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Generating and optimizing the catalytic activity in UiO-66 for aerobic oxidation of alkenes by post-synthetic exchange Ti atoms combined with ligand substitution

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Generating and optimizing the catalytic activity in UiO-66 for aerobic oxidation of alkenes by post-synthetic exchange Ti atoms combined with ligand substitution

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Santiago-Portillo, A.; Navalón Oltra, S.; Alvaro Rodríguez, MM.; García Gómez, H. (2018). Generating and optimizing the catalytic activity in UiO-66 for aerobic oxidation of alkenes by post-synthetic exchange Ti atoms combined with ligand substitution. Journal of Catalysis. 365:450-463. https://doi.org/10.1016/j.jcat.2018.07.032

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/141965

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Title: Generating and optimizing the catalytic activity in UiO-66 for aerobic oxidation of alkenes by post-synthetic exchange Ti atoms combined with ligand substitution
Author: Santiago-Portillo, Andrea Navalón Oltra, Sergio Alvaro Rodríguez, Maria Mercedes García Gómez, Hermenegildo
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] The catalytic activity for the aerobic epoxidation of cyclooctene of UiO-66 has been introduced by post synthetic ion exchange of Zr4+ by Ti4+ at the nodes and the performance optimized by nitro substitution in the ...[+]
Subjects: Heterogeneous catalysis , Aerobic oxidation of alkenes , Metal-organic frameworks , UiO-66
Copyrigths: Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)
Source:
Journal of Catalysis. (issn: 0021-9517 )
DOI: 10.1016/j.jcat.2018.07.032
Publisher:
Elsevier
Publisher version: https://doi.org/10.1016/j.jcat.2018.07.032
Project ID:
MINECO/CTQ2015-69563-CO2-14
GV/PROMETEO/2017/018
info:eu-repo/grantAgreement/MINECO//CTQ2014-53292-R/ES/MATERIALES GRAFENICOS COMO CATALIZADORES PARA REACCIONES ORGANICAS./
Thanks:
Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and CTQ2014-53292-R and CTQ2015-69563-CO2-14) is gratefully acknowledged. Generalidad Valenciana is also thanked for funding (Prometeo ...[+]
Type: Artículo

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