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Basic zeolites containing palladium as bifunctional heterogeneous catalysts for the Heck reaction

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Basic zeolites containing palladium as bifunctional heterogeneous catalysts for the Heck reaction

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Nombre: Corma;García;Leyva ...
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dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Leyva Perez, Antonio es_ES
dc.contributor.author Primo Arnau, Ana Maria es_ES
dc.date.accessioned 2020-04-01T07:15:37Z
dc.date.available 2020-04-01T07:15:37Z
dc.date.issued 2003 es_ES
dc.identifier.issn 0926-860X es_ES
dc.identifier.uri http://hdl.handle.net/10251/139928
dc.description.abstract [EN] K+ and Cs+ exchanged X zeolite containing PdCl2 catalyzes the Heck reaction of PhI or PhBr with styrene in toluene or polymethylbenzenes without the need of extrinsic base. The reaction is truly heterogeneous and no leaching was observed. The activity of the fresh catalyst can be regained in a large extent upon reactivation with water washings. The unprecedented preferent formation of the 1,1-diphenylethene has been observed using PdCl2-CsX as catalyst, a fact that has been related to the smaller size of the transition state leading to this isomer compared to stilbene. (C) 2003 Elsevier Science B.V. All rights reserved. es_ES
dc.description.sponsorship Financial support by the Spanish D.G.E.S. (MAT-2000-1768-C02-01) is gratefully acknowledged. A.L. and A.P thank the Spanish Ministry of Education for post-graduate scholarships. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Applied Catalysis A General es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Basic zeolites containing palladium as bifunctional heterogeneous catalysts for the Heck reaction es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/S0926-860X(03)00060-7 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICYT//MAT2000-1768-C02-01/
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Corma Canós, A.; García Gómez, H.; Leyva Perez, A.; Primo Arnau, AM. (2003). Basic zeolites containing palladium as bifunctional heterogeneous catalysts for the Heck reaction. Applied Catalysis A General. 247(1):41-49. https://doi.org/10.1016/S0926-860X(03)00060-7 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/S0926-860X(03)00060-7 es_ES
dc.description.upvformatpinicio 41 es_ES
dc.description.upvformatpfin 49 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 247 es_ES
dc.description.issue 1 es_ES
dc.relation.pasarela S\220126 es_ES
dc.contributor.funder Ministerio de Ciencia y Tecnología es_ES
dc.contributor.funder Ministerio de Educación


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