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Catalytic oxidation of organic sulfides by H2O2 in the presence of titanosilicate zeolites

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Catalytic oxidation of organic sulfides by H2O2 in the presence of titanosilicate zeolites

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dc.contributor.author Radko, Marcelina es_ES
dc.contributor.author Rutkowska, Malgorzata es_ES
dc.contributor.author Kowalczyk, Andrzej es_ES
dc.contributor.author Mikrut, Pawel es_ES
dc.contributor.author Swies, Aneta es_ES
dc.contributor.author DÍAZ MORALES, URBANO MANUEL es_ES
dc.contributor.author Palomares Gimeno, Antonio Eduardo es_ES
dc.contributor.author Macyk, Wojciech es_ES
dc.contributor.author Chmielarz, Lucjan es_ES
dc.date.accessioned 2021-03-25T04:31:40Z
dc.date.available 2021-03-25T04:31:40Z
dc.date.issued 2020-08-01 es_ES
dc.identifier.issn 1387-1811 es_ES
dc.identifier.uri http://hdl.handle.net/10251/164219
dc.description.abstract [EN] Titanosilicate ferrierite zeolite (FER) and its delaminated form (ITQ-6), with various Si/Ti molar ratios, were synthetized and tested as catalysts for diphenyl sulfide (Ph2S) and dimethyl sulfide (DMS) oxidation with H2O2. The zeolites were characterized with respect to their chemical composition (ICP-OES), structure (XRD, UV-vis DRS) and texture (low-temperature N-2 adsorption-desorption). Titanium in the FER and ITQ-6 samples was present mainly in the zeolite framework with a significant contribution of titanium in the extraframework positions. Titanosilicate zeolites of FER and ITQ-6 series were found to be active catalysts of diphenyl and dimethyl sulfides oxidation by H2O2 to sulfoxides (Ph2SO/DMSO) and sulfones (Ph2SO2/DMSO2). The efficiency of these reactions depends on the porous structure of the zeolite catalysts - conversion of larger molecules of diphenyl sulfide was significantly higher in the presence of delaminated zeolite Ti-ITQ-6 due to the possibility of the interlayer mesopores penetration by reactants. On the other side diphenyl sulfide molecules are too large to be accommodated into micropores of FER zeolite. The efficiency of dimethyl sulfide conversion, due to relatively small size of this molecule, was similar in the presence of Ti-FER and Ti-ITQ-6 zeolites. For all catalysts, the organic sulfide conversion was significantly intensified under UV irradiation. It was suggested that Ti cations in the zeolite framework, as well as in the extraframework, species play a role of the single site photocatalysts active in the formation of hydroxyl radicals, which are known to be effective oxidants of the organic sulfides. es_ES
dc.description.sponsorship The studies were carried out in the frame of project 2016/21/B/ST5/00242 from the National Science Centre (Poland). Part of the research was done with equipment purchased in the frame of European Regional Development Fund (Polish Innovation Economy Operational Program -contract no. POIG.02.01.00-12-023/08). U.D. acknowledges to the Spanish Government by the funding (MAT2017-82288-C2-1-P). The work was partially supported by the Foundation for Polish Science (FNP) within the TEAM project (POIR.04.04.00-00-3D74/16). es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation FEDER/POIG.02.01.00-12-023/08 es_ES
dc.relation Ministerio Ciencia, Innovación y Universidades/MAT2017-82288-C2-1-P es_ES
dc.relation NCN/2016/21/B/ST5/00242 es_ES
dc.relation FNP/POIR.04.04.00-00-3D74/16 es_ES
dc.relation.ispartof Microporous and Mesoporous Materials es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Ti-ITQ-6 es_ES
dc.subject Ti-FER es_ES
dc.subject Diphenyl sulfide es_ES
dc.subject Dimethyl sulfide es_ES
dc.subject Oxidation es_ES
dc.subject H2O2 es_ES
dc.subject Catalysis es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Catalytic oxidation of organic sulfides by H2O2 in the presence of titanosilicate zeolites es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.micromeso.2020.110219 es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Radko, M.; Rutkowska, M.; Kowalczyk, A.; Mikrut, P.; Swies, A.; Díaz Morales, UM.; Palomares Gimeno, AE.... (2020). Catalytic oxidation of organic sulfides by H2O2 in the presence of titanosilicate zeolites. Microporous and Mesoporous Materials. 302:1-9. https://doi.org/10.1016/j.micromeso.2020.110219 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.micromeso.2020.110219 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 9 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 302 es_ES
dc.relation.pasarela S\420366 es_ES
dc.contributor.funder National Science Centre, Polonia es_ES
dc.contributor.funder Foundation for Polish Science es_ES
dc.contributor.funder European Regional Development Fund es_ES
dc.contributor.funder Ministerio de Ciencia, Innovación y Universidades es_ES
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