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N-Doped graphene as a metal-free catalyst for glucose oxidation to succinic acid

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N-Doped graphene as a metal-free catalyst for glucose oxidation to succinic acid

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dc.contributor.author Rizescu, Cristina es_ES
dc.contributor.author Podolean, Iunia es_ES
dc.contributor.author Albero-Sancho, Josep es_ES
dc.contributor.author Parvulescu, Vasile I. es_ES
dc.contributor.author Coman, Simona M. es_ES
dc.contributor.author Bucur, Cristina es_ES
dc.contributor.author Puche Panadero, Marta es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2020-07-30T03:35:00Z
dc.date.available 2020-07-30T03:35:00Z
dc.date.issued 2017-04-21 es_ES
dc.identifier.issn 1463-9262 es_ES
dc.identifier.uri http://hdl.handle.net/10251/148890
dc.description.abstract [EN] N-Containing graphenes obtained either by simultaneous amination and reduction of graphene oxide or by pyrolysis of chitosan under an inert atmosphere have been found to act as catalysts for the selective wet oxidation of glucose to succinic acid. Selectivity values over 60% at complete glucose conversion have been achieved by performing the reaction at 160 degrees C and 18 atm O-2 pressure for 20 h. This activity has been attributed to graphenic-type N atoms on graphene. The active N-containing graphene catalysts were used four times without observing a decrease in conversion and selectivity of the process. A mechanism having tartaric and fumaric acids as key intermediates is proposed. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa, Grapas and CTQ2015-69153-CO2-R1) and Generalitat Valenciana (Prometeo 2013-014) is gratefully acknowledged. Prof. Simona M. Coman kindly acknowledges UEFISCDI for financial support (project PN-II-PT-PCCA-2013-4-1090, Nr. 44/2014). Cristina Bucur acknowledges Core Programme, Project PN-480103/2016. es_ES
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation.ispartof Green Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Wet oxidation es_ES
dc.subject Wheat-Straw es_ES
dc.subject Renewable chemicals es_ES
dc.subject Oxide es_ES
dc.subject Biomass es_ES
dc.subject Carbocatalysis es_ES
dc.subject Hydrocarbons es_ES
dc.subject Pretreatment es_ES
dc.subject Activation es_ES
dc.subject Persulfate es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title N-Doped graphene as a metal-free catalyst for glucose oxidation to succinic acid es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/C7GC00473G es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-69153-C2-1-R/ES/EXPLOTANDO EL USO DEL GRAFENO EN CATALISIS. USO DEL GRAFENO COMO CARBOCATALIZADOR O COMO SOPORTE/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/NIMP//PN-480103%2F2016/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UEFISCDI//PN-II-PT-PCCA-2013-4-1090 44%2F2014/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2013%2F014/ES/SINTESIS DE GRAFENO Y DERIVADOS COMO SENSORES O CON PROPIEDADES OPTOELECTRONICAS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Rizescu, C.; Podolean, I.; Albero-Sancho, J.; Parvulescu, VI.; Coman, SM.; Bucur, C.; Puche Panadero, M.... (2017). N-Doped graphene as a metal-free catalyst for glucose oxidation to succinic acid. Green Chemistry. 19(8):1999-2005. https://doi.org/10.1039/C7GC00473G es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1039/C7GC00473G es_ES
dc.description.upvformatpinicio 1999 es_ES
dc.description.upvformatpfin 2005 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 19 es_ES
dc.description.issue 8 es_ES
dc.relation.pasarela S\355406 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder National Institute of Materials Physics, Rumanía es_ES
dc.contributor.funder Ministerio de Economía, Industria y Competitividad es_ES
dc.contributor.funder Executive Agency for Higher Education, Scientific Research, Development and Innovation Funding, Rumanía es_ES
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