- -

Influence of Ultraviolet Radiation Exposure Time on Styrene-Ethylene-Butadiene-Styrene (SEBS) Copolymer

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

Influence of Ultraviolet Radiation Exposure Time on Styrene-Ethylene-Butadiene-Styrene (SEBS) Copolymer

Mostrar el registro sencillo del ítem

Ficheros en el ítem

dc.contributor.author Garcia-Garcia, Daniel es_ES
dc.contributor.author Crespo, J.E es_ES
dc.contributor.author Parres, F. es_ES
dc.contributor.author Samper, María-Dolores es_ES
dc.date.accessioned 2021-03-01T08:08:15Z
dc.date.available 2021-03-01T08:08:15Z
dc.date.issued 2020-04 es_ES
dc.identifier.uri http://hdl.handle.net/10251/162563
dc.description.abstract [EN] The effect of ultraviolet radiation on styrene-ethylene-butadiene-styrene (SEBS) has been studied at different exposures times in order to obtain a better understanding of the mechanism of ageing. The polymer materials were mechanically tested and then their surfaces were analyzed using a scanning electron microscope (SEM) and atomic force microscopy (AFM). Moreover, the optical analysis of contact angle (OCA) was used to evaluate the surface energy (gamma(s)) and the yellowing index (YI) and attenuated total reflectance infrared spectroscopy (ATR-FTIR) were used to observe structural and physical changes in aging SEBS. The results obtained for the SEBS, in relation to the duration of exposure, showed superficial changes that cause a decrease in the surface energy (gamma(s)) and, therefore, a decrease in surface roughness. This led to a reduction in mechanical performance, decreasing the tensile strength by about 50% for exposure times of around 200 hours. es_ES
dc.description.sponsorship This work was supported by the Ministry of Economy and Competitiveness (MINECO) grant number MAT2017-84909-C2-2-R). Daniel Garcia-Garcia acknowledges Generalitat Valenciana (GVA) for financial support through a postdoctoral contract (APOSTD/2019/201). es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Polymers es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Surface modification es_ES
dc.subject Degradation es_ES
dc.subject AFM es_ES
dc.subject Mechanical properties es_ES
dc.subject Block copolymer es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Influence of Ultraviolet Radiation Exposure Time on Styrene-Ethylene-Butadiene-Styrene (SEBS) Copolymer es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/polym12040862 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//APOSTD%2F2019%2F201/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.description.bibliographicCitation Garcia-Garcia, D.; Crespo, J.; Parres, F.; Samper, M. (2020). Influence of Ultraviolet Radiation Exposure Time on Styrene-Ethylene-Butadiene-Styrene (SEBS) Copolymer. Polymers. 12(4):1-14. https://doi.org/10.3390/polym12040862 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/polym12040862 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 14 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 4 es_ES
dc.identifier.eissn 2073-4360 es_ES
dc.relation.pasarela S\408420 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.description.references Picchioni, F., Giorgi, I., Passaglia, E., Ruggeri, G., & Aglietto, M. (2001). Blending of styrene-block-butadiene-block-styrene copolymer with sulfonated vinyl aromatic polymers. Polymer International, 50(6), 714-721. doi:10.1002/pi.692 es_ES
dc.description.references Zhu, J., Birgisson, B., & Kringos, N. (2014). Polymer modification of bitumen: Advances and challenges. European Polymer Journal, 54, 18-38. doi:10.1016/j.eurpolymj.2014.02.005 es_ES
