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A new efficient, highly dispersed, Pd nanoparticulate silica supported catalyst synthesized from an organometallic precursor. Study of the homogeneous vs. heterogeneous activity in the Suzuki-Miyaura reaction

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A new efficient, highly dispersed, Pd nanoparticulate silica supported catalyst synthesized from an organometallic precursor. Study of the homogeneous vs. heterogeneous activity in the Suzuki-Miyaura reaction

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Alfonso Albiñana, P.; El Haskouri, J.; Marcos Martínez, MD.; Estevan, F.; Amorós Del Toro, P.; Úbeda, MÁ.; Pérez-Pla, F. (2018). A new efficient, highly dispersed, Pd nanoparticulate silica supported catalyst synthesized from an organometallic precursor. Study of the homogeneous vs. heterogeneous activity in the Suzuki-Miyaura reaction. Journal of Catalysis. 367:283-295. https://doi.org/10.1016/j.jcat.2018.09.014

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/145119

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Title: A new efficient, highly dispersed, Pd nanoparticulate silica supported catalyst synthesized from an organometallic precursor. Study of the homogeneous vs. heterogeneous activity in the Suzuki-Miyaura reaction
Author:
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] A new Pd(0) catalyst supported on silica UVM-7 has been synthesized from the organometallic [Pd-2(mu-(C6H4) Pp(2))(2)(CH3CN)(4)](BF4)(2) precursor, characterized by the high dispersion, activity, and small size of the ...[+]
Subjects: Suzuki-Miyaura , Palladium nanoparticles , UVM-7 silica , Heterogeneous homogeneous catalysis , Kinetic study , STEM-HAADF , HRTEM, XRD
Copyrigths: Cerrado
Source:
Journal of Catalysis. (issn: 0021-9517 )
DOI: 10.1016/j.jcat.2018.09.014
Publisher:
Elsevier
Publisher version: https://doi.org/10.1016/j.jcat.2018.09.014
Thanks:
We thank the Spanish Ministerio de Economía y Competitividad and European Feder Funds (MAT2015-64139-C4-2-R) for funding this research.
Type: Artículo

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