from Biobased Polyethylene and Natural Fillers from Thyme Herbs es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10924-017-1025-2 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2014-59242-C2-1-R/ES/TECNICAS AVANZADAS DE PROCESADO PARA SISTEMAS ACTIVOS ENCAPSULADOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.description.bibliographicCitation Montanes, N.; Garcia-Sanoguera, D.; Segui Llinares, VJ.; Fenollar, O.; Boronat, T. (2018). Processing and Characterization of Environmentally Friendly Composites from Biobased Polyethylene and Natural Fillers from Thyme Herbs. Journal of Polymers and the Environment. 26(3):1218-1230. https://doi.org/10.1007/s10924-017-1025-2 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1007/s10924-017-1025-2 es_ES
dc.description.upvformatpinicio 1218 es_ES
dc.description.upvformatpfin 1230 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 26 es_ES
dc.description.issue 3 es_ES
dc.relation.pasarela S\338146 es_ES
dc.contributor.funder Ministerio de Economía, Industria y Competitividad es_ES
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