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Use of Alkylarsonium Directing Agents for the Synthesis and Study of Zeolites

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Use of Alkylarsonium Directing Agents for the Synthesis and Study of Zeolites

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dc.contributor.author Saez-Ferre, Sara es_ES
dc.contributor.author Lopes, Christian W. es_ES
dc.contributor.author Simancas-Coloma, Jorge es_ES
dc.contributor.author Vidal Moya, José Alejandro es_ES
dc.contributor.author Blasco Lanzuela, Teresa es_ES
dc.contributor.author Agostini, Giovanni es_ES
dc.contributor.author Mínguez Espallargas, Guillermo es_ES
dc.contributor.author Jorda Moret, Jose Luis es_ES
dc.contributor.author Rey Garcia, Fernando es_ES
dc.contributor.author Oña-Burgos, Pascual es_ES
dc.date.accessioned 2020-12-03T04:32:00Z
dc.date.available 2020-12-03T04:32:00Z
dc.date.issued 2019-12-18 es_ES
dc.identifier.issn 0947-6539 es_ES
dc.identifier.uri http://hdl.handle.net/10251/156327
dc.description This is the peer reviewed version of the following article: Chem. Eur. J. 2019, 25, 16390 16396 , which has been published in final form at https://doi.org/10.1002/chem.201904043. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. es_ES
dc.description.abstract [EN] Expanding the previously known family of -onium (ammonium, phosphonium, and sulfonium) organic structure-directing agents (OSDAs) for the synthesis of zeolite MFI, a new member, the arsonium cation, is used for the first time. The new group of tetraalkylarsonium cations has allowed the synthesis of the zeolite ZSM-5 with several different chemical compositions, opening a route for the synthesis of zeolites with a new series of OSDA. Moreover, the use of As replacing N in the OSDA allows the introduction of probe atoms that facilitate the study of these molecules by powder X-ray diffraction (PXRD), solid-state nuclear magnetic resonance (MAS NMR), and X-ray absorption spectroscopy (XAS). Finally, the influence of trivalent elements such as B, Al, or Ga isomorphically replacing Si atoms in the framework structure and its interaction with the As species has been studied. The suitability of the tetraalkylarsonium cation for carrying out the crystallization of zeolites is demonstrated along with the benefit of the presence of As atoms in the occluded OSDA, which allows its advanced characterization as well as the study of its evolution during OSDA removal by thermal treatments. es_ES
dc.description.sponsorship Program Severo Ochoa SEV-2016-0683 and Maria de Maeztu MDM-2015-0538 are gratefully acknowledged. S.S-F. thanks MEC for his Severo Ochoa Grant SPV-2013-067884, P.O.-B. and G.M.E. thank MEC for his Ramon y Cajal contracts (RYC-2014-16620 and RYC-2013-14386). The authors thank the financial support by the Spanish Government (RTI2018-096399-A-I00, RTI2018-101784-B-I00 and CTQ2017-89528-P) and the Generalitat Valeciana (PROMETEO/2017/066). The Electron Microscopy Service of the UPV is acknowledged for their help in sample characterization. We gratefully acknowledge ESRF synchrotron for allocating beamtime (proposal CH-5193), the Italian CRG beam-line at ESRF (LISA-BM08), and Alessandro Puri for the help and technical support during our experiment. C.W.L. (Science without Frontiers-Process no. 13191/13-6) thanks CAPES for a predoctoral fellowship. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Alkylarsonium es_ES
dc.subject Arsenic es_ES
dc.subject Cations es_ES
dc.subject Structure-directing agents es_ES
dc.subject Zeolites es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Use of Alkylarsonium Directing Agents for the Synthesis and Study of Zeolites es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/chem.201904043 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-89528-P/ES/MOFS Y MOLECULAS MAGNETICAS PARA ELECTRONICA Y TECNOLOGIA CUANTICA/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/CAPES//13191%2F13-6/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SVP-2013-067884/ES/SVP-2013-067884/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//RYC-2014-16620/ES/RYC-2014-16620/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101784-B-I00/ES/NUEVOS MATERIALES ZEOLITICOS PARA PROCESOS DE SEPARACION SELECTIVA DE GASES, APLICACIONES MEDIOAMBIENTALES Y CONSERVACION DE ALIMENTOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-096399-A-I00/ES/CLUSTERES MULTIMETALICOS Y SUBNANOMETRICOS SOPORTADOS: SINTESIS, ESTRUCTURA Y DINAMISMO ATOMICO, Y EMPLEO COMO CATALIZADORES EN LA VALORIZACION DE METANO Y ALCANOS LIGEROS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MDM-2015-0538/ES/INSTITUTO DE CIENCIA MOLECULAR/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//RYC-2013-14386/ES/RYC-2013-14386/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F066/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Saez-Ferre, S.; Lopes, CW.; Simancas-Coloma, J.; Vidal Moya, JA.; Blasco Lanzuela, T.; Agostini, G.; Mínguez Espallargas, G.... (2019). Use of Alkylarsonium Directing Agents for the Synthesis and Study of Zeolites. Chemistry - A European Journal. 