Blay, G.; Fernández, I.; Pedro, JR.; Ruiz-García, R.; Muñoz Roca, MDC.; Cano, J.; Carrasco, R. (2003). A Hydrogen-Bonded Supramolecular meso-Helix. European Journal of Organic Chemistry. 2003(9):1627-1630. https://doi.org/10.1002/ejoc.200200544
Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/139154
Title:
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A Hydrogen-Bonded Supramolecular meso-Helix
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Author:
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Blay, G.
Fernández, I.
Pedro, J. R.
Ruiz-García, R.
Muñoz Roca, María Del Carmen
Cano, J.
Carrasco, R.
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UPV Unit:
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Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
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Issued date:
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Abstract:
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[EN] A new one-dimensional hydrogen-bonded polymer with a unique meso-helical structure has been prepared from the spontaneous self-assembly in the solid-state of meta-substituted phenylene dioxamic acid diethyl ester ...[+]
[EN] A new one-dimensional hydrogen-bonded polymer with a unique meso-helical structure has been prepared from the spontaneous self-assembly in the solid-state of meta-substituted phenylene dioxamic acid diethyl ester monomers. The helical nature of this molecule and its self-complementary character, through intermolecular hydrogen bonding between oxamic acid ester functions, are the two main factors responsible for the crystalline aggregation process, as confirmed by both experimental X-ray crystallographic data and theoretical ab initio calculations.
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Subjects:
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Amides
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Crystal engineering
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Density functional calculations
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Helical structures
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Hydrogen bonds
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Copyrigths:
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Cerrado |
Source:
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European Journal of Organic Chemistry. (issn:
1434-193X
)
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DOI:
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10.1002/ejoc.200200544
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Publisher:
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John Wiley & Sons
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Publisher version:
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https://doi.org/10.1002/ejoc.200200544
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Project ID:
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Ministerio de Ciencia y Tecnología/BQU2001-2928
MCYT/BQU2001-3017
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Description:
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"This is the peer reviewed version of the following article: [FULL CITE], which has been published in final form at [Link to final article using the DOI]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."
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Thanks:
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This work was supported by the Ministerio de Ciencia y Tecnología (Spain) through the Plan Nacional de Investigación Científica, Desarrollo e Innovación Tecnológica (I+D+I) (Projects ref. BQU2001-3017 and BQU2001-2928) and ...[+]
This work was supported by the Ministerio de Ciencia y Tecnología (Spain) through the Plan Nacional de Investigación Científica, Desarrollo e Innovación Tecnológica (I+D+I) (Projects ref. BQU2001-3017 and BQU2001-2928) and the Ramon y Cajal programs. We thank Profs. Miguel Julve and Francesc Lloret, and Dr. José¿ A. Real for their continuing interest in this work and fruitful discussions during the preparation of the manuscript.
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Type:
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Artículo
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