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Catalytic Activity of Cationic and Neutral Silver(I)-XPhos Complexes with Nitrogen Ligands or Tolylsulfonate for Mannich and Aza-Diels-Alder Coupling Reactions

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Catalytic Activity of Cationic and Neutral Silver(I)-XPhos Complexes with Nitrogen Ligands or Tolylsulfonate for Mannich and Aza-Diels-Alder Coupling Reactions

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dc.contributor.author Grirrane, Abdessamad es_ES
dc.contributor.author Alvarez-González, Eleuterio es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2020-04-06T08:57:45Z
dc.date.available 2020-04-06T08:57:45Z
dc.date.issued 2016 es_ES
dc.identifier.issn 0947-6539 es_ES
dc.identifier.uri http://hdl.handle.net/10251/140256
dc.description.abstract [EN] Cationic and neutral silver(I)-L complexes (L = Buchwald-type biaryl phosphanes) with nitrogen co-ligands or organosulfonate counter ions have been synthesised and characterised through their structural and spectroscopic properties. At room temperature, both cationic and neutral silver(I)-L complexes are extremely active catalysts in the promotion of the single and double A(3) coupling of terminal (di)alkynes, pyrrolidine and formaldehyde. In addition, the aza-Diels-Alder two-and three-component coupling reactions of Danishefsky's diene with an imine or amine and aldehyde are efficiently catalysed by these cationic or neutral silver(I)-L complexes. The solvent influences the catalytic performance due to limited complex solubility or solvent decomposition and reactivity. The isolation of new silver(I)-L complexes with reagents as ligands lends support to mechanistic proposals for such catalytic processes. The activity, stability and metal-distal arene interaction of these silver(I)L catalysts have been compared with those of analogous cationic gold(I) and copper(I) complexes. es_ES
dc.description.sponsorship Financial support by the Spanish ministry of Economy and Competitiveness (Severo Ochoa and CTQ2012-32315) and the Generalidad Valenciana (Prometeo 2012-014) is gratefully acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation GV/PROMETEO/2012/014 es_ES
dc.relation MINECO/CTQ2012-32315 es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Cross-coupling es_ES
dc.subject Homogeneous catalysis es_ES
dc.subject P ligands es_ES
dc.subject Reaction mechanisms es_ES
dc.subject Silver es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Catalytic Activity of Cationic and Neutral Silver(I)-XPhos Complexes with Nitrogen Ligands or Tolylsulfonate for Mannich and Aza-Diels-Alder Coupling Reactions es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/chem.201503386 es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Grirrane, A.; Alvarez-González, E.; García Gómez, H.; Corma Canós, A. (2016). Catalytic Activity of Cationic and Neutral Silver(I)-XPhos Complexes with Nitrogen Ligands or Tolylsulfonate for Mannich and Aza-Diels-Alder Coupling Reactions. Chemistry - A European Journal. 22(1):340-354. https://doi.org/10.1002/chem.201503386 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/chem.201503386 es_ES
dc.description.upvformatpinicio 340 es_ES
dc.description.upvformatpfin 354 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 22 es_ES
dc.description.issue 1 es_ES
dc.relation.pasarela S\328551 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía, Industria y Competitividad es_ES
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