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A Combination of Visible-Light Organophotoredox Catalysis and Asymmetric Organocatalysis for the Enantioselective Mannich Reaction of Dihydroquinoxalinones with Ketones

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A Combination of Visible-Light Organophotoredox Catalysis and Asymmetric Organocatalysis for the Enantioselective Mannich Reaction of Dihydroquinoxalinones with Ketones

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Rostoll-Berenguer, J.; Blay, G.; Muñoz Roca, MDC.; Pedro, J.; Vila, C. (2019). A Combination of Visible-Light Organophotoredox Catalysis and Asymmetric Organocatalysis for the Enantioselective Mannich Reaction of Dihydroquinoxalinones with Ketones. Organic Letters. 21(15):6011-6015. https://doi.org/10.1021/acs.orglett.9b02157

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/144829

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Title: A Combination of Visible-Light Organophotoredox Catalysis and Asymmetric Organocatalysis for the Enantioselective Mannich Reaction of Dihydroquinoxalinones with Ketones
Author: Rostoll-Berenguer, J. Blay, G. Muñoz Roca, María Del Carmen Pedro, J.R. Vila, C.
UPV Unit: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Issued date:
Abstract:
[EN] An enantioselective photooxidative Mannich reaction of dihydroquinoxalinones with ketones by the merger of organophotoredox and asymmetric organocatalysis is described. This protocol features very mild reaction ...[+]
Subjects: Photoredox catalysis , Tertiary-Amines , Acid , Functionalization , Efficient , Hydrogenation , Methodology , Activation , Alkylation , Complexes
Copyrigths: Cerrado
Source:
Organic Letters. (issn: 1523-7060 )
DOI: 10.1021/acs.orglett.9b02157
Publisher:
American Chemical Society
Publisher version: https://doi.org/10.1021/acs.orglett.9b02157
Project ID:
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-84900-P/ES/REACCIONES DE ADICION ENANTIOSELECTIVAS MEDIANTE SISTEMAS MULTICATALITICOS. HERRAMIENTAS PARA LA SINTESIS EFICIENTE DE MOLECULAS CON ACTIVIDAD FARMACOLOGICA/
info:eu-repo/grantAgreement/MICINN//RYC-2016-20187
Thanks:
Financial support from the Agencia Estatal de Investigation (AEI, Spanish Government) and Fondo Europeo de Desarrollo Regional (FEDER, European Union) (CTQ2017-84900-P) is acknowledged. J.R.-B. thanks the Ministerio de ...[+]
Type: Artículo

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