dc.description.references Gupta, S., Chandra, T., Sikder, A., Menon, A., & Bhowmick, A. K. (2008). Accelerated weathering behavior of poly(phenylene ether)-based TPE. Journal of Materials Science, 43(9), 3338-3350. doi:10.1007/s10853-008-2484-6 es_ES
dc.description.references Mamodia, M., Indukuri, K., Atkins, E. T., De Jeu, W. H., & Lesser, A. J. (2008). Hierarchical description of deformation in block copolymer TPEs. Journal of Materials Science, 43(22), 7035-7046. doi:10.1007/s10853-008-3030-2 es_ES
dc.description.references Allen, N. S., Edge, M., Wilkinson, A., Liauw, C. M., Mourelatou, D., Barrio, J., & Martı́nez-Zaporta, M. A. (2000). Degradation and stabilisation of styrene–ethylene–butadiene–styrene (SEBS) block copolymer. Polymer Degradation and Stability, 71(1), 113-122. doi:10.1016/s0141-3910(00)00162-2 es_ES
dc.description.references Costa, P., Ribeiro, S., Botelho, G., Machado, A. V., & Lanceros Mendez, S. (2015). Effect of butadiene/styrene ratio, block structure and carbon nanotube content on the mechanical and electrical properties of thermoplastic elastomers after UV ageing. Polymer Testing, 42, 225-233. doi:10.1016/j.polymertesting.2015.02.002 es_ES
dc.description.references Tomacheski, D., Pittol, M., Lopes, A. P. M., Simões, D. N., Ribeiro, V. F., & Santana, R. M. C. (2017). Effects of Weathering on Mechanical, Antimicrobial Properties and Biodegradation Process of Silver Loaded TPE Compounds. Journal of Polymers and the Environment, 26(1), 73-82. doi:10.1007/s10924-016-0927-8 es_ES
dc.description.references Singh, B., & Sharma, N. (2008). Mechanistic implications of plastic degradation. Polymer Degradation and Stability, 93(3), 561-584. doi:10.1016/j.polymdegradstab.2007.11.008 es_ES
dc.description.references White, C. C., Tan, K. T., Hunston, D. L., Nguyen, T., Benatti, D. J., Stanley, D., & Chin, J. W. (2011). Laboratory accelerated and natural weathering of styrene–ethylene–butylene–styrene (SEBS) block copolymer. Polymer Degradation and Stability, 96(6), 1104-1110. doi:10.1016/j.polymdegradstab.2011.03.003 es_ES
dc.description.references Allen, N. (2004). Photooxidation of styrene–ethylene–butadiene–styrene (SEBS) block copolymer. Journal of Photochemistry and Photobiology A: Chemistry, 162(1), 41-51. doi:10.1016/s1010-6030(03)00311-3 es_ES
dc.description.references Flaris, V., & Stachurski, Z. H. (1992). The effects of processing on the mechanical properties of a polyolefin blend. Polymer International, 27(3), 267-273. doi:10.1002/pi.4990270312 es_ES
dc.description.references Li, Y., Li, L., Zhang, Y., Zhao, S., Xie, L., & Yao, S. (2009). Improving the aging resistance of styrene-butadiene-styrene tri-block copolymer and application in polymer-modified asphalt. Journal of Applied Polymer Science, n/a-n/a. doi:10.1002/app.31458 es_ES
dc.description.references Xu, X., Yu, J., Xue, L., Zhang, C., He, B., & Wu, M. (2017). Structure and performance evaluation on aged SBS modified bitumen with bi- or tri-epoxy reactive rejuvenating system. Construction and Building Materials, 151, 479-486. doi:10.1016/j.conbuildmat.2017.06.102 es_ES
dc.description.references Si Bachir, D., Dekhli, S., & Ait Mokhtar, K. (2016). Rheological Evaluation of Ageing Properties of SEBS Polymer Modified Bitumens. Periodica Polytechnica Civil Engineering, 397-404. doi:10.3311/ppci.7853 es_ES
dc.description.references Awaja, F., Gilbert, M., Kelly, G., Fox, B., & Pigram, P. J. (2009). Adhesion of polymers. Progress in Polymer Science, 34(9), 948-968. doi:10.1016/j.progpolymsci.2009.04.007 es_ES
