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Generation and Reactivity of Electron-Rich Carbenes on the Surface of Catalytic Gold Nanoparticles

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Generation and Reactivity of Electron-Rich Carbenes on the Surface of Catalytic Gold Nanoparticles

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Oliver-Meseguer, J.; Boronat Zaragoza, M.; Vidal Moya, JA.; Concepción Heydorn, P.; Rivero-Crespo, MÁ.; Leyva Perez, A.; Corma Canós, A. (2018). Generation and Reactivity of Electron-Rich Carbenes on the Surface of Catalytic Gold Nanoparticles. Journal of the American Chemical Society. 140(9):3215-3218. https://doi.org/10.1021/jacs.7b13696

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/154389

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Title: Generation and Reactivity of Electron-Rich Carbenes on the Surface of Catalytic Gold Nanoparticles
Author: Oliver-Meseguer, Judit Boronat Zaragoza, Mercedes Vidal Moya, José Alejandro Concepción Heydorn, Patricia Rivero-Crespo, Miguel Ángel Leyva Perez, Antonio Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] The reactive nature of carbenes can be modulated, and ultimately reversed, by receiving additional electron density from a metal. Here, it is shown that Au nanoparticles (NPs) generate an electron-rich carbene on ...[+]
Copyrigths: Reserva de todos los derechos
Source:
Journal of the American Chemical Society. (issn: 0002-7863 )
DOI: 10.1021/jacs.7b13696
Publisher:
American Chemical Society
Publisher version: https://doi.org/10.1021/jacs.7b13696
Project ID:
info:eu-repo/grantAgreement/MINECO//CTQ2014-55178-R/ES/HIERRO Y BISMUTO SUB-NANOMETRICO Y CATALITICO/
Thanks:
Financial support by MINECO through the Severo Ochoa program, RETOS program (CTQ2014-55178-R), and Ramon y Cajal Program (to A.L.-P.) is acknowledged. J.O.-M. thanks ITQ for the concession of a contract. We are thankful ...[+]
Type: Artículo

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