- -

Tuning the Microenvironment of Gold Nanoparticles Encapsulated within MIL-101(Cr) for the Selective Oxidation of Alcohols with O-2: Influence of the Amino Terephthalate Linker

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

Tuning the Microenvironment of Gold Nanoparticles Encapsulated within MIL-101(Cr) for the Selective Oxidation of Alcohols with O-2: Influence of the Amino Terephthalate Linker

Mostrar el registro sencillo del ítem

Ficheros en el ítem

Thumbnail
Nombre: Santiago-Portillo ...
Tamaño: 583.5Kb
Formato: PDF
Descripción: Versión del Autor.
Abrir
[Cerrado]
Nombre: Paper Au.pdf
Tamaño: 1.208Mb
Formato: PDF
Descripción: Versión editorial
Solicitar una copia al autor
dc.contributor.author Santiago-Portillo, Andrea es_ES
dc.contributor.author Cabrero-Antonino, Maria es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.date.accessioned 2020-11-18T04:31:25Z
dc.date.available 2020-11-18T04:31:25Z
dc.date.issued 2019-07-11 es_ES
dc.identifier.issn 0947-6539 es_ES
dc.identifier.uri http://hdl.handle.net/10251/155238
dc.description This is the peer reviewed version of the following article: Chem. Eur. J. 2019, 25, 9280 9286, which has been published in final form at https://doi.org/10.1002/chem.201901361. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. es_ES
dc.description.abstract [EN] This manuscript reports a comparative study of the catalytic performance of gold nanoparticles (NPs) encapsulated within MIL-101(Cr) with or without amino groups in the terephthalate linker. The purpose is to show how the amino groups can influence the microenvironment and catalytic stability of incorporated gold nanoparticles. The first influence of the presence of this substituent is the smaller particle size of Au NPs hosted in MIL-101(Cr)-NH2 (2.45 +/- 0.19 nm) compared with the parent MIL-101(Cr)-H (3.02 +/- 0.39 nm). Both materials are highly active to promote the aerobic alcohol oxidation and exhibit a wide substrate scope. Although both catalysts can achieve turnover numbers as high as 10(6) for the solvent-free aerobic oxidation of benzyl alcohol, Au@MIL-101(Cr)-NH2 exhibits higher turnover frequency values (12 000 h(-1)) than Au@MIL-101(Cr)-H (6800 h(-1)). Au@MIL-101(Cr)-NH2 also exhibits higher catalytic stability, being recyclable for 20 times with coincident temporal conversion profiles, in comparison with some decay observed in the parent Au@MIL-101(Cr)-H. Characterization by transmission electron microscopy of the 20-times used samples shows a very minor particle size increase in the case of Au@MIL-101(Cr)-NH2 (2.97 +/- 0.27 nm) in comparison with the Au@MIL-101(Cr)-H analog (5.32 +/- 0.72 nm). The data presented show the potential of better control of the microenvironment to improve the performance of encapsulated Au nanoparticles. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa, CTQ2015-65963-CQ-R1 and CTQ2014-53292-R) is gratefully acknowledged. Generalidad Valenciana is also thanked for funding (Prometeo 2017/083). S.N. thanks financial support by the Fundación Ramón Areces (XVIII Concurso Nacional para la Adjudicación de Ayudas a la Investigación en Ciencias de la Vida y de la Materia, 2016). es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Aerobic oxidation es_ES
dc.subject Alcohol oxidation es_ES
dc.subject Gold catalysis es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject MIL-101(Cr)-NH2 es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Tuning the Microenvironment of Gold Nanoparticles Encapsulated within MIL-101(Cr) for the Selective Oxidation of Alcohols with O-2: Influence of the Amino Terephthalate Linker es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/chem.201901361 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2014-53292-R/ES/MATERIALES GRAFENICOS COMO CATALIZADORES PARA REACCIONES ORGANICAS./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-69153-C2-1-R/ES/EXPLOTANDO EL USO DEL GRAFENO EN CATALISIS. USO DEL GRAFENO COMO CARBOCATALIZADOR O COMO SOPORTE/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F083/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Santiago-Portillo, A.; Cabrero-Antonino, M.; Alvaro Rodríguez, MM.; Navalón Oltra, S.; García Gómez, H. (2019). Tuning the Microenvironment of Gold Nanoparticles Encapsulated within MIL-101(Cr) for the Selective Oxidation of Alcohols with O-2: Influence of the Amino Terephthalate Linker. Chemistry - A European Journal. 25(39):9280-9286. https://doi.org/10.1002/chem.201901361 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/chem.201901361 es_ES