25(71):16390-16396. https://doi.org/10.1002/chem.201904043 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/chem.201904043 es_ES
dc.description.upvformatpinicio 16390 es_ES
dc.description.upvformatpfin 16396 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 25 es_ES
dc.description.issue 71 es_ES
dc.identifier.pmid 31603997 es_ES
dc.relation.pasarela S\406641 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Educación y Ciencia es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministerio de Ciencia, Innovación y Universidades es_ES
dc.contributor.funder Coordenaçao de Aperfeiçoamento de Pessoal de Nível Superior, Brasil es_ES
dc.description.references Sun, J., Bonneau, C., Cantín, Á., Corma, A., Díaz-Cabañas, M. J., Moliner, M., … Zou, X. (2009). The ITQ-37 mesoporous chiral zeolite. Nature, 458(7242), 1154-1157. doi:10.1038/nature07957 es_ES
dc.description.references Jiang, J., Yu, J., & Corma, A. (2010). Extra-Large-Pore Zeolites: Bridging the Gap between Micro and Mesoporous Structures. Angewandte Chemie International Edition, 49(18), 3120-3145. doi:10.1002/anie.200904016 es_ES
dc.description.references Jiang, J., Yu, J., & Corma, A. (2010). Zeolithe mit sehr großen Poren als Bindeglied zwischen mikro- und mesoporösen Strukturen. Angewandte Chemie, 122(18), 3186-3212. doi:10.1002/ange.200904016 es_ES
dc.description.references Shayib, R. M., George, N. C., Seshadri, R., Burton, A. W., Zones, S. I., & Chmelka, B. F. (2011). Structure-Directing Roles and Interactions of Fluoride and Organocations with Siliceous Zeolite Frameworks. Journal of the American Chemical Society, 133(46), 18728-18741. doi:10.1021/ja205164u es_ES
dc.description.references International Zeolite Association Website http://www.iza-online.org/(accessed October 4 2018). es_ES
dc.description.references Pinar, A. B., McCusker, L. B., Baerlocher, C., Hwang, S.-J., Xie, D., Benin, A. I., & Zones, S. I. (2016). Synthesis and structural characterization of Zn-containing DAF-1. New Journal of Chemistry, 40(5), 4160-4166. doi:10.1039/c5nj02897c es_ES
dc.description.references Dorset, D. L., Kennedy, G. J., Strohmaier, K. G., Diaz-Cabañas, M. J., Rey, F., & Corma, A. (2006). P-Derived Organic Cations as Structure-Directing Agents:  Synthesis of a High-Silica Zeolite (ITQ-27) with a Two-Dimensional 12-Ring Channel System. Journal of the American Chemical Society, 128(27), 8862-8867. doi:10.1021/ja061206o es_ES
dc.description.references Corma, A., Diaz-Cabanas, M. J., Jorda, J. L., Rey, F., Sastre, G., & Strohmaier, K. G. (2008). A Zeolitic Structure (ITQ-34) with Connected 9- and 10-Ring Channels Obtained with Phosphonium Cations as Structure Directing Agents. Journal of the American Chemical Society, 130(49), 16482-16483. doi:10.1021/ja806903c es_ES
dc.description.references Corma, A., Diaz-Cabanas, M. J., Jiang, J., Afeworki, M., Dorset, D. L., Soled, S. L., & Strohmaier, K. G. (2010). Extra-large pore zeolite (ITQ-40) with the lowest framework density containing double four- and double three-rings. Proceedings of the National Academy of Sciences, 107(32), 13997-14002. doi:10.1073/pnas.1003009107 es_ES
dc.description.references Hernández-Rodríguez, M., Jordá, J. L., Rey, F., & Corma, A. (2012). Synthesis and Structure Determination of a New Microporous Zeolite with Large Cavities Connected by Small Pores. Journal of the American Chemical Society, 134(32), 13232-13235. doi:10.1021/ja306013k es_ES
dc.description.references Simancas, J., Simancas, R., Bereciartua, P. J., Jorda, J. L., Rey, F., Corma, A., … Mugnaioli, E. (2016). Ultrafast Electron Diffraction Tomography for Structure Determination of the New Zeolite ITQ-58. Journal of the American Chemical Society, 138(32), 10116-10119. doi:10.1021/jacs.6b06394 es_ES