dc.description.references Poisson, C., Hervais, V., Lacrampe, M. F., & Krawczak, P. (2006). Optimization of PE/binder/PA extrusion blow-molded films. II. Adhesion properties improvement using binder/EVA blends. Journal of Applied Polymer Science, 101(1), 118-127. doi:10.1002/app.22407 es_ES
dc.description.references Zhang, H., Guo, W., Yu, Y., Li, B., & Wu, C. (2007). Structure and properties of compatibilized recycled poly(ethylene terephthalate)/linear low density polyethylene blends. European Polymer Journal, 43(8), 3662-3670. doi:10.1016/j.eurpolymj.2007.05.001 es_ES
dc.description.references Guerrica-Echevarría, G., Eguiazábal, J. I., & Nazábal, J. (2007). Influence of compatibilization on the mechanical behavior of poly(trimethylene terephthalate)/poly(ethylene–octene) blends. European Polymer Journal, 43(3), 1027-1037. doi:10.1016/j.eurpolymj.2006.11.036 es_ES
dc.description.references Chang, Y.-W., Shin, J.-Y., & Ryu, S. H. (2004). Preparation and properties of styrene–ethylene/butylene–styrene(SEBS)–clay hybrids. Polymer International, 53(8), 1047-1051. doi:10.1002/pi.1480 es_ES
dc.description.references Chen, W.-C., Lai, S.-M., & Chen, C.-M. (2008). Preparation and properties of styrene-ethylene-butylene-styrene block copolymer/clay nanocomposites: I. Effect of clay content and compatibilizer types. Polymer International, 57(3), 515-522. doi:10.1002/pi.2377 es_ES
dc.description.references Qin, R.-Y., & Schreiber, H. P. (1999). Adhesion at partially restructured polymer surfaces. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 156(1-3), 85-93. doi:10.1016/s0927-7757(99)00061-8 es_ES
dc.description.references Zhang, X., Xie, F., Pen, Z., Zhang, Y., Zhang, Y., & Zhou, W. (2002). Effect of nucleating agent on the structure and properties of polypropylene/poly(ethylene–octene) blends. European Polymer Journal, 38(1), 1-6. doi:10.1016/s0014-3057(01)00182-3 es_ES
dc.description.references Beholz, L. G., Aronson, C. L., & Zand, A. (2005). Adhesion modification of polyolefin surfaces with sodium hypochlorite in acidic media. Polymer, 46(13), 4604-4613. doi:10.1016/j.polymer.2005.03.086 es_ES
dc.description.references Kinloch, A. J. (1980). The science of adhesion. Journal of Materials Science, 15(9), 2141-2166. doi:10.1007/bf00552302 es_ES
dc.description.references Lippert, T., & Dickinson, J. T. (2003). Chemical and Spectroscopic Aspects of Polymer Ablation:  Special Features and Novel Directions. Chemical Reviews, 103(2), 453-486. doi:10.1021/cr010460q es_ES
dc.description.references Van der Leeden, M. C., & Frens, G. (2002). Surface Properties of Plastic Materials in Relation to Their Adhering Performance. Advanced Engineering Materials, 4(5), 280-289. doi:10.1002/1527-2648(20020503)4:5<280::aid-adem280>3.0.co;2-z es_ES
dc.description.references Pukánszky, B. (2005). Interfaces and interphases in multicomponent materials: past, present, future. European Polymer Journal, 41(4), 645-662. doi:10.1016/j.eurpolymj.2004.10.035 es_ES
dc.description.references Tjong, S. C., Xu, S.-A., & Mai, Y.-W. (2003). Journal of Materials Science, 38(2), 207-215. doi:10.1023/a:1021132725370 es_ES
dc.description.references Sanchis, R., Fenollar, O., García, D., Sánchez, L., & Balart, R. (2008). Improved adhesion of LDPE films to polyolefin foams for automotive industry using low-pressure plasma. International Journal of Adhesion and Adhesives, 28(8), 445-451. doi:10.1016/j.ijadhadh.2008.04.002 es_ES
