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Impact of Zeolite Framework Composition and Flexibility on Methanol-To-Olefins Selectivity: Confinement or Diffusion?

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Impact of Zeolite Framework Composition and Flexibility on Methanol-To-Olefins Selectivity: Confinement or Diffusion?

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Ferri-Vicedo, P.; Li, C.; Millán-Cabrera, R.; Martínez-Triguero, J.; Moliner Marin, M.; Boronat Zaragoza, M.; Corma Canós, A. (2020). Impact of Zeolite Framework Composition and Flexibility on Methanol-To-Olefins Selectivity: Confinement or Diffusion?. Angewandte Chemie International Edition. 59(44):19708-19715. https://doi.org/10.1002/anie.202007609

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Title: Impact of Zeolite Framework Composition and Flexibility on Methanol-To-Olefins Selectivity: Confinement or Diffusion?
Author: Ferri-Vicedo, Pau Li, Chengeng Millán-Cabrera, Reisel Martínez-Triguero, Joaquín Moliner Marin, Manuel Boronat Zaragoza, Mercedes Corma Canós, Avelino
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] The methanol-to-olefins reaction catalyzed by small-pore cage-based acid zeolites and zeotypes produces a mixture of short chain olefins, whose selectivity to ethene, propene and butene varies with the cavity architecture ...[+]
Subjects: Ab initio calculations , Diffusion , MTO , Reaction mechanism , Structure-selectivity relationship
Copyrigths: Reserva de todos los derechos
Source:
Angewandte Chemie International Edition. (issn: 1433-7851 )
DOI: 10.1002/anie.202007609
Publisher:
John Wiley & Sons
Publisher version: https://doi.org/10.1002/anie.202007609
Project ID:
info:eu-repo/grantAgreement/EC/H2020/671093/EU/MATching zeolite SYNthesis with CATalytic activity/
info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-82288-C2-1-P/ES/MATERIALES HIBRIDOS MULTIFUNCIONALES BASADOS EN NANO-UNIDADES ESTRUCTURALES ACTIVAS/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101033-B-I00/ES/DISEÑO DE CATALIZADORES MULTIFUNCIONALES PARA LA CONVERSION EFICIENTE DE BIOGAS Y GAS NATURAL A HIDROCARBUROS DE INTERES INDUSTRIAL/
info:eu-repo/grantAgreement/GVA//AICO%2F2019%2F060/
Description: This is the peer reviewed version of the following article: P. Ferri, C. Li, R. Millán, J. Martínez-Triguero, M. Moliner, M. Boronat, A. Corma, Angew. Chem. Int. Ed. 2020, 59, 19708, which has been published in final form at https://doi.org/10.1002/anie.202007609. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
Thanks:
This work has been supported by the European Union through ERC-AdG-2014-671093 (SynCatMatch), Spanish Government through "Severo Ochoa" (SEV-2016-0683, MINECO), MAT2017-82288-C2-1-P (AEI/FEDER, UE) and RTI2018-101033-B-I00 ...[+]
Type: Artículo

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