dc.description.references Jo, C., Lee, S., Cho, S. J., & Ryoo, R. (2015). Synthesis of Silicate Zeolite Analogues Using Organic Sulfonium Compounds as Structure-Directing Agents. Angewandte Chemie International Edition, 54(43), 12805-12808. doi:10.1002/anie.201506678 es_ES
dc.description.references Jo, C., Lee, S., Cho, S. J., & Ryoo, R. (2015). Synthesis of Silicate Zeolite Analogues Using Organic Sulfonium Compounds as Structure-Directing Agents. Angewandte Chemie, 127(43), 12996-12999. doi:10.1002/ange.201506678 es_ES
dc.description.references Lee, S., Jo, C., Park, H., Kim, J., & Ryoo, R. (2019). Sulfonium-based organic structure-directing agents for microporous aluminophosphate synthesis. Microporous and Mesoporous Materials, 280, 75-81. doi:10.1016/j.micromeso.2019.01.048 es_ES
dc.description.references Fattorini, D., Notti, A., & Regoli, F. (2006). Characterization of arsenic content in marine organisms from temperate, tropical, and polar environments. Chemistry and Ecology, 22(5), 405-414. doi:10.1080/02757540600917328 es_ES
dc.description.references Bonilla, G., Díaz, I., Tsapatsis, M., Jeong, H.-K., Lee, Y., & Vlachos, D. G. (2004). Zeolite (MFI) Crystal Morphology Control Using Organic Structure-Directing Agents. Chemistry of Materials, 16(26), 5697-5705. doi:10.1021/cm048854w es_ES
dc.description.references Van Koningsveld, H., van Bekkum, H., & Jansen, J. C. (1987). On the location and disorder of the tetrapropylammonium (TPA) ion in zeolite ZSM-5 with improved framework accuracy. Acta Crystallographica Section B Structural Science, 43(2), 127-132. doi:10.1107/s0108768187098173 es_ES
dc.description.references Fyfe, C. A., Brouwer, D. H., Lewis, A. R., & Chézeau, J.-M. (2001). Location of the Fluoride Ion in Tetrapropylammonium Fluoride Silicalite-1 Determined by1H/19F/29Si Triple Resonance CP, REDOR, and TEDOR NMR Experiments. Journal of the American Chemical Society, 123(28), 6882-6891. doi:10.1021/ja010532v es_ES
dc.description.references Balimann, G., & Pregosin, P. . (1977). Arsenic-75 nuclear magnetic resonance. A study of some arsenic salts. Journal of Magnetic Resonance (1969), 26(2), 283-289. doi:10.1016/0022-2364(77)90174-3 es_ES
dc.description.references Klinowski, J. (1991). Solid-state NMR studies of molecular sieve catalysts. Chemical Reviews, 91(7), 1459-1479. doi:10.1021/cr00007a010 es_ES
dc.description.references Canche-Tello, J., Vargas, M. C., Hérnandez-Cobos, J., Ortega-Blake, I., Leclercq, A., Solari, P. L., … Mustre de Leon, J. (2015). X-ray Accelerated Photo-Oxidation of As(III) in Solution. The Journal of Physical Chemistry A, 119(12), 2829-2833. doi:10.1021/jp510596p es_ES
dc.description.references Arai, Y., Elzinga, E. J., & Sparks, D. L. (2001). X-ray Absorption Spectroscopic Investigation of Arsenite and Arsenate Adsorption at the Aluminum Oxide–Water Interface. Journal of Colloid and Interface Science, 235(1), 80-88. doi:10.1006/jcis.2000.7249 es_ES
dc.description.references Farquhar, M. L., Charnock, J. M., Livens, F. R., & Vaughan, D. J. (2002). Mechanisms of Arsenic Uptake from Aqueous Solution by Interaction with Goethite, Lepidocrocite, Mackinawite, and Pyrite:  An X-ray Absorption Spectroscopy Study. Environmental Science & Technology, 36(8), 1757-1762. doi:10.1021/es010216g es_ES
dc.description.references Morin, G., Ona-Nguema, G., Wang, Y., Menguy, N., Juillot, F., Proux, O., … Brown Jr., G. E. (2008). Extended X-ray Absorption Fine Structure Analysis of Arsenite and Arsenate Adsorption on Maghemite. Environmental Science & Technology, 42(7), 2361-2366. doi:10.1021/es072057s es_ES
dc.description.references Ramírez-Solís, A., Mukopadhyay, R., Rosen, B. P., & Stemmler, T. L. (2004). Experimental and Theoretical Characterization of Arsenite in Water:  Insights into the Coordination Environment of As−O. Inorganic Chemistry, 43(9), 2954-2959. doi:10.1021/ic0351592 es_ES
dc.description.references Prieto, C., Blasco, T., Camblor, M., & Pérez-Pariente, J. (2000). Characterization of Ga-substituted zeolite Beta by X-ray absorption spectroscopy. Journal of Materials Chemistry, 10(6), 1383-1387. doi:10.1039/b001643h es_ES
dc.description.references Lamberti, C., Turnes Palomino, G., Bordiga, S., Zecchina, A., Spanò, G., & Otero Areán, C. (1999). Catalysis Letters, 63(3/4), 213-216. doi:10.1023/a:1019025206662 es_ES
dc.description.references Axon, S. A., Huddersman, K., & Klinowski, J. (1990). Gallium EXAFS and solid-state NMR studies of Ga-substituted MFI-type zeolites. Chemical Physics Letters, 172(5), 398-404. doi:10.1016/s0009-2614(90)87133-c es_ES


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