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Elemental Composition of Natural Nanoparticles and Fine Colloids in European Forest Stream Waters and Their Role as Phosphorus Carriers

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Elemental Composition of Natural Nanoparticles and Fine Colloids in European Forest Stream Waters and Their Role as Phosphorus Carriers

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dc.contributor.author Gottselig, N. es_ES
dc.contributor.author Amelung, W. es_ES
dc.contributor.author Kirchner, J.W. es_ES
dc.contributor.author Bol, R. es_ES
dc.contributor.author Eugster, W. es_ES
dc.contributor.author Granger, S.J. es_ES
dc.contributor.author Hernández Crespo, Carmen es_ES
dc.contributor.author Herrmann, F. es_ES
dc.contributor.author Keizer, J.J. es_ES
dc.contributor.author Korkiakoski, M. es_ES
dc.contributor.author Laudon, H. es_ES
dc.contributor.author Lehner, I. es_ES
dc.contributor.author Löfgren, S. es_ES
dc.contributor.author Lohila, A. es_ES
dc.contributor.author Macleod, C.J.A. es_ES
dc.date.accessioned 2020-09-12T03:35:18Z
dc.date.available 2020-09-12T03:35:18Z
dc.date.issued 2017-10 es_ES
dc.identifier.issn 0886-6236 es_ES
dc.identifier.uri http://hdl.handle.net/10251/149961
dc.description "This is the peer reviewed version of the following article: Gottselig, N., W. Amelung, J. W. Kirchner, R. Bol, W. Eugster, S. J. Granger, C. Hernández-Crespo, et al. 2017. Elemental Composition of Natural Nanoparticles and Fine Colloids in European Forest Stream Waters and Their Role as Phosphorus Carriers. Global Biogeochemical Cycles 31 (10). American Geophysical Union (AGU): 1592 1607. doi:10.1002/2017gb005657, which has been published in final form at https://doi.org/10.1002/2017GB005657. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving." es_ES
dc.description.abstract [EN] Biogeochemical cycling of elements largely occurs in dissolved state, but many elements may also be bound to natural nanoparticles (NNP, 1-100 nm) and fine colloids (100-450 nm). We examined the hypothesis that the size and composition of stream water NNP and colloids vary systematically across Europe. To test this hypothesis, 96 stream water samples were simultaneously collected in 26 forested headwater catchments along two transects across Europe. Three size fractions (similar to 1-20 nm, >20-60 nm, and >60 nm) of NNP and fine colloids were identified with Field Flow Fractionation coupled to inductively coupled plasma mass spectrometry and an organic carbon detector. The results showed that NNP and fine colloids constituted between 2 +/- 5% (Si) and 53 +/- 21% (Fe; mean +/- SD) of total element concentrations, indicating a substantial contribution of particles to element transport in these European streams, especially for P and Fe. The particulate contents of Fe, Al, and organic C were correlated to their total element concentrations, but those of particulate Si, Mn, P, and Ca were not. The fine colloidal fractions >60 nm were dominated by clay minerals across all sites. The resulting element patterns of NNP <60 nm changed from North to South Europe from Fe-to Ca-dominated particles, along with associated changes in acidity, forest type, and dominant lithology. es_ES
dc.description.sponsorship The authors gratefully acknowledge the assistance of the following people in locating suitable sampling sites, contacting site operators, performing the sampling, and providing data: A. Avila Castells (Autonomous University of Barcelona), R. Batalla (University of Lleida), P. Blomkvist (Swedish University of Agricultural Sciences), H. Bogena (Julich Research Center), A.K. Boulet (University of Aveiro), D. Estany (University of Lleida), F. Garnier (French National Institute of Agricultural Research), H.J. Hendricks-Franssen (Research Center Julich), L. JacksonBlake (James Hutton Institute, NIVA), T. Laurila (Finnish Meteorological Institute), A. Lindroth (Lund University), M.M. Monerris (Universitat Politecnica de Valencia), M. Ottosson Lofvenius (Swedish University of Agricultural Sciences), I. Taberman (Swedish University of Agricultural Sciences), F. Wendland (Research Center Julich), T. Zetterberg (Swedish University of Agricultural Sciences and The Swedish Environmental Research Institute, IVL) and further unnamed contributors. The Swedish Infrastructure for Ecosystem Science (SITES) and the Swedish Integrated Monitoring, the latter financed by the Swedish Environmental Protection Agency, and ICOS Sweden have supported sampling and provided data for the Swedish sites. J.J.K. gratefully acknowledges the support from CESAM (UID/AMB/50017/2013), funded by the FCT/MCTES (PIDDAC) with cofunding by FEDER through COMPETE. N.G. gratefully acknowledges all those who contributed to organizing and implementing the continental sampling. The raw data can be found at http://hdl.handle.net/2128/14937. This project was partly funded by the German Research Foundation (DFG KL2495/1-1). es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Global Biogeochemical Cycles es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Field-Flow fractionation es_ES
dc.subject Dissolved organic-matter es_ES
dc.subject Iron-Rich colloids es_ES
dc.subject River systems es_ES
dc.subject Trace-Metals es_ES
dc.subject Land-Use es_ES
dc.subject Soil es_ES
dc.subject Particles es_ES
dc.subject Transport es_ES
dc.subject Separation es_ES
dc.subject.classification TECNOLOGIA DEL MEDIO AMBIENTE es_ES
dc.title Elemental Composition of Natural Nanoparticles and Fine Colloids in European Forest Stream Waters and Their Role as Phosphorus Carriers es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/2017GB005657 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/FCT/5876/147273/PT/Centre for Environmental and Marine Studies/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/DFG//KL2495%2F1-1/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario de Ingeniería del Agua y del Medio Ambiente - Institut Universitari d'Enginyeria de l'Aigua i Medi Ambient es_ES
dc.description.bibliographicCitation Gottselig, N.; Amelung, W.; Kirchner, J.; Bol, R.; Eugster, W.; Granger, S.; Hernández Crespo, C.... (2017). Elemental Composition of Natural Nanoparticles and Fine Colloids in European Forest Stream Waters and Their Role as Phosphorus Carriers. Global Biogeochemical Cycles. 31(10):1592-1607. https://doi.org/10.1002/2017GB005657 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/2017GB005657 es_ES
dc.description.upvformatpinicio 1592 es_ES
dc.description.upvformatpfin 1607 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 31 es_ES
dc.description.issue 10 es_ES
dc.relation.pasarela S\360050 es_ES
dc.contributor.funder Swedish Environmental Protection Agency es_ES
dc.contributor.funder Deutsche Forschungsgemeinschaft es_ES
dc.contributor.funder European Regional Development Fund es_ES
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