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Manganese(III)-mediated oxidative carbon-carbon bond cleavage of 1,10-phenanthroline-5,6-dione ligand

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Manganese(III)-mediated oxidative carbon-carbon bond cleavage of 1,10-phenanthroline-5,6-dione ligand

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Ruiz, R.; Caneschi, A.; Gatteschi, D.; Gaspar, AB.; Real, JA.; Fernández, I.; Muñoz Roca, MDC. (01-1). Manganese(III)-mediated oxidative carbon-carbon bond cleavage of 1,10-phenanthroline-5,6-dione ligand. Inorganic Chemistry Communications. 2(11):521-523. https://doi.org/10.1016/S1387-7003(99)00144-6

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Title: Manganese(III)-mediated oxidative carbon-carbon bond cleavage of 1,10-phenanthroline-5,6-dione ligand
Author:
UPV Unit: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Issued date:
Abstract:
[EN] A new manganese(III)-1,10-phenanthroline-5,6-dione (phendione) complex possessing a putative Mn-2(mu-O) (mu-O2CMe)(2) core has been found to undergo a Ligand-based oxidative cleavage of the C(5)-C(6) bond in weak acid ...[+]
Subjects: Carboxylato complexes , Crystal structures , Manganese complexes , Oxidation , Polynuclear complexes , Quinone complexes
Copyrigths: Cerrado
Source:
Inorganic Chemistry Communications. (issn: 1387-7003 )
DOI: 10.1016/S1387-7003(99)00144-6
Publisher:
Elsevier
Publisher version: https://doi.org/10.1016/S1387-7003(99)00144-6
Thanks:
This work was supported by the DGICYT, Ministerio de Educación y Ciencia (Spain) through projects PB97-1397 and PB97-1411. R.R. thanks the 3MD-EU Network (contract no. ERB 4061, PL 97-0197) for a grant. We would also like ...[+]
Type: Artículo

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