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dc.contributor.author | Moliner, C.![]() |
es_ES |
dc.contributor.author | Badia, J.D.![]() |
es_ES |
dc.contributor.author | Bosio, B.![]() |
es_ES |
dc.contributor.author | Arato, E.![]() |
es_ES |
dc.contributor.author | Teruel-Juanes, R.![]() |
es_ES |
dc.contributor.author | Kittikorn, T.![]() |
es_ES |
dc.contributor.author | Stromberg, E.![]() |
es_ES |
dc.contributor.author | Ek, M.![]() |
es_ES |
dc.contributor.author | Karlsson, S.![]() |
es_ES |
dc.contributor.author | Ribes-Greus, A.![]() |
es_ES |
dc.date.accessioned | 2019-12-28T21:00:40Z | |
dc.date.available | 2019-12-28T21:00:40Z | |
dc.date.issued | 2018 | es_ES |
dc.identifier.issn | 0040-6031 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/133754 | |
dc.description.abstract | [EN] The thermal stability and decomposition kinetics of PLA/sisal biocomposites was discussed to evaluate the suitability of their use in energy recovery processes such as pyrolysis and combustion. The influence of the addition of sisal up to 30%wt, the presence of coupling agent, and the atmosphere of operation, i.e. inert or oxidative was discussed by means of multi-rate linear non-isothermal thermogravimetric experiments. All biocomposites showed a mean high heating value of 15 MJ/kg indicating their suitability for energy recovery processes. The thermal requirements of PLA/sisal decomposition were assessed in terms of onset decomposition temperature and apparent activation energy. A minimum of 240 degrees C and 174 kJ mol(-1) in inert environment and 225 degrees C and 190 kJ mol(-1) in oxidative environment ensured the feasibility of the reactions regardless the composition of the PLA/sisal biocomposites. The atmosphere of work lead to a greater amount of residue in case of pyrolysis reactions that would need further treatment whereas an oxidative atmosphere resulted in nearly zero final waste stream. The similar kinetics obtained for all samples regardless the amount of sisal or use of coupling agent eases the operability of energy facilities aimed of turning these biowastes into new fuels. | es_ES |
dc.description.sponsorship | The Spanish Ministry of Economy and Competitiveness and European Regional Development Funds are acknowledged for the projects ENE2014-53734-C2-1-R, ENE2017-86711-C3-1-R (UPOV13-3E-1947). Generalitat Valenciana is thanked for the APOSTD/2014/041 for J.D. Badia. The financial support given by the Prince of Songkla University and KTH Royal Institute of Technology is gratefully acknowledged. Rossella Acerbo and Emanuele Righi are gratefully acknowledged for their activity in the framework of their Bachelor Theses. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation.ispartof | Thermochimica Acta | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Energy valorisation | es_ES |
dc.subject | Thermal decomposition | es_ES |
dc.subject | Kinetics | es_ES |
dc.subject | Biocomposites | es_ES |
dc.subject | Polylactide (PLA) | es_ES |
dc.subject | Natural fibres | es_ES |
dc.subject.classification | MAQUINAS Y MOTORES TERMICOS | es_ES |
dc.title | Thermal kinetics for the energy valorisation of polylactide/sisal biocomposites | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1016/j.tca.2018.10.029 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//ENE2014-53734-C2-1-R/ES/DISEÑO Y VALIDACION DE MEMBRANAS CON CONTROL MORFOLOGICO PARA SU USO EN PILAS DE COMBUSTIBLE DE BAJA TEMPERATURA SOSTENIBLES EN VEHICULOS EFICIENTES NO TRIPULADOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2017-86711-C3-1-R/ES/SISTEMA INTEGRADO DE DESCARBONIZACION Y PRODUCCION DE ENERGIA BASADO EN PILAS DE COMBUSTIBLE DE METANOL DIRECTO PARA APLICACIONES NAVALES Y AEROESPACIALES/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//APOSTD%2F2014%2F041/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Máquinas y Motores Térmicos - Departament de Màquines i Motors Tèrmics | es_ES |
dc.description.bibliographicCitation | Moliner, C.; Badia, J.; Bosio, B.; Arato, E.; Teruel-Juanes, R.; Kittikorn, T.; Stromberg, E.... (2018). Thermal kinetics for the energy valorisation of polylactide/sisal biocomposites. Thermochimica Acta. 670:169-177. https://doi.org/10.1016/j.tca.2018.10.029 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1016/j.tca.2018.10.029 | es_ES |
dc.description.upvformatpinicio | 169 | es_ES |
dc.description.upvformatpfin | 177 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 670 | es_ES |
dc.relation.pasarela | S\379081 | es_ES |
dc.contributor.funder | Generalitat Valenciana | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | Ministerio de Economía y Empresa | es_ES |