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Characterization and Distillation of Pyrolysis Liquids Coming from Polyolefins Segregated of MSW for Their Use as Automotive Diesel Fuel

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Characterization and Distillation of Pyrolysis Liquids Coming from Polyolefins Segregated of MSW for Their Use as Automotive Diesel Fuel

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dc.contributor.author Gala, Alberto es_ES
dc.contributor.author Guerrero, Marta es_ES
dc.contributor.author Guirao, Beatriz es_ES
dc.contributor.author Domine, Marcelo Eduardo es_ES
dc.contributor.author Serra Alfaro, José Manuel es_ES
dc.date.accessioned 2021-03-24T04:31:33Z
dc.date.available 2021-03-24T04:31:33Z
dc.date.issued 2020-05-21 es_ES
dc.identifier.issn 0887-0624 es_ES
dc.identifier.uri http://hdl.handle.net/10251/164164
dc.description This document is the Accepted Manuscript version of a Published Work that appeared in final form in Energy & Fuels, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.energyfuels.0c00403. es_ES
dc.description.abstract [EN] The liquids resulting from pyrolysis of industrial plastic waste (IPW) and postconsumer colored and white plastic film waste (PCPW and PWPW, respectively) at the pilot scale (80 kg/h) were widely characterized by different techniques to assess their potential as both petrochemical raw material and automotive diesel fuel. It was found that pyrolysis liquids mainly consisted of hydrocarbons in the diesel boiling point range (180-380 degrees C), amounting to approximately 50-55 vol %. Therefore, the results were further contrasted with limits established by the EN 590:2014 + A1:2017 standard for automotive diesel fuel. Although pyrolysis liquids showed good properties, they do not conform to some key fuel parameters for diesel engines, such as density, distillation curve, kinematic viscosity, flash point, and cold filter plugging point. To improve these properties, PWPW pyrolysis liquids were distilled in the diesel range and the liquid fractions were characterized according to automotive diesel standards. It was found that the diesel fraction met all specifications with the exception of the cold filter plugging point (-10 to 4 degrees C vs -10 degrees C winter/0 degrees C summer) and density (800-807 vs 820 kg/m(3)). To accomplish these standards, a blend of diesel obtained from PWPW pyrolysis liquids and commercial diesel (50/50 wt %) was also prepared and analyzed. Results revealed that the blend met the requirements of the 21 parameters demanded by the standard for a product to be marketed and used as automotive fuel in diesel engine vehicles. es_ES
dc.description.sponsorship The authors acknowledge the financial support of the Centre for the Development of Industrial Technology (grant number IDI-20150730) and the Ministerio de Ciencia, Innovacion y Universidades (Spain) (grant number DI-16-08700). es_ES
dc.language Inglés es_ES
dc.publisher American Chemical Society es_ES
dc.relation.ispartof Energy & Fuels es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Plastic waste es_ES
dc.subject Pyrolysis es_ES
dc.subject Alternative fuel es_ES
dc.subject Distillation es_ES
dc.subject LDPE es_ES
dc.subject Transportation fuels es_ES
dc.subject Post-consumer plastic waste es_ES
dc.title Characterization and Distillation of Pyrolysis Liquids Coming from Polyolefins Segregated of MSW for Their Use as Automotive Diesel Fuel es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1021/acs.energyfuels.0c00403 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//IDI-20150730/ES/3R2020+ DEL RESIDUO AL RECURSO MEDIANTE EL RECICLAJE (1%2F7)/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI//DI-16-08700/ es_ES
dc.rights.accessRights Abierto es_ES
dc.description.bibliographicCitation Gala, A.; Guerrero, M.; Guirao, B.; Domine, ME.; Serra Alfaro, JM. (2020). Characterization and Distillation of Pyrolysis Liquids Coming from Polyolefins Segregated of MSW for Their Use as Automotive Diesel Fuel. Energy & Fuels. 34(5):5969-5982. https://doi.org/10.1021/acs.energyfuels.0c00403 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1021/acs.energyfuels.0c00403 es_ES
dc.description.upvformatpinicio 5969 es_ES
dc.description.upvformatpfin 5982 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 34 es_ES
dc.description.issue 5 es_ES
dc.relation.pasarela S\414254 es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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