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Switchable Spin-Crossover Hofmann-Type 3D Coordination Polymers Based on Tri- and Tetratopic Ligands

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Switchable Spin-Crossover Hofmann-Type 3D Coordination Polymers Based on Tri- and Tetratopic Ligands

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dc.contributor.author Valverde-Muñoz, F. J. es_ES
dc.contributor.author Muñoz Roca, María Del Carmen es_ES
dc.contributor.author Ferrer, S. es_ES
dc.contributor.author Bartual-Murgui, C. es_ES
dc.contributor.author Real, J. A. es_ES
dc.date.accessioned 2020-04-17T12:51:45Z
dc.date.available 2020-04-17T12:51:45Z
dc.date.issued 2018-10-01 es_ES
dc.identifier.issn 0020-1669 es_ES
dc.identifier.uri http://hdl.handle.net/10251/140961
dc.description.abstract [EN] Fe-II spin-crossover (SCO) coordination polymers of the Hofmann type have become an archetypal class of responsive materials. Almost invariably, the construction of their architectures has been based on the use of monotopic and linear ditopic pyridine like ligands. In the search for new Hofmann-type architectures with SCO properties, here we analyze the possibilities of bridging ligands with higher connectivity degree. More precisely, the synthesis and structure of {Fe-II(L-N3)[M-I(CN)(2)](2)}center dot(Guest) (Guest = nitro-benzene, benzonitrile, o-dichlorobenzene; M-I = Ag, Au) and {Fe-II(L-N4)[Ag-2(CN)(3)][Ag(CN)(2)]}center dot H2O are described, where L-N3 and L-N4 are the tritopic and tetratopic ligands 1,3,5-tris(pyridin-4-ylethynyl)benzene and 1,2,4,5-tetrakis(pyridin-4-ylethynyl)benzene. This new series of Hofmann clathrates displays thermo- and photoinduced SCO behaviors. es_ES
dc.description.sponsorship We thank the Spanish Ministerio de Economia y Competitividad (MINECO) and FEDER funds (CTQ2013-46275-P and CTQ2016-78341-P and Unidad de Excelencia Maria de Maeztu MDM-2015-0538), and Generalitat Valenciana (PROMETEO/2016/147). FJ.V.-M. thanks MINECO for a predoctoral FPI grant. We also thank Dr. Carlos Marti for helping us with ToposPro software. es_ES
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof Inorganic Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Switchable Spin-Crossover Hofmann-Type 3D Coordination Polymers Based on Tri- and Tetratopic Ligands es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1021/acs.inorgchem.8b01842 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2013-46275-P/ES/SENSORES Y MEMORIAS BASADOS EN MATERIALES BIESTABLES CON TRANSICION DE ESPIN/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO2016%2F147/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2016-78341-P/ES/MATERIALES SPIN CROSSOVER BIESTABLES: DE LAS PROPIEDADES MACROSCOPICAS A LA ESPINTRONICA MOLECULAR/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MDM-2015-0538/ES/INSTITUTO DE CIENCIA MOLECULAR/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Valverde-Muñoz, FJ.; Muñoz Roca, MDC.; Ferrer, S.; Bartual-Murgui, C.; Real, JA. (2018). Switchable Spin-Crossover Hofmann-Type 3D Coordination Polymers Based on Tri- and Tetratopic Ligands. Inorganic Chemistry. 57(19):12195-12205. https://doi.org/10.1021/acs.inorgchem.8b01842 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1021/acs.inorgchem.8b01842 es_ES
dc.description.upvformatpinicio 12195 es_ES
dc.description.upvformatpfin 12205 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 57 es_ES
dc.description.issue 19 es_ES
dc.relation.pasarela S\373562 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES


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