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Chemistry and reactivity of dinuclear manganese oxamate complexes: Aerobic catechol oxidation catalyzed by high-valent bis(oxo)-bridged dimanganese(IV) complexes with a homologous series of binucleating 4,5-disubstituted-o-phennylenedioxamate ligands

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Chemistry and reactivity of dinuclear manganese oxamate complexes: Aerobic catechol oxidation catalyzed by high-valent bis(oxo)-bridged dimanganese(IV) complexes with a homologous series of binucleating 4,5-disubstituted-o-phennylenedioxamate ligands

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Blay, G.; Fernández, I.; Pedro, JR.; Ruiz-García, R.; Temporal-Sánchez, T.; Pardo, E.; Lloret, F.... (2006). Chemistry and reactivity of dinuclear manganese oxamate complexes: Aerobic catechol oxidation catalyzed by high-valent bis(oxo)-bridged dimanganese(IV) complexes with a homologous series of binucleating 4,5-disubstituted-o-phennylenedioxamate ligands. Journal of Molecular Catalysis A Chemical. 250(1-2):20-26. https://doi.org/10.1016/j.molcata.2006.01.021

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/140873

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Title: Chemistry and reactivity of dinuclear manganese oxamate complexes: Aerobic catechol oxidation catalyzed by high-valent bis(oxo)-bridged dimanganese(IV) complexes with a homologous series of binucleating 4,5-disubstituted-o-phennylenedioxamate ligands
Author: Blay, G. Fernández, I. Pedro, J. R. Ruiz-García, R. Temporal-Sánchez, T. Pardo, E. Lloret, F. Muñoz Roca, María Del Carmen
UPV Unit: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Issued date:
Abstract:
[EN] The high-valent bis(oxo)-bridged dimanganese(IV) complexes with the series of binucleating 4.5-X-2-o-phenylenebis(oxamate) ligands (opbaX(2); X = H, Cl, Me) (1a-c) have been synthesized and characterized structurally, ...[+]
Subjects: Catalysis , Catechols , Manganese , O-O Bond activation , Oxidations , Redox properties
Copyrigths: Cerrado
Source:
Journal of Molecular Catalysis A Chemical. (issn: 1381-1169 )
DOI: 10.1016/j.molcata.2006.01.021
Publisher:
Elsevier
Publisher version: https://doi.org/10.1016/j.molcata.2006.01.021
Project ID:
GV/CTIDIA2002-131
MCYT/BQU2001-3017
GV/AVCYT 03/168
Thanks:
This work was supported by the Ministerio de Ciencia y Tecnología (Spain) (Project BQU2001-3017) and the Ramon y Cajal program. Further support from the Generalitat Valenciana (Spain) (Project CTIDIA2002-131 and AVCYT ...[+]
Type: Artículo

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