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Communication between iron(II) building blocks in cooperative spin transition phenomena

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Communication between iron(II) building blocks in cooperative spin transition phenomena

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dc.contributor.author Real, J. A. es_ES
dc.contributor.author Gaspar, A. B. es_ES
dc.contributor.author Niel, V. es_ES
dc.contributor.author Muñoz Roca, María Del Carmen es_ES
dc.date.accessioned 2020-09-24T12:28:44Z
dc.date.available 2020-09-24T12:28:44Z
dc.date.issued 2003-01 es_ES
dc.identifier.issn 0010-8545 es_ES
dc.identifier.uri http://hdl.handle.net/10251/150631
dc.description.abstract [EN] In the present article we discuss the cooperative nature of the spin crossover phenomenon in iron(II) complexes, providing a perspective of the state of the art in this area. The first aspect we discuss is the role of the intermolecular interactions, more precisely the ¿-interactions, in mononuclear complexes. We show that by playing with the nature of the ligands, aliphatic, aromatic, or extended aromatic, it is possible to create stronger cohesive forces and receive a more cooperative response from the compound. In the next step the singular family of bipyrimidine-bridged iron(II) dinuclear compounds is presented as the simplest example of polynuclear spin crossover complexes exhibiting a rich variety of magnetic behaviours, which stem from the synergistic effect between intramolecular and cooperative intermolecular interactions. Finally, a number of polymeric 1-3D architectures of varying dimensionality and topology are discussed in terms of the search for strong cooperative spin crossover systems. es_ES
dc.description.sponsorship We are grateful for financial support from the European Commission through the TMR-Network project Thermal and Optical Switching of Spin States (TOSS) , Contract No. ERB-FMRX-CT98-0199EEC/TMR. Some important results here reviewed have been carried out in collaboration with other TOSS groups, in particular, pressure and Mössbauer experiments in presence of strong magnetic combined with LIESST effect, were performed together with Professor P. Gütlich and Dr. V. Ksenovontov and photomagnetic measurements with Professor O. Kahn and Dr. J.F. Létard to whom we are deeply grateful. We thank the financial assistance from the Ministerio Español de Ciencia y Tecnología (project BQU 2001-2928). es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation EC/ERB-FMRX-CT98-0199EEC/TMR es_ES
dc.relation Ministerio de Ciencia y Tecnología/BQU2001-2928 es_ES
dc.relation.ispartof Coordination Chemistry Reviews es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Molecular magnetism es_ES
dc.subject Spin transition es_ES
dc.subject Iron(II) complexes es_ES
dc.subject Supramolecular chemistry es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Communication between iron(II) building blocks in cooperative spin transition phenomena es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/S0010-8545(02)00220-5 es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Real, JA.; Gaspar, AB.; Niel, V.; Muñoz Roca, MDC. (2003). Communication between iron(II) building blocks in cooperative spin transition phenomena. Coordination Chemistry Reviews. 236(1-2):121-141. https://doi.org/10.1016/S0010-8545(02)00220-5 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/S0010-8545(02)00220-5 es_ES
dc.description.upvformatpinicio 121 es_ES
dc.description.upvformatpfin 141 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 236 es_ES
dc.description.issue 1-2 es_ES
dc.relation.pasarela S\24146 es_ES
dc.contributor.funder European Commission es_ES
dc.contributor.funder Ministerio de Ciencia y Tecnología es_ES


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