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Nickel nanoparticles supported on graphene as catalysts for aldehyde hydrosilylation

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Nickel nanoparticles supported on graphene as catalysts for aldehyde hydrosilylation

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Nombre: Blandez;Esteve-Ad ...
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dc.contributor.author Blandez, Juan F. es_ES
dc.contributor.author Esteve-Adell, Iván es_ES
dc.contributor.author Primo Arnau, Ana Maria es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2020-09-15T03:32:06Z
dc.date.available 2020-09-15T03:32:06Z
dc.date.issued 2016-01 es_ES
dc.identifier.issn 1381-1169 es_ES
dc.identifier.uri http://hdl.handle.net/10251/150037
dc.description.abstract [EN] Nickel nanoparticles (NPs) supported on different undoped or doped with N or B graphenes (Gs) have been tested as catalyst for the hydrosilylation of aldehydes to obtain the corresponding siloxanes with high conversion and good selectivity in short reaction time. The different Gs employed were obtained by pyrolysis under inert atmosphere of alginate or chitosan, modified or not with boric acid. Then the metal NPs obtained by polyol reduction method using ethylene glycol were adsorbed on Gs. The Ni-containing G catalysts were characterized by electron microscopy, XPS and Raman spectroscopy. The scope of the Ni/G catalyst includes aliphatic and aromatic aldehydes as well as a variety of hydrosilanes. (C) 2015 Elsevier B.V. All rights reserved. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and CTQ2012-32315) and Generalitat Valenciana (Prometeo 2013-019) in gratefully acknowledged. J.F.B. and I.E.A. thanks to the Technical University of Valencia and the Spanish Ministry of Economy and Competitiveness for postgraduate scholarships, respectively. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Journal of Molecular Catalysis A Chemical es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject Nickel nanoparticles es_ES
dc.subject Graphene as support es_ES
dc.subject Aldehyde hydrosilylation es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Nickel nanoparticles supported on graphene as catalysts for aldehyde hydrosilylation es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.molcata.2015.11.011 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2013%2F019/ES/HUMBACE: HUMAN-LIKE COMPUTATIONAL MODELS FOR AGENT-BASED COMPUTATIONAL ECONOMICS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología Eléctrica - Institut de Tecnologia Elèctrica es_ES
dc.description.bibliographicCitation Blandez, JF.; Esteve-Adell, I.; Primo Arnau, AM.; Alvaro Rodríguez, MM.; García Gómez, H. (2016). Nickel nanoparticles supported on graphene as catalysts for aldehyde hydrosilylation. Journal of Molecular Catalysis A Chemical. 412:13-19. https://doi.org/10.1016/j.molcata.2015.11.011 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.molcata.2015.11.011 es_ES
dc.description.upvformatpinicio 13 es_ES
dc.description.upvformatpfin 19 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 412 es_ES
dc.relation.pasarela S\304243 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Universitat Politècnica de València es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES


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