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A comparative study on the reactive compatibilization of melt-processed polyamide 1010/polylactide blends by multi-functionalized additives derived from linseed oil and petroleum

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A comparative study on the reactive compatibilization of melt-processed polyamide 1010/polylactide blends by multi-functionalized additives derived from linseed oil and petroleum

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dc.contributor.author Quiles-Carrillo, Luis es_ES
dc.contributor.author Fenollar, Octavio es_ES
dc.contributor.author Balart, Rafael es_ES
dc.contributor.author Torres-Giner, S. es_ES
dc.contributor.author Rallini, M. es_ES
dc.contributor.author Dominici, F. es_ES
dc.contributor.author Torre, L. es_ES
dc.date.accessioned 2021-02-09T04:32:09Z
dc.date.available 2021-02-09T04:32:09Z
dc.date.issued 2020-06 es_ES
dc.identifier.issn 1788-618X es_ES
dc.identifier.uri http://hdl.handle.net/10251/160903
dc.description.abstract [EN] This research work describes the manufacturing and characterization of novel engineering materials consisted of fully bio-based blends of polyamide 1010 (PA1010) with 20 wt% of polylactide (PLA). Four different compatibilizers were used to enhance the miscibility and the performance of the biopolymer blends. Two multi-functionalized vegetable oils (maleinized linseed oil (MLO) and epoxidized linseed oil (ELO)) and two petroleum-derived glycidyl-based additives (epoxy styrene-acrylic oligomer (ESAO) and styrene-glycidyl methacrylate copolymer (PS-GMA)) were tested during melt compounding. The resultant biopolymer blends were processed by either cast film extrusion or injection molding to obtain films and pieces, respectively. Thin films with an average thickness of 50¿60 µm and thick pieces of 4 mm were obtained, and their mechanical, morphological, thermal, thermomechanical, barrier and, optical properties were characterized. Although all four compatibilizers successfully provided compatibilization to the blends, the chemically modified vegetable oils, that is, MLO and ELO yielded the injection-molded pieces with the most balanced mechanical properties in terms of strength and toughness. Besides, the resultant films showed very low oxygen transmission rate values, thus broadening the potential of these biopolymer blends for the food packaging industry es_ES
dc.description.sponsorship This research work was funded by the Spanish Ministry of Science, Innovation, and Universities (MICIU) project numbers MAT2017-84909-C2-2-R and AGL2015-63855-C2-1-R. Quiles-Carrillo and Torres-Giner are recipients of a FPU grant (FPU15/03812) from the Spanish Ministry of Education, Culture, and Sports (MECD) and a Juan de la Cierva contract (IJCI-2016-29675) from MICIU, respectively. Microscopy services at UPV are acknowledged for their help in collecting and analyzing FESEM images. Authors thank Polyscope for kindly supplying XibondTM 920 for this study. es_ES
dc.language Inglés es_ES
dc.publisher Department of Polymer Engineering Budapest University of Technology & Economics), Scientific Society of Mechanical Engineerin es_ES
dc.relation Agencia Estatal de Investigación/IJCI-2016-29675 es_ES
dc.relation MICINN/AGL2015-63855-C2-1-R es_ES
dc.relation MECYD/FPU15/03812 es_ES
dc.relation info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ es_ES
dc.relation.ispartof eXPRESS Polymer Letters es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Biopolymers es_ES
dc.subject Biocomposites es_ES
dc.subject Bio-based polyamides es_ES
dc.subject Multi-functionalized vegetable oils es_ES
dc.subject Reactive compatibilization es_ES
dc.subject.classification TECNOLOGIA DE ALIMENTOS es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title A comparative study on the reactive compatibilization of melt-processed polyamide 1010/polylactide blends by multi-functionalized additives derived from linseed oil and petroleum es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3144/expresspolymlett.2020.48 es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario de Ingeniería de Alimentos para el Desarrollo - Institut Universitari d'Enginyeria d'Aliments per al Desenvolupament es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation Quiles-Carrillo, L.; Fenollar, O.; Balart, R.; Torres-Giner, S.; Rallini, M.; Dominici, F.; Torre, L. (2020). A comparative study on the reactive compatibilization of melt-processed polyamide 1010/polylactide blends by multi-functionalized additives derived from linseed oil and petroleum. eXPRESS Polymer Letters. 14(6):583-604. https://doi.org/10.3144/expresspolymlett.2020.48 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3144/expresspolymlett.2020.48 es_ES
dc.description.upvformatpinicio 583 es_ES
dc.description.upvformatpfin 604 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 14 es_ES
dc.description.issue 6 es_ES
dc.relation.pasarela S\408457 es_ES
dc.contributor.funder Ministerio de Educación es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Ciencia, Innovación y Universidades es_ES


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