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On-Surface Cucurbit[n]uril Supramolecular Recognition for an Optical Sensor Design

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On-Surface Cucurbit[n]uril Supramolecular Recognition for an Optical Sensor Design

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dc.contributor.author Jiménez, Javier es_ES
dc.contributor.author Blasco, Sonia es_ES
dc.contributor.author Blanco, Elias es_ES
dc.contributor.author Atienzar Corvillo, Pedro Enrique es_ES
dc.contributor.author del Pozo, María es_ES
dc.contributor.author Quintana, Carmen es_ES
dc.date.accessioned 2020-11-19T04:31:55Z
dc.date.available 2020-11-19T04:31:55Z
dc.date.issued 2019-06-28 es_ES
dc.identifier.uri http://hdl.handle.net/10251/155301
dc.description This is the peer reviewed version of the following article: ChemistrySelect 2019, 4, 7036 7041, which has been published in final form at https://doi.org/10.1002/slct.201901127. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. es_ES
dc.description.abstract [EN] A novel optical sensor, based on the use of the macrocyclic receptor cucurbit[7]uril as molecular selector taking part of a sensing poly(vinyl chloride)-based membrane immobilized onto a quartz slide surface, has been developed and tested to thiabendazole analysis. The method is built upon the increase of the thiabendazole fluorescence as a result of the supramolecular recognition event. Variables involved in the membrane construction and fluorescence measurements have been evaluated and optimized. The sensing membrane is prepared by a spin-coating procedure (1 min at 800 r.p.m.). An increase of more than 2 fold in the fluorescence signal is observed when the supramolecular complex is immobilized into the membrane respect to that observed for the free guest. Under optimized conditions, the dispositive responds in a few seconds to thiabendazole concentrations at 10(-7) M level. In addition, the characterization of the supramolecular complex together with lifetime measurements is included. es_ES
dc.description.sponsorship The authors would like to thank the Comunidad Autonoma de Madrid (P2018/NMT-4349, TRANSNANOAVANSENS-CM) for financial support. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof ChemistrySelect es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Cucurbituril es_ES
dc.subject Fungicide es_ES
dc.subject Membrane es_ES
dc.subject Sensors es_ES
dc.subject Thiabendazole es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title On-Surface Cucurbit[n]uril Supramolecular Recognition for an Optical Sensor Design es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/slct.201901127 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CAM//P2018%2FNMT-4349/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Jiménez, J.; Blasco, S.; Blanco, E.; Atienzar Corvillo, PE.; Del Pozo, M.; Quintana, C. (2019). On-Surface Cucurbit[n]uril Supramolecular Recognition for an Optical Sensor Design. ChemistrySelect. 4(24):7036-7041. https://doi.org/10.1002/slct.201901127 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/slct.201901127 es_ES
dc.description.upvformatpinicio 7036 es_ES
dc.description.upvformatpfin 7041 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 4 es_ES
dc.description.issue 24 es_ES
dc.identifier.eissn 2365-6549 es_ES
dc.relation.pasarela S\410846 es_ES
dc.contributor.funder Comunidad de Madrid es_ES
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