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dc.contributor.author | Cerezo-Navarrete, Christian | es_ES |
dc.contributor.author | Lara, Patricia | es_ES |
dc.contributor.author | Martínez-Prieto, Luis Miguel | es_ES |
dc.date.accessioned | 2021-04-21T03:31:26Z | |
dc.date.available | 2021-04-21T03:31:26Z | |
dc.date.issued | 2020-10 | es_ES |
dc.identifier.uri | http://hdl.handle.net/10251/165403 | |
dc.description.abstract | [EN] Over the last 20 years, the use of metallic nanoparticles (MNPs) in catalysis has awakened a great interest in the scientific community, mainly due to the many advantages of this kind of nanostructures in catalytic applications. MNPs exhibit the characteristic stability of heterogeneous catalysts, but with a higher active surface area than conventional metallic materials. However, despite their higher activity, MNPs present a wide variety of active sites, which makes it difficult to control their selectivity in catalytic processes. An efficient way to modulate the activity/selectivity of MNPs is the use of coordinating ligands, which transforms the MNP surface, subsequently modifying the nanoparticle catalytic properties. In relation to this, the use of N-heterocyclic carbenes (NHC) as stabilizing ligands has demonstrated to be an effective tool to modify the size, stability, solubility and catalytic reactivity of MNPs. Although NHC-stabilized MNPs can be prepared by different synthetic methods, this review is centered on those prepared by an organometallic approach. Here, an organometallic precursor is decomposed under H-2 in the presence of non-stoichiometric amounts of the corresponding NHC-ligand. The resulting organometallic nanoparticles present a clean surface, which makes them perfect candidates for catalytic applications and surface studies. In short, this revision study emphasizes the great versatility of NHC ligands as MNP stabilizers, as well as their influence on catalysis. | es_ES |
dc.description.sponsorship | This research was funded by: Proyectos Intramurales Especiales (201880E079), Primero Proyectos de Investigacion PAID-06-18 (SP20180088), Agencia Estatal de Investigacion (PID2019-104159GB-I00/AEI/10.13039/501100011033) and Junta de Andalucia (PY18-3208). The authors thank Instituto de Tecnología Química (ITQ), Consejo Superior de Investigaciones Científicas (CSIC), Universitat Politècnica de València (UPV), Departamento de Química Inorgánica (University of Seville), Institute for Chemical Research (IIQ) for the facilities and Severo Ochoa excellence programme, C.C.-N. thanks Generalitat Valenciana for the predoctoral GVA fellowship (ACIF/2019/076). We gratefully acknowledge B. Chaudret for his invaluable contribution to this research area and his sincere friendship. | es_ES |
dc.language | Inglés | es_ES |
dc.publisher | MDPI AG | es_ES |
dc.relation.ispartof | Catalysts | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | Organometallic nanoparticles | es_ES |
dc.subject | N-heterocyclic carbenes | es_ES |
dc.subject | Organometallic approach | es_ES |
dc.subject | Surface chemistry | es_ES |
dc.subject | Ligand effects | es_ES |
dc.subject | Catalysis | es_ES |
dc.subject | Hydrogenation reactions | es_ES |
dc.subject | H/D exchanges | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Organometallic Nanoparticles Ligated by NHCs: Synthesis, Surface Chemistry and Ligand Effects | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.3390/catal10101144 | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/CSIC//201880E079/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104159GB-I00/ES/SISTEMAS ORGANOMETALICOS PARA TRANSFORMACIONES ESTEQUIOMETRICAS Y CATALITICAS SELECTIVAS DE DERIVADOS ORGANICOS INSATURADOS/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/Junta de Andalucía//PY18-3208/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/GVA//ACIF%2F2019%2F076/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/UPV//SP20180088/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.description.bibliographicCitation | Cerezo-Navarrete, C.; Lara, P.; Martínez-Prieto, LM. (2020). Organometallic Nanoparticles Ligated by NHCs: Synthesis, Surface Chemistry and Ligand Effects. Catalysts. 10(10):1-30. https://doi.org/10.3390/catal10101144 | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | https://doi.org/10.3390/catal10101144 | es_ES |
dc.description.upvformatpinicio | 1 | es_ES |
dc.description.upvformatpfin | 30 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 10 | es_ES |
dc.description.issue | 10 | es_ES |
dc.identifier.eissn | 2073-4344 | es_ES |
dc.relation.pasarela | S\425416 | es_ES |
dc.contributor.funder | Junta de Andalucía | es_ES |
dc.contributor.funder | Generalitat Valenciana | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación | es_ES |
dc.contributor.funder | Universitat Politècnica de València | es_ES |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas | es_ES |
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