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Capped Mesoporous Silica Nanoparticles for the Selective and Sensitive Detection of Cyanide

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Capped Mesoporous Silica Nanoparticles for the Selective and Sensitive Detection of Cyanide

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dc.contributor.author El Sayed, Sameh es_ES
dc.contributor.author Licchelli, Maurizio es_ES
dc.contributor.author Martínez-Máñez, Ramón es_ES
dc.contributor.author Sancenón Galarza, Félix es_ES
dc.date.accessioned 2020-07-23T03:31:19Z
dc.date.available 2020-07-23T03:31:19Z
dc.date.issued 2017-10-18 es_ES
dc.identifier.issn 1861-4728 es_ES
dc.identifier.uri http://hdl.handle.net/10251/148521
dc.description.abstract [EN] The development of easy and affordable methods for the detection of cyanide is of great significance due to the high toxicity of this anion and the potential risks associated with its pollution. Herein, optical detection of cyanide in water has been achieved by using a hybrid organic-inorganic nanomaterial. Mesoporous silica nanoparticles were loaded with [Ru(bipy)(3)](2+), functionalized with macrocyclic nickel(II) complex subunits, and capped with a sterically hindering anion (hexametaphosphate). Cyanide selectively induces demetallation of nickel(II) complexes and the removal of capping anions from the silica surface, allowing the release of the dye and the consequent increase in fluorescence intensity. The response of the capped nanoparticles in aqueous solution is highly selective and sensitive towards cyanide with a limit of detection of 2 mu M. es_ES
dc.description.sponsorship We thank the Spanish Government (projects MAT2015-64139-C4-1-R and AGL2015-70235-C2-2-R (MINECO/FEDER, UE)) and the Generalitat Valenciana (project PROMETEOII/2014/047) for support. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Chemistry - An Asian Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Cyanides es_ES
dc.subject Hybrid materials es_ES
dc.subject Macrocyclic ligands es_ES
dc.subject Mesoporous silica nanoparticles es_ES
dc.subject Optical detection es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.title Capped Mesoporous Silica Nanoparticles for the Selective and Sensitive Detection of Cyanide es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/asia.201701130 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-64139-C4-1-R/ES/NANOMATERIALES INTELIGENTES, SONDAS Y DISPOSITIVOS PARA EL DESARROLLO INTEGRADO DE NUEVAS HERRAMIENTAS APLICADAS AL CAMPO BIOMEDICO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEOII%2F2014%2F047/ES/Nuevas aproximaciones para el diseño de materiales de liberación controlada y la detección de compuestos peligrosos/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//AGL2015-70235-C2-2-R/ES/DESARROLLO DE SISTEMAS HIBRIDOS CON OPTIMIZACION DEL ANCLADO DE BIOMOLECULAS Y DISEÑADOS CON PROPIEDADES DE ENCAPSULACION Y LIBERACION CONTROLADA MEJORADAS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation El Sayed, S.; Licchelli, M.; Martínez-Máñez, R.; Sancenón Galarza, F. (2017). Capped Mesoporous Silica Nanoparticles for the Selective and Sensitive Detection of Cyanide. Chemistry - An Asian Journal. 12(20):2670-2674. https://doi.org/10.1002/asia.201701130 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/asia.201701130 es_ES
dc.description.upvformatpinicio 2670 es_ES
dc.description.upvformatpfin 2674 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 20 es_ES
dc.identifier.pmid 28941199 es_ES
dc.relation.pasarela S\350014 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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