dc.description.upvformatpinicio 9280 es_ES
dc.description.upvformatpfin 9286 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 25 es_ES
dc.description.issue 39 es_ES
dc.identifier.pmid 31063224 es_ES
dc.relation.pasarela S\398873 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Fundación Ramón Areces es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.description.references H�ft, E., Kosslick, H., Fricke, R., & Hamann, H.-J. (1996). Titanhaltige Molekularsiebe als Katalysatoren f�r selektive Oxidationsreaktionen mit Wasserstoffperoxid. Journal f�r Praktische Chemie/Chemiker-Zeitung, 338(1), 1-15. doi:10.1002/prac.19963380102 es_ES
dc.description.references Matsumoto, T., Ueno, M., Wang, N., & Kobayashi, S. (2008). Recent Advances in Immobilized Metal Catalysts for Environmentally Benign Oxidation of Alcohols. Chemistry - An Asian Journal, 3(2), 196-214. doi:10.1002/asia.200700359 es_ES
dc.description.references Saikia, M., Bhuyan, D., & Saikia, L. (2015). Facile synthesis of Fe3O4nanoparticles on metal organic framework MIL-101(Cr): characterization and catalytic activity. New Journal of Chemistry, 39(1), 64-67. doi:10.1039/c4nj01312c es_ES
dc.description.references Corma, A., & Garcia, H. (2008). Supported gold nanoparticles as catalysts for organic reactions. Chemical Society Reviews, 37(9), 2096. doi:10.1039/b707314n es_ES
dc.description.references Parmeggiani, C., & Cardona, F. (2012). Transition metal based catalysts in the aerobic oxidation of alcohols. Green Chemistry, 14(3), 547. doi:10.1039/c2gc16344f es_ES
dc.description.references Stahl, S. S. (2004). Palladium Oxidase Catalysis: Selective Oxidation of Organic Chemicals by Direct Dioxygen-Coupled Turnover. Angewandte Chemie International Edition, 43(26), 3400-3420. doi:10.1002/anie.200300630 es_ES
dc.description.references Dhakshinamoorthy, A., & Garcia, H. (2012). Catalysis by metal nanoparticles embedded on metal–organic frameworks. Chemical Society Reviews, 41(15), 5262. doi:10.1039/c2cs35047e es_ES
dc.description.references Alhumaimess, M., Lin, Z., He, Q., Lu, L., Dimitratos, N., Dummer, N. F., … Hutchings, G. J. (2014). Oxidation of Benzyl Alcohol and Carbon Monoxide Using Gold Nanoparticles Supported on MnO2Nanowire Microspheres. Chemistry - A European Journal, 20(6), 1701-1710. doi:10.1002/chem.201303355 es_ES
dc.description.references Buonerba, A., Cuomo, C., Ortega Sánchez, S., Canton, P., & Grassi, A. (2011). Gold Nanoparticles Incarcerated in Nanoporous Syndiotactic Polystyrene Matrices as New and Efficient Catalysts for Alcohol Oxidations. Chemistry - A European Journal, 18(2), 709-715. doi:10.1002/chem.201101034 es_ES
dc.description.references Costa, V. V., Estrada, M., Demidova, Y., Prosvirin, I., Kriventsov, V., Cotta, R. F., … Gusevskaya, E. V. (2012). Gold nanoparticles supported on magnesium oxide as catalysts for the aerobic oxidation of alcohols under alkali-free conditions. Journal of Catalysis, 292, 148-156. doi:10.1016/j.jcat.2012.05.009 es_ES
dc.description.references Zhang, W., Xiao, Z., Wang, J., Fu, W., Tan, R., & Yin, D. (2019). Selective Aerobic Oxidation of Alcohols over Gold‐Palladium Alloy Catalysts Using Air at Atmospheric Pressure in Water. ChemCatChem, 11(6), 1779-1788. doi:10.1002/cctc.201900015 es_ES
dc.description.references Liu, X. Y., Wang, A., Zhang, T., & Mou, C.-Y. (2013). Catalysis by gold: New insights into the support effect. Nano Today, 8(4), 403-416. doi:10.1016/j.nantod.2013.07.005 es_ES
dc.description.references Navalon, S., Dhakshinamoorthy, A., Alvaro, M., & Garcia, H. (2016). Metal nanoparticles supported on two-dimensional graphenes as heterogeneous catalysts. Coordination Chemistry Reviews, 312, 99-148. doi:10.1016/j.ccr.2015.12.005 es_ES
