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Assembly and encapsulation of coordination tectons driven by hydrogen-bondingand space-filling

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Assembly and encapsulation of coordination tectons driven by hydrogen-bondingand space-filling

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dc.contributor.author Gaspar, A.B. es_ES
dc.contributor.author Muñoz Roca, María Del Carmen es_ES
dc.contributor.author Real, J.A. es_ES
dc.date.accessioned 2020-09-24T12:29:59Z
dc.date.available 2020-09-24T12:29:59Z
dc.date.issued 2001-03 es_ES
dc.identifier.issn 1387-1609 es_ES
dc.identifier.uri http://hdl.handle.net/10251/150665
dc.description.abstract [FR] Le composé ¿Fe(LI)3¿2¿Fe(H2O)6¿(ClO4)6 (2), LI = 1,10-phénanthroline-5,6-dione, a été synthétisé et caractérisé. La structure cristalline 2 est définie par un assemblage bidimensionnel non covalent, peu commun, constitué par des tectons chiraux ¿Fe(LI)3¿2+, assemblés par des cations ¿Fe(H2O)6¿2+ encapsulés dans des cages. Ces cages sont formées par 12 liaisons hydrogène établies entre les molécules d¿eau coordinées et les groupes dione appartenant à six molecules chirales ¿Fe(LI)3¿2+ ¿, ¿ alternées. es_ES
dc.description.abstract [EN] The synthesis and characterisation of [Fe(L-1)(3)](2)[Fe(H2O)(6)](ClO4)(6) (2), L-1 = 1,10-phenanthroline-5,6-dione, is described. The crystal structure 2 is an unprecedented example of two-dimensional non-covalent array made up of [Fe(L-1)(3)](2+) species assembled by [Fe(H2O)(6)](2+) cations encapsulated in pseudo-hexagonal cages. These cages are sustained by 12 hydrogen bonds established between the coordinated water molecules and the dione groups of six alternating Delta, Lambda chiral [Fe(L-1)(3)](2+) moieties. (C) 2001 Academie des sciences / Editions scientifiques et medicales Elsevier SAS. es_ES
dc.description.sponsorship This work was supported by the Spanish Dirección General de Investigación Científica y Técnica (DGICYT) (Project PB97-1397). The authors are thankful to Prof. M. Julve and Dr. R. Ruiz for reviewing this contribution. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof Comptes Rendus de l Académie des Sciences - Series IIC - Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Iron(II) low-spin tectons es_ES
dc.subject Alpha-Diimine ligands es_ES
dc.subject Orthodiquinone ligands es_ES
dc.subject Supramolecular interaction es_ES
dc.subject Non-Covalent assembly es_ES
dc.subject Hydrogen bonds es_ES
dc.subject Fer(II) bas spin es_ES
dc.subject Ligands alpha-diimine es_ES
dc.subject Ligands orthodiquinone es_ES
dc.subject Interaction supramoléculaire es_ES
dc.subject Assemblage non covalent es_ES
dc.subject Liaisons hydrogène es_ES
dc.subject.classification FISICA APLICADA es_ES
dc.title Assembly and encapsulation of coordination tectons driven by hydrogen-bondingand space-filling es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/S1387-1609(00)01216-0 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MECD//PB97-1387/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada es_ES
dc.description.bibliographicCitation Gaspar, A.; Muñoz Roca, MDC.; Real, J. (2001). Assembly and encapsulation of coordination tectons driven by hydrogen-bondingand space-filling. Comptes Rendus de l Académie des Sciences - Series IIC - Chemistry. 4(3):193-196. https://doi.org/10.1016/S1387-1609(00)01216-0 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/S1387-1609(00)01216-0 es_ES
dc.description.upvformatpinicio 193 es_ES
dc.description.upvformatpfin 196 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 4 es_ES
dc.description.issue 3 es_ES
dc.relation.pasarela S\20923 es_ES
dc.contributor.funder Ministerio de Educación y Cultura es_ES


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