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The First Study on the Reactivity of Water Vapor in Metal-Organic Frameworks with Platinum Nanocrystals

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The First Study on the Reactivity of Water Vapor in Metal-Organic Frameworks with Platinum Nanocrystals

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Nombre: Ogiwara;Kobayashi ...
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dc.contributor.author Ogiwara, Naoki es_ES
dc.contributor.author Kobayashi, Hirokazu es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author Rey Garcia, Fernando es_ES
dc.contributor.author Kitagawa, Hiroshi es_ES
dc.date.accessioned 2020-12-01T04:32:00Z
dc.date.available 2020-12-01T04:32:00Z
dc.date.issued 2019-08-19 es_ES
dc.identifier.issn 1433-7851 es_ES
dc.identifier.uri http://hdl.handle.net/10251/156098
dc.description.abstract [EN] We first studied the reactivity of H2O vapor in metal-organic frameworks (MOFs) with Pt nanocrystals (NCs) through the water-gas shift (WGS) reaction. A water-stable MOF, UiO-66, serves as a highly effective support material for the WGS reaction compared with ZrO2. The origin of the high catalytic performance was investigated using in situ IR spectroscopy. In addition, from a comparison of the catalytic activities of Pt on UiO-66, where Pt NCs are located on the surface of UiO-66 and Pt@UiO-66, where Pt NCs are coated with UiO-66, we found that the competitive effects of H2O condensation and diffusion in the UiO-66 play important roles in the catalytic activity of Pt NCs. A thinner UiO-66 coating further enhanced the WGS reaction activity of Pt NCs by minimizing the negative effect of slow H2O diffusion in UiO-66. es_ES
dc.description.sponsorship This work was supported by JST PRESTO (No. JPMJPR1514), JSPS Grants-in-Aid for Scientific Research (B) (No. 17750056), JSPS Research Fellow (No. 17J10099) and Spanish Government-MINECO through "Severo Ochoa" Excellence Programme (SEV-2016-0683). The synchrotron radiation experiments were performed at the BL14B2 of SPring-8 with the approval of JASRI (Proposal No. 2018A1753). es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Angewandte Chemie International Edition es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Heterogeneous catalysts es_ES
dc.subject Platinum nanocrystals es_ES
dc.subject Metal-organic frameworks es_ES
dc.subject Water es_ES
dc.subject Water-gas shift reaction es_ES
dc.title The First Study on the Reactivity of Water Vapor in Metal-Organic Frameworks with Platinum Nanocrystals es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/anie.201905667 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/JSPS//17750056/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/JSPS//17J10099/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/JST//JPMJPR1514/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Ogiwara, N.; Kobayashi, H.; Concepción Heydorn, P.; Rey Garcia, F.; Kitagawa, H. (2019). The First Study on the Reactivity of Water Vapor in Metal-Organic Frameworks with Platinum Nanocrystals. Angewandte Chemie International Edition. 58(34):11731-11736. https://doi.org/10.1002/anie.201905667 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1002/anie.201905667 es_ES
dc.description.upvformatpinicio 11731 es_ES
dc.description.upvformatpfin 11736 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 58 es_ES
dc.description.issue 34 es_ES
dc.identifier.pmid 31267626 es_ES
dc.relation.pasarela S\410688 es_ES
dc.contributor.funder Japan Science and Technology Agency es_ES
dc.contributor.funder Japan Society for the Promotion of Science es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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