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Towards the fluorogenic detection of peroxide explosives through host-guest chemistry

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Towards the fluorogenic detection of peroxide explosives through host-guest chemistry

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Nombre: Almenar;Costero;Gaviña ...
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dc.contributor.author Almenar, Estefanía es_ES
dc.contributor.author Costero, Ana M. es_ES
dc.contributor.author Gaviña, Pablo es_ES
dc.contributor.author Gil Grau, Salvador es_ES
dc.contributor.author Parra Álvarez, Margarita es_ES
dc.date.accessioned 2020-05-15T03:03:34Z
dc.date.available 2020-05-15T03:03:34Z
dc.date.issued 2018-04 es_ES
dc.identifier.uri http://hdl.handle.net/10251/143334
dc.description.abstract [EN] Two dansyl-modified beta-cyclodextrin derivatives (1 and 2) have been synthesized as host-guest sensory systems for the direct fluorescent detection of the peroxide explosives diacetone diperoxide (DADP) and triacetone triperoxide (TATP) in aqueous media. The sensing is based on the displacement of the dansyl moiety from the cavity of the cyclodextrin by the peroxide guest resulting in a decrease of the intensity of the fluorescence of the dye. Both systems showed similar fluorescent responses and were more sensitive towards TATP than DADP. es_ES
dc.description.sponsorship We thank the Spanish Government (MAT2015-64139-C4-4-R) and Generalitat Valenciana (PROMETEOII/2014/047) for financial support. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society es_ES
dc.relation.ispartof Royal Society Open Science es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Peroxide explosives es_ES
dc.subject Fluorescent sensors es_ES
dc.subject Cyclodextrins es_ES
dc.subject Host-guest chemistry es_ES
dc.title Towards the fluorogenic detection of peroxide explosives through host-guest chemistry es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1098/rsos.171787 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-64139-C4-4-R/ES/QUIMIOSENSORES CROMOGENICOS Y FLUOROGENICOS PARA LA DETECCION DE NEUROTRASMISORES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEOII%2F2014%2F047/ES/Nuevas aproximaciones para el diseño de materiales de liberación controlada y la detección de compuestos peligrosos/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic es_ES
dc.description.bibliographicCitation Almenar, E.; Costero, AM.; Gaviña, P.; Gil Grau, S.; Parra Álvarez, M. (2018). Towards the fluorogenic detection of peroxide explosives through host-guest chemistry. Royal Society Open Science. 5(4). https://doi.org/10.1098/rsos.171787 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1098/rsos.171787 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 5 es_ES
dc.description.issue 4 es_ES
dc.identifier.eissn 2054-5703 es_ES
dc.identifier.pmid 29765646 es_ES
dc.identifier.pmcid PMC5936911 es_ES
dc.relation.pasarela S\374121 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.description.references Dubnikova, F., Kosloff, R., Almog, J., Zeiri, Y., Boese, R., Itzhaky, H., … Keinan, E. (2005). Decomposition of Triacetone Triperoxide Is an Entropic Explosion. Journal of the American Chemical Society, 127(4), 1146-1159. doi:10.1021/ja0464903 es_ES
dc.description.references Fitzgerald, M., & Bilusich, D. (2011). Sulfuric, Hydrochloric, and Nitric Acid-Catalyzed Triacetone Triperoxide (TATP) Reaction Mixtures: An Aging Study. Journal of Forensic Sciences, 56(5), 1143-1149. doi:10.1111/j.1556-4029.2011.01806.x es_ES
dc.description.references Matyáš, R., Pachman, J., & Ang, H.-G. (2009). Study of TATP: Spontaneous Transformation of TATP to DADP - Full Paper. Propellants, Explosives, Pyrotechnics, 34(6), 484-488. doi:10.1002/prep.200800043 es_ES
dc.description.references Matyas, R., Pachman, J., & Ang, H.-G. (2008). Study of TATP: Spontaneous Transformation of TATP to DADP. Propellants, Explosives, Pyrotechnics, 33(2), 89-91. doi:10.1002/prep.200700247 es_ES
dc.description.references Wang, J. (2007). Electrochemical Sensing of Explosives. Electroanalysis, 19(4), 415-423. doi:10.1002/elan.200603748 es_ES
dc.description.references Bauer, C., Willer, U., Lewicki, R., Pohlkötter, A., Kosterev, A., Kosynkin, D., … Schade, W. (2009). A Mid-infrared QEPAS sensor device for TATP detection. Journal of Physics: Conference Series, 157, 012002. doi:10.1088/1742-6596/157/1/012002 es_ES
