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Crystallization kinetics of poly(ethylene oxide) confined in semicrystalline poly(vinylidene) fluoride

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Crystallization kinetics of poly(ethylene oxide) confined in semicrystalline poly(vinylidene) fluoride

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dc.contributor.author Tamaño-Machiavello, María Noel es_ES
dc.contributor.author Costa, C.M. es_ES
dc.contributor.author Romero Colomer, Francisco José es_ES
dc.contributor.author Meseguer Dueñas, José María es_ES
dc.contributor.author Lanceros-Méndez, S. es_ES
dc.contributor.author Gómez Ribelles, José Luís es_ES
dc.date.accessioned 2020-07-09T03:32:13Z
dc.date.available 2020-07-09T03:32:13Z
dc.date.issued 2018 es_ES
dc.identifier.issn 0887-6266 es_ES
dc.identifier.uri http://hdl.handle.net/10251/147685
dc.description.abstract [EN] Polymer blends based on poly(vinylidene fluoride) (PVDF) and poly(ethylene oxide) (PEO) have been prepared to analyze the crystallization kinetics of poly(ethylene oxide) confined in semicrystalline PVDF with different ratios of both polymers. Both blend components were dissolved in a common solvent, dimethyl formamide. Blend films were obtained by casting from the solution at 70 degrees C. Thus, PVDF crystals are formed by crystallization from the solution while PEO (which is in the liquid state during the whole process) is confined between PVDF crystallites. The kinetics of crystallization of the confined PEO phase was studied by isothermal and nonisothermal experiments. Fitting of Avrami model to the experimental DSC traces allows a quantitative comparison of the influence of the PVDF/PEO ratio in the blend on the crystallization behavior. The effect of melting and further recrystallization of the PVDF matrix on PEO confinement is also studied. (c) 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018, 56, 588-597 es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Journal of Polymer Science Part B Polymer Physics es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Confinement es_ES
dc.subject Crystallization es_ES
dc.subject Electroactive polymers es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.subject.classification MAQUINAS Y MOTORES TERMICOS es_ES
dc.title Crystallization kinetics of poly(ethylene oxide) confined in semicrystalline poly(vinylidene) fluoride es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/polb.24564 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/5876/147414/PT/Physics Center of Minho and Porto Universities/
dc.relation.projectID info:eu-repo/grantAgreement/FCT/SFRH/FCT%2FSFRH%2FBPD%2F112547%2F2015/PT/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2016-76039-C4-1-R/ES/BIOMATERIALES PIEZOELECTRICOS PARA LA DIFERENCIACION CELULAR EN INTERFASES CELULA-MATERIAL ELECTRICAMENTE ACTIVAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2016-76039-C4-3-R/ES/UNA NUEVA GENERACION DE MATERIALES ELECTROACTIVOS Y BIOREACTORES PARA INGENIERIA DE TEJIDO MUSCULAR/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada es_ES
dc.description.bibliographicCitation Tamaño-Machiavello, MN.; Costa, C.; Romero Colomer, FJ.; Meseguer Dueñas, JM.; Lanceros-Méndez, S.; Gómez Ribelles, JL. (2018). Crystallization kinetics of poly(ethylene oxide) confined in semicrystalline poly(vinylidene) fluoride. Journal of Polymer Science Part B Polymer Physics. 56(7):588-597. https://doi.org/10.1002/polb.24564 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1002/polb.24564 es_ES
dc.description.upvformatpinicio 588 es_ES
dc.description.upvformatpfin 597 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 56 es_ES
dc.description.issue 7 es_ES
dc.relation.pasarela S\380392 es_ES
dc.contributor.funder Instituto de Salud Carlos III es_ES
dc.contributor.funder Gobierno Vasco/Eusko Jaurlaritza es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Fundação para a Ciência e a Tecnologia, Portugal es_ES
dc.contributor.funder Centro de Investigación Biomédica en Red en Bioingeniería, Biomateriales y Nanomedicina es_ES
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