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Mechanical and Shape-Memory Properties of Poly(mannitol sebacate)/Cellulose Nanocrystal Nanocomposites

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Mechanical and Shape-Memory Properties of Poly(mannitol sebacate)/Cellulose Nanocrystal Nanocomposites

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dc.contributor.author Sonseca, Agueda es_ES
dc.contributor.author Camarero-Espinosa, Sandra es_ES
dc.contributor.author Peponi, Laura es_ES
dc.contributor.author Weder, Christoph es_ES
dc.contributor.author Foster, E.J. es_ES
dc.contributor.author Kenny, José M. es_ES
dc.contributor.author Giménez Torres, Enrique es_ES
dc.date.accessioned 2020-10-07T03:33:40Z
dc.date.available 2020-10-07T03:33:40Z
dc.date.issued 2014-11-01 es_ES
dc.identifier.issn 0887-624X es_ES
dc.identifier.uri http://hdl.handle.net/10251/151281
dc.description "This is the peer reviewed version of the following article: Sonseca, Á., Camarero‐Espinosa, S., Peponi, L., Weder, C., Foster, E. J., Kenny, J. M., & Giménez, E. (2014). Mechanical and shape‐memory properties of poly (mannitol sebacate)/cellulose nanocrystal nanocomposites. Journal of Polymer Science Part A: Polymer Chemistry, 52(21), 3123-3133., which has been published in final form at https://doi.org/10.1002/pola.27367. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving." es_ES
dc.description.abstract [EN] Polyesters based on polyols and sebacic acid, known as poly(polyol sebacate)s (PPS), are attracting considerable attention, as their properties are potentially useful in the context of soft-tissue engineering applications. To overcome the drawback that PPSs generally display rather low strength and stiffness, we have pursued the preparation of nano composites based poly(mannitol sebacate) (PMS), a prominent example of this materials family, with cellulose nanocrystals (CNCs). Nanocomposites were achieved in a two-step process. A soluble, low-molecular-weight PMS pre-polymer was formed via the polycondensation reaction between sebacic acid and D-mannitol. Nanocomposites with different CNC content were prepared by solution-casting and curing under vacuum using two different profiles designed to prepare materials with low and high degree of crosslinking. The as-prepared nano composites have higher stiffness and toughness than the neat PMS matrix while maintaining a high elongation at break. A highly crosslinked nanocomposite with a CNC content of 5 wt % displays a sixfold increase in Young s modulus and a fivefold improvement in toughness. Nanocomposites also exhibit a shape memory effect with a switch temperature in the range of 15 to 45 C; in particular the materials with a thermal transition in the upper part of this range are potentially useful for biomedical applications es_ES
dc.description.sponsorship The authors gratefully acknowledge financial support received from Spanish Ministry of Economy and Competitiveness (Project MAT2010/21494-C03), as well as the support of FPU grant from MED (MED-FPU; AP2009-2482), JAE-Doc grant (CSIC co-financed by FSE), Swiss National Science foundation (National Research Programme 64, Project #406440_131264/1) and the Adolphe Merkle Foundation. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Journal of Polymer Science Part A Polymer Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Cellulose nanocrystals es_ES
dc.subject Mechanical properties es_ES
dc.subject Nanocomposites es_ES
dc.subject Nanoparticles es_ES
dc.subject Poly(polyol sebacate) es_ES
dc.subject Shape memory es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Mechanical and Shape-Memory Properties of Poly(mannitol sebacate)/Cellulose Nanocrystal Nanocomposites es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/pola.27367 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/SNSF//406440_131264/CH/Cellulose-based nanocomposite building materials: solutions and toxicity/
dc.relation.projectID info:eu-repo/grantAgreement/ME//AP2009-2482/ES/AP2009-2482/ / es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//MAT2010-21494-C03-01/ES/DESARROLLO DE ESPUMAS Y SISTEMAS RIGIDOS CON MEMORIA DE FORMA BASADOS EN NANOCOMPUESTOS BIODEGRADABLES NANONOESTRUCTURADOS/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.description.bibliographicCitation Sonseca, A.; Camarero-Espinosa, S.; Peponi, L.; Weder, C.; Foster, E.; Kenny, JM.; Giménez Torres, E. (2014). Mechanical and Shape-Memory Properties of Poly(mannitol sebacate)/Cellulose Nanocrystal Nanocomposites. Journal of Polymer Science Part A Polymer Chemistry. 52(21):3123-3133. https://doi.org/10.1002/pola.27367 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/pola.27367 es_ES
dc.description.upvformatpinicio 3123 es_ES
dc.description.upvformatpfin 3133 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 52 es_ES
dc.description.issue 21 es_ES
dc.relation.pasarela S\283006 es_ES
dc.contributor.funder Ministerio de Educación es_ES
dc.contributor.funder Adolphe Merkle Foundation es_ES
dc.contributor.funder Swiss National Science Foundation es_ES
dc.contributor.funder Consejo Superior de Investigaciones Científicas es_ES
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
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