dc.description.references Brockmann, W., & Hüther, R. (1996). Adhesion mechanisms of pressure sensitive adhesives. International Journal of Adhesion and Adhesives, 16(2), 81-86. doi:10.1016/0143-7496(96)89797-1 es_ES
dc.description.references Brovko, O., Rosso, P., & Friedrich, K. (2002). Journal of Materials Science Letters, 21(4), 305-308. doi:10.1023/a:1017936206578 es_ES
dc.description.references Court, R. S., Sutcliffe, M. P. F., & Tavakoli, S. M. (2001). Ageing of adhesively bonded joints—fracture and failure analysis using video imaging techniques. International Journal of Adhesion and Adhesives, 21(6), 455-463. doi:10.1016/s0143-7496(01)00022-7 es_ES
dc.description.references Komvopoulos, K. (2003). Adhesion and friction forces in microelectromechanical systems: mechanisms, measurement, surface modification techniques, and adhesion theory. Journal of Adhesion Science and Technology, 17(4), 477-517. doi:10.1163/15685610360554384 es_ES
dc.description.references Pijpers, A. ., & Meier, R. J. (2001). Adhesion behaviour of polypropylenes after flame treatment determined by XPS(ESCA) spectral analysis. Journal of Electron Spectroscopy and Related Phenomena, 121(1-3), 299-313. doi:10.1016/s0368-2048(01)00341-3 es_ES
dc.description.references Yu, S., Hu, H., Zhang, Y., & Liu, Y. (2008). Effect of transfer film on tribological behavior of polyamide 66-based binary and ternary nanocomposites. Polymer International, 57(3), 454-462. doi:10.1002/pi.2337 es_ES
dc.description.references Żenkiewicz, M. (2007). Comparative study on the surface free energy of a solid calculated by different methods. Polymer Testing, 26(1), 14-19. doi:10.1016/j.polymertesting.2006.08.005 es_ES
dc.description.references Kumar, S., & Misra, R. K. (2007). Analysis of Banana Fibers Reinforced Low‐density Polyethylene/Poly(Є‐caprolactone) Composites. Soft Materials, 4(1), 1-13. doi:10.1080/15394450600823040 es_ES
dc.description.references Fowkes, F. ., McCarthy, D. ., & Mostafa, M. . (1980). Contact angles and the equilibrium spreading pressures of liquids on hydrophobic solids. Journal of Colloid and Interface Science, 78(1), 200-206. doi:10.1016/0021-9797(80)90508-1 es_ES
dc.description.references Owens, D. K., & Wendt, R. C. (1969). Estimation of the surface free energy of polymers. Journal of Applied Polymer Science, 13(8), 1741-1747. doi:10.1002/app.1969.070130815 es_ES
dc.description.references Zhao, Y., Tang, S., Myung, S.-W., Lu, N., & Choi, H.-S. (2006). Effect of washing on surface free energy of polystyrene plate treated by RF atmospheric pressure plasma. Polymer Testing, 25(3), 327-332. doi:10.1016/j.polymertesting.2005.12.007 es_ES
dc.description.references Hänni‐Ciunel, K., Findenegg, G. H., & von Klitzing, R. (2007). Water Contact Angle On Polyelectrolyte‐Coated Surfaces: Effects of Film Swelling and Droplet Evaporation. Soft Materials, 5(2-3), 61-73. doi:10.1080/15394450701554452 es_ES
dc.description.references Radovanovic, E., Carone, E., & Gonçalves, M. . (2004). Comparative AFM and TEM investigation of the morphology of nylon6-rubber blends. Polymer Testing, 23(2), 231-237. doi:10.1016/s0142-9418(03)00099-0 es_ES
dc.description.references Drnovská, H., Lapčík, L., Buršíková, V., Zemek, J., & Barros-Timmons, A. M. (2003). Surface properties of polyethylene after low-temperature plasma treatment. Colloid and Polymer Science, 281(11), 1025-1033. doi:10.1007/s00396-003-0871-8 es_ES
dc.description.references Lehocký, M., Drnovská, H., Lapčı́ková, B., Barros-Timmons, A. ., Trindade, T., Zembala, M., & Lapčı́k, L. (2003). Plasma surface modification of polyethylene. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 222(1-3), 125-131. doi:10.1016/s0927-7757(03)00242-5 es_ES
