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Nickel exsolution driven phase transformation from an n=2 to an n=1 Ruddlesden Popper manganite for methane steam reforming reaction in SOFC conditions

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Nickel exsolution driven phase transformation from an n=2 to an n=1 Ruddlesden Popper manganite for methane steam reforming reaction in SOFC conditions

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dc.contributor.author Vecino-Mantilla, Sebastián es_ES
dc.contributor.author Gauthier-Maradei, Paola es_ES
dc.contributor.author Huvé, Marielle es_ES
dc.contributor.author Serra Alfaro, José Manuel es_ES
dc.contributor.author Roussel, Pascal es_ES
dc.contributor.author Gauthier, Gilles H. es_ES
dc.date.accessioned 2020-11-13T04:32:47Z
dc.date.available 2020-11-13T04:32:47Z
dc.date.issued 2019-09-19 es_ES
dc.identifier.issn 1867-3880 es_ES
dc.identifier.uri http://hdl.handle.net/10251/155008
dc.description This is the peer reviewed version of the following article: S. Vecino-Mantilla, P. Gauthier-Maradei, M. Huvé, J. M. Serra, P. Roussel, G. H. Gauthier, ChemCatChem 2019, 11, 4631, which has been published in final form at https://doi.org/10.1002/cctc.201901002. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. es_ES
dc.description.abstract [EN] An original way to perform the exsolution of Ni nanoparticles on a ceramic support was explored for the development of methane steam reforming catalyst in SOFC anode conditions. The n=2 Ruddlesden-Popper (RP) phase La1.5Sr1.5Mn1.5Ni0.5O7 +/-delta has been synthesized by the Pechini method and subsequently reduced with an H-2-N-2 mixture at different temperatures and reducing times to induce the formation of two phases: LaSrMnO4 (n=1 RP) decorated with metallic Ni nanoparticles. Preliminary measurements of catalytic behavior for the steam reforming have been carried out in a reduction-reaction process with a mixture of 82 mol %CH4, 18 mol %N-2 and low steam to carbon ratio (S/C=0.15). The catalyst exhibits a selectivity for CO production (0.97), 14.60 mol % CH4 conversion and around 24.19 mol % H-2 production. Such catalytic behavior was maintained for more than 4 h, with a constant rate of hydrogen production and CH4 conversion rate. es_ES
dc.description.sponsorship The authors acknowledge the financial support of the Colombian Administrative Department of Science, Technology and Innovation COLCIENCIAS (Project #110265842833 "Symmetrical high temperature Fuel Cell operating with Colombian natural gas" (contract #038-2015) and S. Vecino-Mantilla's Ph.D. scholarship (call #647)) and of the Spanish National Research Council CSIC (Project #COOPA20112). The authors are also grateful to UIS' X-Ray Laboratory (Parque Tecnologico Guatiguara) for XRD measurements, UPV's Electronic Microscopy Laboratory for the FESEM analysis, and finally to Margarita Vecino-Mantilla, Carolina Cardenas-Velandia, Santiago Paez-Duque, Ivan Suarez-Acelas (UIS), Maria Fabuel (UPV) and Olivier Gardoll (UCCS) for their contribution to materials synthesis and characterization. As well as Santiago Palencia, Monica Sandoval (UIS) and Caroline Pirovano (UCCS) are warmly acknowledged for useful discussions. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof ChemCatChem es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Exsolution es_ES
dc.subject Fuel cells es_ES
dc.subject Nickel es_ES
dc.subject Ruddlesden-Popper es_ES
dc.subject Steam reforming es_ES
dc.title Nickel exsolution driven phase transformation from an n=2 to an n=1 Ruddlesden Popper manganite for methane steam reforming reaction in SOFC conditions es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/cctc.201901002 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/COLCIENCIAS//110265842833/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/COLCIENCIAS//038-2015/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/COLCIENCIAS//647/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CSIC//COOPA20112/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Vecino-Mantilla, S.; Gauthier-Maradei, P.; Huvé, M.; Serra Alfaro, JM.; Roussel, P.; Gauthier, GH. (2019). Nickel exsolution driven phase transformation from an n=2 to an n=1 Ruddlesden Popper manganite for methane steam reforming reaction in SOFC conditions. ChemCatChem. 11(18):4631-4641. https://doi.org/10.1002/cctc.201901002 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/cctc.201901002 es_ES
dc.description.upvformatpinicio 4631 es_ES
dc.description.upvformatpfin 4641 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 11 es_ES
dc.description.issue 18 es_ES
dc.relation.pasarela S\392220 es_ES
dc.contributor.funder Consejo Superior de Investigaciones Científicas es_ES
dc.contributor.funder Departamento Administrativo de Ciencia, Tecnología e Innovación, Colombia es_ES
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