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Control of zeolite framework flexibility and pore topology for separation of ethane and ethylene

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Control of zeolite framework flexibility and pore topology for separation of ethane and ethylene

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dc.contributor.author Bereciartua-Pérez, Pablo Javier es_ES
dc.contributor.author Cantin Sanz, Angel es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author Jorda Moret, Jose Luis es_ES
dc.contributor.author Palomino Roca, Miguel es_ES
dc.contributor.author Rey Garcia, Fernando es_ES
dc.contributor.author Valencia Valencia, Susana es_ES
dc.contributor.author Corcoran Jr., Edward W. es_ES
dc.contributor.author Kortunov, Pavel es_ES
dc.contributor.author Ravikovitch, Peter I. es_ES
dc.contributor.author Burton, Allen es_ES
dc.contributor.author Yoon, Chris es_ES
dc.contributor.author Wang, Yu es_ES
dc.contributor.author Paur, Charanjit es_ES
dc.contributor.author Guzman, Javier es_ES
dc.contributor.author Bishop, Adeana R. es_ES
dc.contributor.author Casty, Gary L. es_ES
dc.date.accessioned 2020-09-08T03:32:03Z
dc.date.available 2020-09-08T03:32:03Z
dc.date.issued 2017-11-24 es_ES
dc.identifier.issn 0036-8075 es_ES
dc.identifier.uri http://hdl.handle.net/10251/149541
dc.description.abstract [EN] The discovery of new materials for separating ethylene from ethane by adsorption, instead of using cryogenic distillation, is a key milestone for molecular separations because of the multiple and widely extended uses of these molecules in industry. This technique has the potential to provide tremendous energy savings when compared with the currently used cryogenic distillation process for ethylene produced through steam cracking. Here we describe the synthesis and structural determination of a flexible pure silica zeolite (ITQ-55). This material can kinetically separate ethylene from ethane with an unprecedented selectivity of ~100, owing to its distinctive pore topology with large heart-shaped cages and framework flexibility. Control of such properties extends the boundaries for applicability of zeolites to challenging separations. es_ES
dc.description.sponsorship We gratefully acknowledge financial support from ExxonMobil Research and Engineering Company, Instituto de Tecnologia Quimica researchers also thank the European Research Council (grant ERC-2014-AdG-671093 "MATching zeolite SYNthiesis with CATalytic activity") and the Spanish government (grants MAT2015-71842-P MINECO/FEDER and Severe Ochea SEV-2012-0267 and SEV-2016-0683) for economic support es_ES
dc.language Inglés es_ES
dc.publisher American Association for the Advancement of Science (AAAS) es_ES
dc.relation.ispartof Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Adsorption es_ES
dc.subject Ethylene es_ES
dc.subject Ethane es_ES
dc.subject Zeolite es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Control of zeolite framework flexibility and pore topology for separation of ethane and ethylene es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1126/science.aao0092 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-71842-P/ES/SINTESIS Y CARACTERIZACION AVANZADA DE NUEVOS MATERIALES ZEOLITICOS Y APLICACIONES EN ADSORCION, MEDIOAMBIENTE Y EN LA CONSERVACION DE ALIMENTOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Bereciartua-Pérez, PJ.; Cantin Sanz, A.; Corma Canós, A.; Jorda Moret, JL.; Palomino Roca, M.; Rey Garcia, F.; Valencia Valencia, S.... (2017). Control of zeolite framework flexibility and pore topology for separation of ethane and ethylene. Science. 358(6366):1068-1071. https://doi.org/10.1126/science.aao0092 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1126/science.aao0092 es_ES
dc.description.upvformatpinicio 1068 es_ES
dc.description.upvformatpfin 1071 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 358 es_ES
dc.description.issue 6366 es_ES
dc.identifier.pmid 29170235 es_ES
dc.relation.pasarela S\348494 es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder ExxonMobil Research and Engineering Company es_ES
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