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Influence of the synthesis method on the catalytic activity of mayenite for the oxidation of gas-phase trichloroethylene

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Influence of the synthesis method on the catalytic activity of mayenite for the oxidation of gas-phase trichloroethylene

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dc.contributor.author Intiso, Adriano es_ES
dc.contributor.author Martínez-Triguero, Joaquín es_ES
dc.contributor.author Cucciniello, Raffaele es_ES
dc.contributor.author Rossi, Federico es_ES
dc.contributor.author Palomares Gimeno, Antonio Eduardo es_ES
dc.date.accessioned 2021-02-04T04:31:46Z
dc.date.available 2021-02-04T04:31:46Z
dc.date.issued 2019-01-23 es_ES
dc.identifier.issn 2045-2322 es_ES
dc.identifier.uri http://hdl.handle.net/10251/160674
dc.description.abstract [EN] Catalytic oxidation of trichloroethylene (TCE) in heterogeneous phase (gas-solid) is an effective strategy for the conversion of this pollutant in less harmful compounds, namely CO2, CO and HCl. In this work, we have studied the use of mayenite, a cost-effective material, as an active catalyst for the TCE conversion. In particular, we have assessed the influence of the mayenite synthesis method (hydrothermal, sol-gel and ceramic) on the reaction performance. The materials have been characterized by different techniques, such as XRD, N-2-sorption (BET), TPR, Raman spectroscopy, FESEM-EDX and TEM. The analysis of the light-off curves and product distribution, has shown that the use of the hydrothermal method for the mayenite synthesis results in the most active and selective catalyst. This has been related with a higher surface area and with a higher concentration of oxygen anions in the mayenite prepared by this method. It has been found that the presence of water in the stream do not influence the catalytic performance of the material. A mechanism for the reaction and for the partial deactivation of the catalyst has been proposed. es_ES
dc.description.sponsorship This work was supported by the grants ORSA167988 and ORSA174250 funded by the University of Salerno. AI gratefully acknowledges the Erasmus+ traineeship program. AEP and JMT thanks the Spanish Ministry of Economy and Competitiveness and the Fondo Europeo de Desarrollo Regional through MAT2015-71842-P and CTQ2015-68951-C3-1-R (MINECO/FEDER) es_ES
dc.language Inglés es_ES
dc.publisher Nature Publishing Group es_ES
dc.relation.ispartof Scientific Reports es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Influence of the synthesis method on the catalytic activity of mayenite for the oxidation of gas-phase trichloroethylene es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1038/s41598-018-36708-2 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-71842-P/ES/SINTESIS Y CARACTERIZACION AVANZADA DE NUEVOS MATERIALES ZEOLITICOS Y APLICACIONES EN ADSORCION, MEDIOAMBIENTE Y EN LA CONSERVACION DE ALIMENTOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2015-68951-C3-1-R/ES/TRATAMIENTOS CATALITICOS AVANZADOS PARA LA VALORIZACION DE LA BIOMASA Y LA ELIMINACION DE RESIDUOS ASOCIADOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNISA//ORSA167988/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNISA//ORSA174250/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Intiso, A.; Martínez-Triguero, J.; Cucciniello, R.; Rossi, F.; Palomares Gimeno, AE. (2019). Influence of the synthesis method on the catalytic activity of mayenite for the oxidation of gas-phase trichloroethylene. Scientific Reports. 9:1-9. https://doi.org/10.1038/s41598-018-36708-2 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1038/s41598-018-36708-2 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 9 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 9 es_ES
dc.identifier.pmid 30674937 es_ES
dc.identifier.pmcid PMC6344594 es_ES
dc.relation.pasarela S\385677 es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Università degli Studi di Salerno es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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