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Mixed-metal or mixed-linker metal organic frameworks as heterogeneous catalysts

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Mixed-metal or mixed-linker metal organic frameworks as heterogeneous catalysts

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dc.contributor.author Dhakshinamoorthy, Amarajothi es_ES
dc.contributor.author Asiri, Abdullah M. es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2020-04-06T08:56:37Z
dc.date.available 2020-04-06T08:56:37Z
dc.date.issued 2016 es_ES
dc.identifier.issn 2044-4753 es_ES
dc.identifier.uri http://hdl.handle.net/10251/140217
dc.description.abstract [EN] Metal organic frameworks (MOFs) are among the most studied heterogeneous catalysts that have been applied to promote a wide range of reactions. Most of the initial studies on the catalytic activity of MOFs were based on the use of materials containing a single metal and a single linker. However, the most recent trend in the field is to exploit the synthetic flexibility offered by MOFs to obtain new MOFs possessing two different metals in their structure, or the same metal in different oxidation states (¿mixed metals¿) or different linkers (¿mixed linkers¿), resulting in materials with a superior catalytic activity over the corresponding single metal or single linker MOFs. This review is aimed to address the possible advantages of the use of mixed metal or mixed linker strategies to increase the activity of MOFs in some selected reactions. After some general sections introducing the structural features of MOFs, the nature of possible active sites, different ways to characterize mixed-metal or mixed-ligand MOFs and good practices, the main body of the review describes the current state of the art in the use of this type of MOF as heterogeneous catalysts, classified depending on the presence of more than one metal or more than one ligand. The final concluding remarks include some future targets in the area. es_ES
dc.description.sponsorship ADM thanks University Grants Commission (UGC), New Delhi for the award of Assistant Professorship under its Faculty Recharge Programme. ADM also thanks the Department of Science and Technology, India, for financial support through the Fast Track project (SB/FT/CS-166/2013) and the Generalidad Valenciana for financial aid supporting his stay at Valencia through the Prometeo programme. Financial support by the Spanish Ministry of Economy and Competitiveness (CTQ-2015-69153-C2-1-R and Severo Ochoa) and Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged. The research leading to these results has received partial funding from the European Community's Seventh Framework Programme (FP7/2007-2013) under grant agreement no. 228862. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation DST/ SB/FT/CS-166/2013 es_ES
dc.relation GV/Prometeo 2012-014 es_ES
dc.relation MINISTERIO DE ECONOMIA Y EMPRESA/CTQ2015-69153-C2-1-R es_ES
dc.relation.ispartof Catalysis Science & Technology es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Mixed-metal or mixed-linker metal organic frameworks as heterogeneous catalysts es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c6cy00695g es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/228862/EU es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Dhakshinamoorthy, A.; Asiri, AM.; García Gómez, H. (2016). Mixed-metal or mixed-linker metal organic frameworks as heterogeneous catalysts. Catalysis Science & Technology. 6(14):5238-5261. https://doi.org/10.1039/c6cy00695g es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c6cy00695g es_ES
dc.description.upvformatpinicio 5238 es_ES
dc.description.upvformatpfin 5261 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 6 es_ES
dc.description.issue 14 es_ES
dc.relation.pasarela S\328613 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía y Empresa es_ES
dc.contributor.funder University Grants Commission, India es_ES
dc.contributor.funder Department of Science and Technology, India es_ES


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