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dc.contributor.author | Alfonso, Carmina | es_ES |
dc.contributor.author | Feliz Rodriguez, Marta | es_ES |
dc.contributor.author | Llusar, Rosa | es_ES |
dc.date.accessioned | 2020-04-17T12:48:16Z | |
dc.date.available | 2020-04-17T12:48:16Z | |
dc.date.issued | 2017 | es_ES |
dc.identifier.issn | 1877-9441 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/140842 | |
dc.description.abstract | [EN] Molecular molybdenum cluster sulphides are an unexpensive alternative to noble metal based homogenous catalysts. In this paper, we present the synthesis of the first PNP Mo3S4 derivative as well as the crystal structure of the isomer which contains the ligand bound in a bidentate fashion. The potential of this new complex as precursor for heterobimetallic systems is also analyzed.Our results indicated that Mo3S4 cluster cores can be functionalized with aminodiphosphine groups acting as bidentate or tridentate ligands. | es_ES |
dc.description.sponsorship | The financial support of the Spanish Ministerio de Economía y Competitividad (Grant CTQ2015-65207), Universitat Jaume I (Research Project P1·1B2013-19) and Generalitat Valenciana (Prometeo/2014/022) is gratefully acknowledged. The authors also thank the Servei Central d Instrumentació Científica (SCIC) of the University Jaume I for providing us with the mass spectrometry, NMR, elemental analysis and X-ray facilities. C.A. thanks the Spanish Ministerio de Economía y Competitividad for a predoctoral fellowship (FPI). | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | Bentham Science | es_ES |
dc.relation.ispartof | Current Inorganic Chemistry | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Molybdenum sulfides | es_ES |
dc.subject | Trinuclear clusters | es_ES |
dc.subject | Aminodiphosphane complexes | es_ES |
dc.subject | Denticity | es_ES |
dc.subject | Elemental analysis | es_ES |
dc.subject | Ligands | es_ES |
dc.title | Coordination Modes of Aminodiphosphane Ligands to the Cuboidal Mo3S4 Cluster Unit | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.2174/1877944107666171025162409 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//CTQ2015-65207-P/ES/DISEÑO RACIONAL DE MATERIALES A ESCALA MICRO, NANO Y CLUSTER BASADOS EN METALES DEL GRUPO SEIS PARA APLICACIONES EN CATALISIS Y FOTOCATALISIS COMBINANDO TEORIA Y EXPERIMENTO./ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/UJI//P1·1B2013-19/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//PROMETEO%2F2014%2F022/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Alfonso, C.; Feliz Rodriguez, M.; Llusar, R. (2017). Coordination Modes of Aminodiphosphane Ligands to the Cuboidal Mo3S4 Cluster Unit. Current Inorganic Chemistry. 7(2):106-110. https://doi.org/10.2174/1877944107666171025162409 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.2174/1877944107666171025162409 | es_ES |
dc.description.upvformatpinicio | 106 | es_ES |
dc.description.upvformatpfin | 110 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 7 | es_ES |
dc.description.issue | 2 | es_ES |
dc.relation.pasarela | S\355712 | es_ES |
dc.contributor.funder | Universitat Jaume I | es_ES |
dc.contributor.funder | Generalitat Valenciana | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |