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dc.contributor.author | Galet, A. | es_ES |
dc.contributor.author | Niel, V. | es_ES |
dc.contributor.author | Muñoz Roca, María Del Carmen | es_ES |
dc.contributor.author | Real, J. A. | es_ES |
dc.date.accessioned | 2020-04-17T12:49:17Z | |
dc.date.available | 2020-04-17T12:49:17Z | |
dc.date.issued | 2003-11-26 | es_ES |
dc.identifier.issn | 0002-7863 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/140877 | |
dc.description.abstract | [EN] Self-assembly of [Ag(CN)2]-, 3-cyanopyridine, and iron(II) gives triple interpenetration of three-dimensional spin crossover (SCO) networks with the NbO topology, which interact each other via argentophilic interactions. Superposition of the networks along the c-axis defines an infinite mosaic of trigonal and hexagonal cross-sectional tubes where water molecules are installed. The structural changes associated with the SCO tune the homoatomic interactions and induce an uncommon change of the lattice volume. | es_ES |
dc.description.sponsorship | We are grateful for the financial assistance from the Ministerio Español de Ciencia y Tecnología (project BQU 2001-2928). A.G. thanks the Universitat Politécnica de València for a predoctoral fellowship. We are grateful to Dr. A. E. Goeta for helpful discussions | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation.ispartof | Journal of the American Chemical Society | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | Iron | es_ES |
dc.subject | Quantum mechanics | es_ES |
dc.subject | Gold | es_ES |
dc.subject | Hysteresis | es_ES |
dc.subject | Materials | es_ES |
dc.subject.classification | FISICA APLICADA | es_ES |
dc.title | Synergy Between Spin Crossover and Metallophilicity in Triple Interpenetrated 3D Nets with the NbO Structure Type | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1021/ja0377347 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/MICYT//BQU2001-2928/ES/Msíntesis, Estructura y Propiedades Magnéticas de Compuestos con Interacción de Canje entre Centros Metálicos/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada | es_ES |
dc.description.bibliographicCitation | Galet, A.; Niel, V.; Muñoz Roca, MDC.; Real, JA. (2003). Synergy Between Spin Crossover and Metallophilicity in Triple Interpenetrated 3D Nets with the NbO Structure Type. Journal of the American Chemical Society. 125(47):14224-14225. https://doi.org/10.1021/ja0377347 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.1021/ja0377347 | es_ES |
dc.description.upvformatpinicio | 14224 | es_ES |
dc.description.upvformatpfin | 14225 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 125 | es_ES |
dc.description.issue | 47 | es_ES |
dc.relation.pasarela | S\24186 | es_ES |
dc.contributor.funder | Ministerio de Ciencia y Tecnología | es_ES |
dc.contributor.funder | Universitat Politècnica de València | es_ES |