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A highly stable and hierarchical tetrathiafulvalene-based metal organic framework with improved performance as a solid catalyst

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A highly stable and hierarchical tetrathiafulvalene-based metal organic framework with improved performance as a solid catalyst

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dc.contributor.author Souto, Manuel es_ES
dc.contributor.author Santiago-Portillo, Andrea es_ES
dc.contributor.author Palomino Roca, Miguel es_ES
dc.contributor.author Vitorica-Yrezabal, Iñigo J. es_ES
dc.contributor.author Vieira, Bruno J. C. es_ES
dc.contributor.author Waerenborgh, João C. es_ES
dc.contributor.author Valencia Valencia, Susana es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.contributor.author Rey Garcia, Fernando es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Minguez Espallargas, Guillermo es_ES
dc.date.accessioned 2020-05-06T07:17:48Z
dc.date.available 2020-05-06T07:17:48Z
dc.date.issued 2018-03 es_ES
dc.identifier.issn 2041-6520 es_ES
dc.identifier.uri http://hdl.handle.net/10251/142513
dc.description.abstract [EN] Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(¿3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes. es_ES
dc.description.sponsorship The work has been supported by the European Union (ERC-2016-CoG 724681-S-CAGE) and the Spanish MINECO (CTQ 2014-59209-P, CTQ2017-89528-P and MAT2015-71842-P). We also thank the Spanish government for the provision of a Severo Ochoa project (SEV-2016-0683) and a Maria de Maeztu project (MDM-2015-0538). G.M.E. and M.S. thank MINECO for a Ramon y Cajal and a Juan de la Cierva-Formacion fellowships, respectively. We thank J. M. Martinez-Agudo, G. Agusti and J. Romero from the University of Valencia for their magnetic and cyclic voltammetry measurements. We thank the Diamond Light Source (UK) for the synchrotron beamtime. C2TN/IST authors acknowledge the Portuguese Foundation for Science and Technology (FCT), contract UID/Multi/04349/2013. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Chemical Science es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject MOF es_ES
dc.subject Highly stable es_ES
dc.subject Catalyst es_ES
dc.subject Tetrathiafulvalene es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title A highly stable and hierarchical tetrathiafulvalene-based metal organic framework with improved performance as a solid catalyst es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c7sc04829g es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/724681/EU/Smart Coordination Polymers with Compartmentalized Pockets for Adaptive Guest Entrance/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2014-59209-P/ES/POLIMEROS DE COORDINACION MAGNETICOS SENSIBLES A ESTIMULOS QUIMICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-89528-P/ES/MOFS Y MOLECULAS MAGNETICAS PARA ELECTRONICA Y TECNOLOGIA CUANTICA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/5876/147266/PT/Centre for Nuclear Sciences and Technologies/
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-71842-P/ES/SINTESIS Y CARACTERIZACION AVANZADA DE NUEVOS MATERIALES ZEOLITICOS Y APLICACIONES EN ADSORCION, MEDIOAMBIENTE Y EN LA CONSERVACION DE ALIMENTOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MDM-2015-0538/ES/INSTITUTO DE CIENCIA MOLECULAR/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Souto, M.; Santiago-Portillo, A.; Palomino Roca, M.; Vitorica-Yrezabal, IJ.; Vieira, BJC.; Waerenborgh, JC.; Valencia Valencia, S.... (2018). A highly stable and hierarchical tetrathiafulvalene-based metal organic framework with improved performance as a solid catalyst. Chemical Science. 9(9):2413-2418. https://doi.org/10.1039/c7sc04829g es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/c7sc04829g es_ES
dc.description.upvformatpinicio 2413 es_ES
dc.description.upvformatpfin 2418 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 9 es_ES
dc.description.issue 9 es_ES
dc.identifier.pmid 29732116 es_ES
dc.relation.pasarela S\354283 es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Fundação para a Ciência e a Tecnologia, Portugal es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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