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Finding the Additives Incorporation Moment in Hybrid Natural Pigments Synthesis to Improve Bioresin Properties

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Finding the Additives Incorporation Moment in Hybrid Natural Pigments Synthesis to Improve Bioresin Properties

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dc.contributor.author Micó-Vicent, Bárbara es_ES
dc.contributor.author Jordán Núñez, Jorge es_ES
dc.contributor.author Perales Romero, Esther es_ES
dc.contributor.author Martínez-Verdú, Francisco Miguel es_ES
dc.contributor.author Cases, Francisco es_ES
dc.date.accessioned 2020-04-24T07:14:39Z
dc.date.available 2020-04-24T07:14:39Z
dc.date.issued 2019 es_ES
dc.identifier.uri http://hdl.handle.net/10251/141466
dc.description.abstract [EN] Interest in applications of natural dye applications has increased because of their antibacterial properties and the possibility of extracting them from nature and residues. Using nanoclays as hosts to reinforce natural dye properties has been successfully demonstrated. However, no one has attempted to optimize the polymer matrix and hybrid pigment properties at the same time to ensure the best final properties for bio-composite applications. Using a statistical design for experiments, we propose the best combination of modifiers with the best nanoclay as the host of three natural dyes: chlorophyll, ß-carotene, and betanine. Using the L9 Taguchi designs, we learned both the influence of the nanoclay structure, and the addition moment of surfactant, mordant salt, and silane modifiers. FTIR, XRD, DTG, integration sphere spectrophotometer, and UV-aging tests were used to characterize the hybrid pigments and epoxy bioresin composites. The degradation temperatures of the three natural dyes rose and the reinforcement of the stability of three natural dyes to UV¿Vis radiation exposure was demonstrated, which avoided the migration of these dyes from bioresin to wet ribbing. Optimal results were obtained with hydrotalcite clay (calcined or not) by using surfactant and mordant before the natural dye, and before or after silane. View Full-Text es_ES
dc.description.sponsorship This research was funded by Spanish Agencia Estatal de Investigacion (AEI) and the European Union (FEDER funds) (contract MAT2016-77742-C2-1-P) and Spanish Ministry of Economy and Competitiveness (project DPI2015-65814-R). es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Coatings es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Hybrid pigments es_ES
dc.subject Natural dyes es_ES
dc.subject Biopolymer es_ES
dc.subject Taguchi es_ES
dc.subject FTIR es_ES
dc.subject Fastness es_ES
dc.subject.classification QUIMICA FISICA es_ES
dc.subject.classification ESTADISTICA E INVESTIGACION OPERATIVA es_ES
dc.title Finding the Additives Incorporation Moment in Hybrid Natural Pigments Synthesis to Improve Bioresin Properties es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/coatings9010034 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//DPI2015-65814-R/ES/REPRODUCCION DIGITAL AVANZADA DE LA GONIOAPARIENCIA VISUAL DE OBJETOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2016-77742-C2-1-P/ES/DESARROLLO DE MATERIALES POROSOS 2D Y 3D CON APLICACIONES ELECTROQUIMICAS, CATALITICAS, TERMICAS Y BIOMEDICAS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Estadística e Investigación Operativa Aplicadas y Calidad - Departament d'Estadística i Investigació Operativa Aplicades i Qualitat es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Textil y Papelera - Departament d'Enginyeria Tèxtil i Paperera es_ES
dc.description.bibliographicCitation Micó-Vicent, B.; Jordán Núñez, J.; Perales Romero, E.; Martínez-Verdú, FM.; Cases, F. (2019). Finding the Additives Incorporation Moment in Hybrid Natural Pigments Synthesis to Improve Bioresin Properties. Coatings. 9(1):1-17. https://doi.org/10.3390/coatings9010034 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/coatings9010034 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 17 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 9 es_ES
dc.description.issue 1 es_ES
dc.identifier.eissn 2079-6412 es_ES
dc.relation.pasarela S\375202 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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