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Stereselective Synthesis of 4-Hydroxy-8,12-Guaianolides from Santonin

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Stereselective Synthesis of 4-Hydroxy-8,12-Guaianolides from Santonin

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Blay, G.; Bargues, V.; Cardona, L.; Collado, AM.; García, B.; Muñoz Roca, MDC.; Pedro, JR. (2000). Stereselective Synthesis of 4-Hydroxy-8,12-Guaianolides from Santonin. The Journal of Organic Chemistry. 65(7):2138-2144. https://doi.org/10.1021/jo991756n

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Title: Stereselective Synthesis of 4-Hydroxy-8,12-Guaianolides from Santonin
Author: Blay, Gonzalo Bargues, Victoria Cardona, Luz Collado, Ana M. García, Begoña Muñoz Roca, María Del Carmen Pedro, Jose R.
UPV Unit: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Issued date:
Abstract:
[EN] Hydroxyester 2, easily obtained from santonin (1), has been transformed into 10¿-hydroxyguai-3-en-8,12-olide 6, a good intermediate for the synthesis of natural 8,12-guaianolides. Compound 6 was obtained from 2 by ...[+]
Copyrigths: Cerrado
Source:
The Journal of Organic Chemistry. (issn: 0022-3263 )
DOI: 10.1021/jo991756n
Publisher:
American Chemical Society
Publisher version: https://doi.org/10.1021/jo991756n
Project ID:
info:eu-repo/grantAgreement/EC/FP4/FAIR961781/EU/TERPENES AS NATURAL CHIRAL STARTING MATERIAL FOR THE SYNTHESIS OF FLAVOURS, FRAGRANCES, PHARMACEUTICALS AND BIOCONTROLE AGENTS/
info:eu-repo/grantAgreement/MEC//PB94-0985/
Thanks:
Financial support from the European Commission (Grant FAIR CT96-1781) and from the Dirección General de Investigación Científica y Técnica (DGICYT; Grant PB 94-0985) is gratefully acknowledged. V.B. and A.M.C. are especially ...[+]
Type: Artículo

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