dc.description.references Widmer, L., Watson, S., Schlatter, K., & Crowson, A. (2002). Development of an LC/MS method for the trace analysis of triacetone triperoxide (TATP). The Analyst, 127(12), 1627-1632. doi:10.1039/b208350g es_ES
dc.description.references Zhang, Y., Ma, X., Zhang, S., Yang, C., Ouyang, Z., & Zhang, X. (2009). Direct detection of explosives on solid surfaces by low temperature plasma desorption mass spectrometry. The Analyst, 134(1), 176-181. doi:10.1039/b816230a es_ES
dc.description.references Girotti, S., Ferri, E., Maiolini, E., Bolelli, L., D’Elia, M., Coppe, D., & Romolo, F. S. (2011). A quantitative chemiluminescent assay for analysis of peroxide-based explosives. Analytical and Bioanalytical Chemistry, 400(2), 313-320. doi:10.1007/s00216-010-4626-3 es_ES
dc.description.references Walter, M. A., Panne, U., & Weller, M. G. (2011). A Novel Immunoreagent for the Specific and Sensitive Detection of the Explosive Triacetone Triperoxide (TATP). Biosensors, 1(3), 93-106. doi:10.3390/bios1030093 es_ES
dc.description.references Sella, E., & Shabat, D. (2008). Self-immolative dendritic probe for direct detection of triacetone triperoxide. Chemical Communications, (44), 5701. doi:10.1039/b814855d es_ES
dc.description.references Germain, M. E., & Knapp, M. J. (2008). Turn-on Fluorescence Detection of H2O2and TATP. Inorganic Chemistry, 47(21), 9748-9750. doi:10.1021/ic801317x es_ES
dc.description.references Lin, H., & Suslick, K. S. (2010). A Colorimetric Sensor Array for Detection of Triacetone Triperoxide Vapor. Journal of the American Chemical Society, 132(44), 15519-15521. doi:10.1021/ja107419t es_ES
dc.description.references Li, Z., Bassett, W. P., Askim, J. R., & Suslick, K. S. (2015). Differentiation among peroxide explosives with an optoelectronic nose. Chemical Communications, 51(83), 15312-15315. doi:10.1039/c5cc06221g es_ES
dc.description.references Askim, J. R., Li, Z., LaGasse, M. K., Rankin, J. M., & Suslick, K. S. (2016). An optoelectronic nose for identification of explosives. Chemical Science, 7(1), 199-206. doi:10.1039/c5sc02632f es_ES
dc.description.references Ueno, A., Minato, S., Suzuki, I., Fukushima, M., Ohkubo, M., Osa, T., … Murai, K. (1990). Host–Guest Sensory System of Dansyl-Modifled β-Cyclodextrin for Detecting Steroidal Compounds by Dansyl Fluorescence. Chemistry Letters, 19(4), 605-608. doi:10.1246/cl.1990.605 es_ES
dc.description.references Hamasaki, K., Ikeda, H., Nakamura, A., Ueno, A., Toda, F., Suzuki, I., & Osa, T. (1993). Fluorescent sensors of molecular recognition. Modified cyclodextrins capable of exhibiting guest-responsive twisted intramolecular charge transfer fluorescence. Journal of the American Chemical Society, 115(12), 5035-5040. doi:10.1021/ja00065a012 es_ES
dc.description.references Ikeda, H., Nakamura, M., Ise, N., Oguma, N., Nakamura, A., Ikeda, T., … Ueno, A. (1996). Fluorescent Cyclodextrins for Molecule Sensing:  Fluorescent Properties, NMR Characterization, and Inclusion Phenomena ofN-Dansylleucine-Modified Cyclodextrins. Journal of the American Chemical Society, 118(45), 10980-10988. doi:10.1021/ja960183i es_ES
dc.description.references Ueno, A., Kuwabara, T., Nakamura, A., & Toda, F. (1992). A modified cyclodextrin as a guest responsive colour-change indicator. Nature, 356(6365), 136-137. doi:10.1038/356136a0 es_ES
dc.description.references Ogoshi, T., & Harada, A. (2008). Chemical Sensors Based on Cyclodextrin Derivatives. Sensors, 8(8), 4961-4982. doi:10.3390/s8084961 es_ES
dc.description.references 6A-O-p-TOLUENESULFONYL-b-CYCLODEXTRIN. (2000). Organic Syntheses, 77, 225. doi:10.15227/orgsyn.077.0225 es_ES
dc.description.references Tang, W., & Ng, S.-C. (2008). Facile synthesis of mono-6-amino-6-deoxy-α-, β-, γ-cyclodextrin hydrochlorides for molecular recognition, chiral separation and drug delivery. Nature Protocols, 3(4), 691-697. doi:10.1038/nprot.2008.37 es_ES
dc.description.references Mourer, M., Hapiot, F., Monflier, E., & Menuel, S. (2008). Click chemistry as an efficient tool to access β-cyclodextrin dimers. Tetrahedron, 64(30-31), 7159-7163. doi:10.1016/j.tet.2008.05.095 es_ES
dc.description.references Eaton, D. F. (1988). Reference materials for fluorescence measurement. Pure and Applied Chemistry, 60(7), 1107-1114. doi:10.1351/pac198860071107 es_ES


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