dc.description.references Ortiz-Magán, A. B., Pastor-Blas, M. M., Ferrándiz-Gómez, T. P., Morant-Zacarés, C., & Martín-Martínez, J. M. (2001). Plasmas and Polymers, 6(1/2), 81-105. doi:10.1023/a:1011352903775 es_ES
dc.description.references Mailhot, B., & Gardette, J. L. (1992). Polystyrene photooxidation. 2. A pseudo wavelength effect. Macromolecules, 25(16), 4127-4133. doi:10.1021/ma00042a013 es_ES
dc.description.references Mailhot, B., Jarroux, N., & Gardette, J.-L. (2000). Comparative analysis of the photo-oxidation of polystyrene and poly(α-methylstyrene). Polymer Degradation and Stability, 68(3), 321-326. doi:10.1016/s0141-3910(00)00016-1 es_ES
dc.description.references Luengo, C., Allen, N. S., Edge, M., Wilkinson, A., Parellada, M. D., Barrio, J. A., & Santa, V. R. (2006). Photo-oxidative degradation mechanisms in styrene–ethylene–butadiene–styrene (SEBS) triblock copolymer. Polymer Degradation and Stability, 91(4), 947-956. doi:10.1016/j.polymdegradstab.2005.06.017 es_ES
dc.description.references Han, X., Zhou, L., Liu, H., & Hu, Y. (2007). Effect of in situ oxidization with potassium permanganate on the morphologies of SEBS membranes. Polymer Degradation and Stability, 92(1), 75-85. doi:10.1016/j.polymdegradstab.2006.09.006 es_ES
dc.description.references Allen, N. S., Edge, M., Mourelatou, D., Wilkinson, A., Liauw, C. M., Dolores Parellada, M., … Ruiz Santa Quiteria, V. (2003). Influence of ozone on styrene–ethylene–butylene–styrene (SEBS) copolymer. Polymer Degradation and Stability, 79(2), 297-307. doi:10.1016/s0141-3910(02)00293-8 es_ES
dc.description.references Fombuena, V., Balart, J., Boronat, T., Sánchez-Nácher, L., & Garcia-Sanoguera, D. (2013). Improving mechanical performance of thermoplastic adhesion joints by atmospheric plasma. Materials & Design, 47, 49-56. doi:10.1016/j.matdes.2012.11.031 es_ES
dc.description.references Sanchis, M. R., Calvo, O., Fenollar, O., Garcia, D., & Balart, R. (2008). Characterization of the surface changes and the aging effects of low-pressure nitrogen plasma treatment in a polyurethane film. Polymer Testing, 27(1), 75-83. doi:10.1016/j.polymertesting.2007.09.002 es_ES
dc.description.references Sheikhy, H., Shahidzadeh, M., Ramezanzadeh, B., & Noroozi, F. (2013). Studying the effects of chain extenders chemical structures on the adhesion and mechanical properties of a polyurethane adhesive. Journal of Industrial and Engineering Chemistry, 19(6), 1949-1955. doi:10.1016/j.jiec.2013.03.008 es_ES
dc.description.references Švab, I., Musil, V., Šmit, I., & Makarovič, M. (2007). Mechanical properties of wollastonite-reinforced polypropylene composites modified with SEBS and SEBS-g-MA elastomers. Polymer Engineering & Science, 47(11), 1873-1880. doi:10.1002/pen.20897 es_ES
dc.description.references Sanchis, M. R., Blanes, V., Blanes, M., Garcia, D., & Balart, R. (2006). Surface modification of low density polyethylene (LDPE) film by low pressure O2 plasma treatment. European Polymer Journal, 42(7), 1558-1568. doi:10.1016/j.eurpolymj.2006.02.001 es_ES
dc.description.references Ganguly, A., & Bhowmick, A. K. (2009). Effect of polar modification on morphology and properties of styrene-(ethylene-co-butylene)-styrene triblock copolymer and its montmorillonite clay-based nanocomposites. Journal of Materials Science, 44(3), 903-918. doi:10.1007/s10853-008-3183-z es_ES


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem