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Control of the Reaction Mechanism of Alkylaromatics Transalkylation by Means of Molecular Confinement Effects Associated to Zeolite Channel Architecture

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Control of the Reaction Mechanism of Alkylaromatics Transalkylation by Means of Molecular Confinement Effects Associated to Zeolite Channel Architecture

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Margarit Benavent, VJ.; Osman, M.; Al-Khattaf, S.; Martínez, C.; Boronat Zaragoza, M.; Corma Canós, A. (2019). Control of the Reaction Mechanism of Alkylaromatics Transalkylation by Means of Molecular Confinement Effects Associated to Zeolite Channel Architecture. ACS Catalysis. 9(7):5935-5946. https://doi.org/10.1021/acscatal.9b00763

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/150681

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Title: Control of the Reaction Mechanism of Alkylaromatics Transalkylation by Means of Molecular Confinement Effects Associated to Zeolite Channel Architecture
Author: Margarit Benavent, Vicente Juan OSMAN, MOGAHID Al-Khattaf, Sulaiman Martínez, Cristina Boronat Zaragoza, Mercedes Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] Transalkylation of alkylaromatics catalyzed by acid zeolites is a process widely employed in the petrochemical industry for upgrading aromatic fractions. The reaction mechanism is complex as it can proceed either by ...[+]
Subjects: Zeolites , MWW structure , Molecular confinement , Ethylbenzene transalkylation , DFT , Transalkylation mechanism
Copyrigths: Reserva de todos los derechos
Source:
ACS Catalysis. (issn: 2155-5435 )
DOI: 10.1021/acscatal.9b00763
Publisher:
American Chemical Society
Publisher version: https://doi.org/10.1021/acscatal.9b00763
Project ID:
info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/
...[+]
info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/
info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/
info:eu-repo/grantAgreement/MINECO//CTQ2015-70126-R/ES/DISEÑO DE CATALIZADORES ZEOLITICOS PARA LA OPTIMIZACION DE PROCESOS QUIMICOS DE INTERES INDUSTRIAL/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-82288-C2-1-P/ES/MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVAS/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101033-B-I00/ES/DISEÑO DE CATALIZADORES MULTIFUNCIONALES PARA LA CONVERSION EFICIENTE DE BIOGAS Y GAS NATURAL A HIDROCARBUROS DE INTERES INDUSTRIAL/
info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/
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Description: "This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acscatal.9b00763"
Thanks:
This work was supported by the Spanish Government through "Severo Ochoa Program" (SEV 2012-0267; SEV-2016-0683), RTI2018-101033-B-I00 and MAT2017-82288-C2-1-P, by the Fundacion Ramon Areces through a research contract of ...[+]
Type: Artículo

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