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Cooperative spin crossover behavior in cyanide-bridged Fe(II)-M(II) bimetallic 3D Hofmann-like networks (M = Ni, Pd, and Pt)

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Cooperative spin crossover behavior in cyanide-bridged Fe(II)-M(II) bimetallic 3D Hofmann-like networks (M = Ni, Pd, and Pt)

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Nombre: Niel;Martinez-Agu ...
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dc.contributor.author Niel, V. es_ES
dc.contributor.author Martinez-Agudo, J. M. es_ES
dc.contributor.author Muñoz Roca, María Del Carmen es_ES
dc.contributor.author Gaspar, A. B. es_ES
dc.contributor.author Real, J. A. es_ES
dc.date.accessioned 2020-04-17T12:50:39Z
dc.date.available 2020-04-17T12:50:39Z
dc.date.issued 2001-07-30 es_ES
dc.identifier.issn 0020-1669 es_ES
dc.identifier.uri http://hdl.handle.net/10251/140924
dc.description.abstract [EN] The three-dimensional polymeric compounds [Fe(pz)M(CN)(4)]. nH(2)O (PZ = pyrazine, M Ni(II), Pd(II), and Pt(Il)) have been synthesized and characterized. They undergo strong cooperative spin transitions, large hysteresis loops, and dramatic color changes upon spin conversion. The two-dimensional homologues [Fe(PY)(2)M(CN)(4)] (py = pyridine; M = Ni(II), Pd(II), and Pt(II)) also have been synthesized and characterized. In the latter case cooperativity is smaller than in the tri-dimensional derivatives, and consequently narrower hysteresis loops were observed. es_ES
dc.description.sponsorship This research was supported by the Spanish Dirección General de Investigación Científica y Técnica (DGICYT) (Project PB97-1397) and the European Commission (TMR-Network Thermal and Optical Switching of Molecular Spin States (TOSS) , Contract No. ERB-FMRX-CT98-0199EEC/ TMR). es_ES
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof Inorganic Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Cooperative spin crossover behavior in cyanide-bridged Fe(II)-M(II) bimetallic 3D Hofmann-like networks (M = Ni, Pd, and Pt) es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1021/ic010259y es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC//ERB-FMRX-CT98-0199EEC%2FTMR/EU/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MECD//PB97-1387/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Niel, V.; Martinez-Agudo, JM.; Muñoz Roca, MDC.; Gaspar, AB.; Real, JA. (2001). Cooperative spin crossover behavior in cyanide-bridged Fe(II)-M(II) bimetallic 3D Hofmann-like networks (M = Ni, Pd, and Pt). Inorganic Chemistry. 40(16):3838-3839. https://doi.org/10.1021/ic010259y es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1021/ic010259y es_ES
dc.description.upvformatpinicio 3838 es_ES
dc.description.upvformatpfin 3839 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 40 es_ES
dc.description.issue 16 es_ES
dc.relation.pasarela S\20916 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Ministerio de Educación, Cultura y Deporte es_ES


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