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Enantioselective Synthesis of 5-Trifluoromethyl-2-oxazolines under Dual Silver/Organocatalysis

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Enantioselective Synthesis of 5-Trifluoromethyl-2-oxazolines under Dual Silver/Organocatalysis

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Martinez-Pardo, P.; Blay, G.; Vila, C.; Sanz-Marco, A.; Muñoz Roca, MDC.; Pedro, JR. (2019). Enantioselective Synthesis of 5-Trifluoromethyl-2-oxazolines under Dual Silver/Organocatalysis. The Journal of Organic Chemistry. 84(1):314-325. https://doi.org/10.1021/acs.joc.8b02808

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Title: Enantioselective Synthesis of 5-Trifluoromethyl-2-oxazolines under Dual Silver/Organocatalysis
Author: Martinez-Pardo, Pablo Blay, Gonzalo Vila, Carlos Sanz-Marco, Amparo Muñoz Roca, María Del Carmen Pedro, Jose R.
UPV Unit: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Issued date:
Abstract:
[EN] The first enantioselective formal [3 + 2] cycloaddition between ¿-isocyanoesters and trifluoromethylketones to give 5-trifluoromethyl-2-oxazolines bearing two contiguous stereogenic centers, one of them being a ...[+]
Copyrigths: Reserva de todos los derechos
Source:
The Journal of Organic Chemistry. (issn: 0022-3263 )
DOI: 10.1021/acs.joc.8b02808
Publisher:
American Chemical Society
Publisher version: https://doi.org/10.1021/acs.joc.8b02808
Project ID:
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-84900-P/ES/REACCIONES DE ADICION ENANTIOSELECTIVAS MEDIANTE SISTEMAS MULTICATALITICOS. HERRAMIENTAS PARA LA SINTESIS EFICIENTE DE MOLECULAS CON ACTIVIDAD FARMACOLOGICA/
info:eu-repo/grantAgreement/MINECO//RYC-2016-20187/
info:eu-repo/grantAgreement/GVA//APOSTD%2F2016%2F139/
Thanks:
Financial support from the MINECO and FEDER (CTQ2017-84900-P). Access to NMR and MS facilities from SCSIE-UV. C.V. thanks the Spanish Government for a Ramon y Cajal contract (RyC-2016-20187). A.S.-M. thanks the Generalitat ...[+]
Type: Artículo

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