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Atrane complexes chemistry as a tool for obtaining trimodal UVM-7-like porous silica

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Atrane complexes chemistry as a tool for obtaining trimodal UVM-7-like porous silica

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dc.contributor.author Garrido, María Dolores es_ES
dc.contributor.author García-Llacer, C. es_ES
dc.contributor.author El Haskouri, Jamal es_ES
dc.contributor.author Marcos Martínez, María Dolores es_ES
dc.contributor.author Sánchez-Royo, J. F. es_ES
dc.contributor.author Beltrán, Aurelio es_ES
dc.contributor.author Amorós, P. es_ES
dc.date.accessioned 2020-04-17T12:49:56Z
dc.date.available 2020-04-17T12:49:56Z
dc.date.issued 2018 es_ES
dc.identifier.issn 0095-8972 es_ES
dc.identifier.uri http://hdl.handle.net/10251/140900
dc.description This is an Accepted Manuscript of an article published by Taylor & Francis in Journal of Coordination Chemistry on 2018, available online: http://www.tandfonline.com/10.1080/00958972.2018.1442002 es_ES
dc.description.abstract [EN] The use of atrane complexes as hydrolytic precursors enables the homogeneous incorporation of manganese (25Si/Mn48) throughout the porous walls of the nanoparticles of a surfactant-templated bimodal mesoporous silica (UVM-7). The subsequent leaching of the manganese nanodomains allows adding controlled microporosity to the host silica framework. The resulting final silica material presents three pore systems structured at different length scales: interparticle textural-type macroporosity (ca. 43.2nm), ordered intraparticle mesoporosity (ca. 2.63nm; after template removal), and well-dispersed microporosity (< 2nm; as consequence of the lixiviation of the Mn-rich domains). The good dispersion of the guest element (Mn) in the silica intermediate provided by the atrane route is responsible for the disordered but regular microporosity achieved. es_ES
dc.description.sponsorship This work was supported by the Spanish Ministerio de Economia y Competitividad and the European Feder Funds [grant number MAT2015-64139-C4-2-R]. es_ES
dc.language Inglés es_ES
dc.publisher Taylor & Francis es_ES
dc.relation.ispartof Journal of Coordination Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Atrane complexes es_ES
dc.subject Silica es_ES
dc.subject Mesoporous es_ES
dc.subject Microporous es_ES
dc.subject Etching es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.title Atrane complexes chemistry as a tool for obtaining trimodal UVM-7-like porous silica es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1080/00958972.2018.1442002 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-64139-C4-2-R/ES/SOLIDOS MESOPOROSOS Y PARTICULADOS PARA EL DISEÑO DE MATERIALES TERANOSTICOS/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Garrido, MD.; García-Llacer, C.; El Haskouri, J.; Marcos Martínez, MD.; Sánchez-Royo, JF.; Beltrán, A.; Amorós, P. (2018). Atrane complexes chemistry as a tool for obtaining trimodal UVM-7-like porous silica. Journal of Coordination Chemistry. 71(6):776-785. https://doi.org/10.1080/00958972.2018.1442002 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1080/00958972.2018.1442002 es_ES
dc.description.upvformatpinicio 776 es_ES
dc.description.upvformatpfin 785 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 71 es_ES
dc.description.issue 6 es_ES
dc.relation.pasarela S\363873 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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