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Bimetallic iron-copper oxide nanoparticles supported on nanometric diamond as efficient and stable sunlight-assisted Fenton photocatalyst

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Bimetallic iron-copper oxide nanoparticles supported on nanometric diamond as efficient and stable sunlight-assisted Fenton photocatalyst

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dc.contributor.author Manickam-Periyaraman, Premkumar es_ES
dc.contributor.author Espinosa, Juan C. es_ES
dc.contributor.author Ferrer Ribera, Rosa Belén es_ES
dc.contributor.author Subramanian, Sivanesan es_ES
dc.contributor.author Alvaro Rodríguez, Maria Mercedes es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Navalón Oltra, Sergio es_ES
dc.date.accessioned 2021-05-14T12:41:11Z
dc.date.available 2021-05-14T12:41:11Z
dc.date.issued 2020-08-01 es_ES
dc.identifier.issn 1385-8947 es_ES
dc.identifier.uri http://hdl.handle.net/10251/166371
dc.description.abstract [EN] Bimetallic iron and copper oxide nanoparticles (NPs) supported on hydroxylated diamond (D3) exhibits an improved activity for the heterogeneous Fenton phenol degradation under natural or simulated sunlight irradiation with respect to analogous monometallic samples or than analogous FeCu NPs on graphite, activated carbon and P25 TiO2 semiconductor. FeCu/D3 catalyst exhibits good recyclability and stability especially working at pH 6. Overall, the high activity of the Fe20Cu80(0.2 wt%)/D3 catalyst is mainly due to the combination of the high activity of reduced copper species decomposing H2O2 to HO center dot radical, while Fe2+ allows the regeneration of these reduced copper species. es_ES
dc.description.sponsorship S.N. thanks financial support by the Fundacion Ramon Areces (XVIII Concurso Nacional para la Adjudicacion de Ayudas a la Investigacion en Ciencias de la Vida y de la Materia, 2016), Ministerio de Ciencia, Innovacion y Universidades RTI2018-099482-A-I00 project and Generalitat Valenciana grupos de investigacion consolidables 2019 (ref: AICO/2019/214) project. H.G. thanks financial support by the Spanish Ministry of Science and Innovation (Severo Ochoa SEV2016 and RTI2018-890237-CO2-1) and Generalitat Valenciana (Prometeo 2017/083) is also gratefully acknowledged. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation MINECO/RTI2018-890237-CO2-R1 es_ES
dc.relation.ispartof Chemical Engineering Journal es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject (photo)Fenton reaction es_ES
dc.subject Heterogeneous catalysis es_ES
dc.subject FeCu oxide bimetallic nanoparticles es_ES
dc.subject Diamond nanoparticles es_ES
dc.subject Natural sunlight irradiation es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Bimetallic iron-copper oxide nanoparticles supported on nanometric diamond as efficient and stable sunlight-assisted Fenton photocatalyst es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1016/j.cej.2020.124770 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2017%2F083/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-099482-A-I00/ES/DESCOMPOSICION FOTOCATALITICA DEL AGUA ASISTIDA POR LUZ VISIBLE EMPLEANDO MATERIALES NOVEDOSOS Y MULTIFUNCIONALES UIO-66%2F67/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//AICO%2F2019%2F214/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología Eléctrica - Institut de Tecnologia Elèctrica es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Manickam-Periyaraman, P.; Espinosa, JC.; Ferrer Ribera, RB.; Subramanian, S.; Alvaro Rodríguez, MM.; García Gómez, H.; Navalón Oltra, S. (2020). Bimetallic iron-copper oxide nanoparticles supported on nanometric diamond as efficient and stable sunlight-assisted Fenton photocatalyst. Chemical Engineering Journal. 393:1-11. https://doi.org/10.1016/j.cej.2020.124770 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.cej.2020.124770 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 11 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 393 es_ES
dc.relation.pasarela S\419868 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Fundación Ramón Areces es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministerio de Ciencia, Innovación y Universidades es_ES
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