dc.description.references Dhakshinamoorthy, A., Asiri, A. M., & Garcia, H. (2017). Metal Organic Frameworks as Versatile Hosts of Au Nanoparticles in Heterogeneous Catalysis. ACS Catalysis, 7(4), 2896-2919. doi:10.1021/acscatal.6b03386 es_ES
dc.description.references Howarth, A. J., Liu, Y., Li, P., Li, Z., Wang, T. C., Hupp, J. T., & Farha, O. K. (2016). Chemical, thermal and mechanical stabilities of metal–organic frameworks. Nature Reviews Materials, 1(3). doi:10.1038/natrevmats.2015.18 es_ES
dc.description.references Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009). Metal–organic framework materials as catalysts. Chemical Society Reviews, 38(5), 1450. doi:10.1039/b807080f es_ES
dc.description.references Leus, K., Concepcion, P., Vandichel, M., Meledina, M., Grirrane, A., Esquivel, D., … Van Der Voort, P. (2015). Au@UiO-66: a base free oxidation catalyst. RSC Advances, 5(29), 22334-22342. doi:10.1039/c4ra16800c es_ES
dc.description.references Saikia, M., Kaichev, V., & Saikia, L. (2016). Gold nanoparticles supported on nanoscale amine-functionalized MIL-101(Cr) as a highly active catalyst for epoxidation of styrene. RSC Advances, 6(108), 106856-106865. doi:10.1039/c6ra24458k es_ES
dc.description.references Liu, H., Liu, Y., Li, Y., Tang, Z., & Jiang, H. (2010). Metal−Organic Framework Supported Gold Nanoparticles as a Highly Active Heterogeneous Catalyst for Aerobic Oxidation of Alcohols. The Journal of Physical Chemistry C, 114(31), 13362-13369. doi:10.1021/jp105666f es_ES
dc.description.references Lammert, M., Bernt, S., Vermoortele, F., De Vos, D. E., & Stock, N. (2013). Single- and Mixed-Linker Cr-MIL-101 Derivatives: A High-Throughput Investigation. Inorganic Chemistry, 52(15), 8521-8528. doi:10.1021/ic4005328 es_ES
dc.description.references Zhu, Q.-L., Li, J., & Xu, Q. (2013). Immobilizing Metal Nanoparticles to Metal–Organic Frameworks with Size and Location Control for Optimizing Catalytic Performance. Journal of the American Chemical Society, 135(28), 10210-10213. doi:10.1021/ja403330m es_ES
dc.description.references Chen, Y. F., Babarao, R., Sandler, S. I., & Jiang, J. W. (2010). Metal−Organic Framework MIL-101 for Adsorption and Effect of Terminal Water Molecules: From Quantum Mechanics to Molecular Simulation. Langmuir, 26(11), 8743-8750. doi:10.1021/la904502h es_ES
dc.description.references Ferey, G. (2005). A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area. Science, 309(5743), 2040-2042. doi:10.1126/science.1116275 es_ES
dc.description.references Santiago-Portillo, A., Navalón, S., Cirujano, F. G., Xamena, F. X. L. i, Alvaro, M., & Garcia, H. (2015). MIL-101 as Reusable Solid Catalyst for Autoxidation of Benzylic Hydrocarbons in the Absence of Additional Oxidizing Reagents. ACS Catalysis, 5(6), 3216-3224. doi:10.1021/acscatal.5b00411 es_ES
dc.description.references Buxton, G. V., Greenstock, C. L., Helman, W. P., & Ross, A. B. (1988). Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O− in Aqueous Solution. Journal of Physical and Chemical Reference Data, 17(2), 513-886. doi:10.1063/1.555805 es_ES
dc.description.references Clifton, C. L., & Huie, R. E. (1989). Rate constants for hydrogen abstraction reactions of the sulfate radical, SO4?. Alcohols. International Journal of Chemical Kinetics, 21(8), 677-687. doi:10.1002/kin.550210807 es_ES
dc.description.references Dhakshinamoorthy, A., Asiri, A. M., & Garcia, H. (2017). Tuneable nature of metal organic frameworks as heterogeneous solid catalysts for alcohol oxidation. Chemical Communications, 53(79), 10851-10869. doi:10.1039/c7cc05927b es_ES
dc.description.references Cancino, P., Vega, A., Santiago-Portillo, A., Navalon, S., Alvaro, M., Aguirre, P., … García, H. (2016). A novel copper(ii)–lanthanum(iii) metal organic framework as a selective catalyst for the aerobic oxidation of benzylic hydrocarbons and cycloalkenes. Catalysis Science & Technology, 6(11), 3727-3736. doi:10.1039/c5cy01448d es_ES
dc.description.references Gómez-Paricio, A., Santiago-Portillo, A., Navalón, S., Concepción, P., Alvaro, M., & Garcia, H. (2016). MIL-101 promotes the efficient aerobic oxidative desulfurization of dibenzothiophenes. Green Chemistry, 18(2), 508-515. doi:10.1039/c5gc00862j es_ES


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem