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An Na8 Cluster in the Structure of a Novel oxamato-bridged Na'Cu'' three-Dimensional Coordination Polymer

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An Na8 Cluster in the Structure of a Novel oxamato-bridged Na'Cu'' three-Dimensional Coordination Polymer

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dc.contributor.author Aukauloo, A. es_ES
dc.contributor.author Ottenwaelder, X. es_ES
dc.contributor.author Ruiz, R. es_ES
dc.contributor.author Journaux, Y. es_ES
dc.contributor.author Pei, Y. es_ES
dc.contributor.author Riviére, E. es_ES
dc.contributor.author Cervera, B. es_ES
dc.contributor.author Muñoz Roca, María Del Carmen es_ES
dc.date.accessioned 2020-03-13T08:29:16Z
dc.date.available 2020-03-13T08:29:16Z
dc.date.issued 1999-01-18 es_ES
dc.identifier.issn 1434-1948 es_ES
dc.identifier.uri http://hdl.handle.net/10251/138902
dc.description.abstract [EN] The new heterometallic sodium(I)¿copper(II) compound Na4Cu2 (2) · 10.5 H2O (3), where H8[2] stands for N,N',N'',N'''-methanetetrayltetrakismethylenetetrakis(oxamic acid), has been synthesized and its crystal structure determined by single-crystal X-ray diffraction. The structure of 3 consists of cationic [Cu2(¿4:¿4-2)]4- dinuclear units, coordinated sodium cations, and water molecules. In the crystal, the dinuclear copper entities are joined through discrete aggregates of eight sodium atoms linked by oxamato and water bridges, leading to a three-dimensional polymeric network. es_ES
dc.description.sponsorship This work was supported by the CNRS (France) and the DGICYT (Spain) through project PB94-1002. B. C. thanks the Conselleria de Educació i Ciència de la Generalitat Valenciana (Spain) for a grant. We would also like to express our gratitude to Profs. M. Julve and T. Mallah for fruitful discussions during the preparation of this manuscript. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof European Journal of Inorganic Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Amides es_ES
dc.subject Chirality es_ES
dc.subject Clusters es_ES
dc.subject Copper es_ES
dc.subject Sodium es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title An Na8 Cluster in the Structure of a Novel oxamato-bridged Na'Cu'' three-Dimensional Coordination Polymer es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/(SICI)1099-0682(19990202)1999:2<209::AID-EJIC209>3.0.CO;2-J es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MEC//PB94-1002/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Aukauloo, A.; Ottenwaelder, X.; Ruiz, R.; Journaux, Y.; Pei, Y.; Riviére, E.; Cervera, B.... (1999). An Na8 Cluster in the Structure of a Novel oxamato-bridged Na'Cu'' three-Dimensional Coordination Polymer. European Journal of Inorganic Chemistry. 1999(2):209-212. https://doi.org/10.1002/(SICI)1099-0682(19990202)1999:2<209::AID-EJIC209>3.0.CO;2-J es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/(SICI)1099-0682(19990202)1999:2<209::AID-EJIC209>3.0.CO;2-J es_ES
dc.description.upvformatpinicio 209 es_ES
dc.description.upvformatpfin 212 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 1999 es_ES
dc.description.issue 2 es_ES
dc.relation.pasarela S\16535 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Centre National de la Recherche Scientifique, Francia es_ES
dc.contributor.funder Ministerio de Educación y Ciencia es_ES
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