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Enantioselective synthesis of 2-substituted-1,4-diketones from (S)-mandelic acid enolate and alpha, beta-enones

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Enantioselective synthesis of 2-substituted-1,4-diketones from (S)-mandelic acid enolate and alpha, beta-enones

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Blay, G.; Fernandez, I.; Monje, B.; Muñoz Roca, MDC.; Pedro, JR.; Vila, C. (2006). Enantioselective synthesis of 2-substituted-1,4-diketones from (S)-mandelic acid enolate and alpha, beta-enones. Tetrahedron. 62(39):9174-9182. https://doi.org/10.1016/j.tet.2006.07.036

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/151882

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Title: Enantioselective synthesis of 2-substituted-1,4-diketones from (S)-mandelic acid enolate and alpha, beta-enones
Author: Blay, Gonzalo Fernandez, Isabel Monje, Belen Muñoz Roca, María Del Carmen Pedro, Jose R. Vila, Carlos
UPV Unit: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Issued date:
Abstract:
[EN] An approach for the synthesis of chiral non-racemic 2-substituted-1,4-diketones from (S)-mandelic acid and ¿,ß-enones has been developed. The reaction of lithium enolate of the 1,3-dioxolan-4-one derived from optically ...[+]
Copyrigths: Cerrado
Source:
Tetrahedron. (issn: 0040-4020 )
DOI: 10.1016/j.tet.2006.07.036
Publisher:
Elsevier
Publisher version: https://doi.org/10.1016/j.tet.2006.07.036
Project ID:
info:eu-repo/grantAgreement/MICYT//BQU2001-3017/ES/Complejos de metales de transición como catalizadores biomiméticos en síntesis orgánica: De la catálisis oxidativa a la catálisis de ácidos de Lewis/
info:eu-repo/grantAgreement/GVA//GV05%2F10/
info:eu-repo/grantAgreement/GVA//GV%2F03%2F168/
Thanks:
Financial support from the Spanish Government MEC (BQU2001-3017) and from Generalitat Valenciana (Grupos 03/168 and GV05/10) is acknowledged. B.M. thanks the MEC for a grant (FPI program).
Type: Artículo

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